Effect of surface oxygen functionalization of carbon support on the activity and durability of Pt/C catalysts for the oxygen reduction reaction
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As a result of electron withdrawal, Pt NPs could be oxidized, Ostwald ripening takes place easily, and finally the ripening of Pt NPs was accelerated.
“As a result, Pt NPs could be oxidized, the Oswald ripening takes place easily, and nally the ripening of Pt NPs was accelerated.”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [126]
Oxygen functionalization of Pt/C catalysts can have a positive impact on the initial activity for the ORR, but can exert an adverse effect on its long-term durability.
“The results from Kim et al. 126 indicate that oxygen functionalization of Pt/C catalysts can have a positive impact on the initial activity for the ORR, but can exert an adverse effect on its long-term durability.”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [126]
For oxygen-functionalized carbon support (CB_O), electrons in Pt NPs nearby oxygen groups could be withdrawn by highly electronegative oxygen.
“For oxygenfunctionalized carbon support (CB_O), the electrons in Pt NPs nearby oxygen groups could be withdrawn by highly electronegative oxygen.”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [126]
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- Authors
- Kim, J. H., Cheon, J. Y., Shin, T. J., Park, J. Y., & Joo, S. H.
- Affiliations
- Ulsan National Institute of Science and Technology (KR)
- Korea Advanced Institute of Science and Technology (KR)
- Corresponding author
- Joo, Sang Hoon
- Venue
- Carbon
- Publisher
- Elsevier BV
- Published
- 2016-05
- Volume
- 101
- Pages
- 449-457
- ISSN
- 0008-6223 (ISSN-L)
- OpenAlex
- W2256996027
- Cited by
- 153
- References
- 60
- Citations by year
- 2026: 6 · 2025: 23 · 2024: 14 · 2023: 18 · 2022: 18 · 2021: 27 · 2020: 16 · 2019: 8 · 2018: 10 · 2017: 7 · 2016: 6
- FWCI
- 2.81
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Carbon (publishedVersion)
- Scholarworks@UNIST (Ulsan National Institute of Science and Technology) (submittedVersion)
- Funders
- Ministry of Education
- Ministry of Trade, Industry and Energy (20133030011320)
- Korea Evaluation Institute of Industrial Technology (10050509, IBS-R004-G4)
- National Research Foundation of Korea (NRF-2013R1A1A2012960)
- Korea Institute of Energy Technology Evaluation and Planning
- Pohang University of Science and Technology
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Keywords
- oxygen reduction reaction, Pt/C catalyst, carbon black support, oxidative functionalization, catalyst stability, electrochemically active surface area, Ostwald ripening, interfacial structure, fuel cell catalysts
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