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Pectin as a rheology modifier: Origin, structure, commercial production and rheology

Open access
Chan, Siew Yin, Choo, Wee Sim, Young, David James, Loh, Xian Jun·2017·Carbohydrate Polymers

Abstract

Pectins are a diverse family of biopolymers with an anionic polysaccharide backbone of α-1,4-linked d-galacturonic acids in common. They have been widely used as emulsifiers, gelling agents, glazing agents, stabilizers, and/or thickeners in food, pharmaceutical, personal care and polymer products. Commercial pectin is classified as high methoxy pectin (HMP) with a degree of methylation (DM) >50% and low methoxy pectin (LMP) with a DM <50%. Amidated low methoxy pectins (ALMP) can be obtained through aminolysis of HMP. Gelation of HMP occurs by cross-linking through hydrogen bonds and hydrophobic forces between the methyl groups, assisted by a high co-solute concentration and low pH. In contrast, gelation of LMP occurs by the formation of ionic linkages via calcium bridges between two carboxyl groups from two different chains in close proximity, known as the 'egg-box' model. Pectin gels exhibit Newtonian behaviour at low shear rates and shear-thinning behaviour when the shear rate is increased. An overview of pectin from its origin to its physicochemical properties is presented in this review.

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Metadata

Authors
Chan, S. Y., Choo, W. S., Young, D. J., & Loh, X. J.
Venue
Carbohydrate Polymers
Publisher
Elsevier BV
Published
2017-04
Volume
161
Pages
118-139
ISSN
0144-8617 (ISSN-L)
OpenAlex
W2564611239
Cited by
557
References
7
FWCI
36.05
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Pectin as a rheology modifier: Origin, structure, commercial production and rheology. https://app.cochat.ai/papers/10.1016/j.carbpol.2016.12.033
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Chan, S. Y., Choo, W. S., Young, D. J., & Loh, X. J. (2017). Pectin as a rheology modifier: Origin, structure, commercial production and rheology. Carbohydrate Polymers. https://doi.org/10.1016/j.carbpol.2016.12.033

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