Acid- and base-catalyzed hydrolyses of aliphatic polycarbonates and polyesters
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Jung found that PPC was less susceptible to degradation in acidic medium than PCL and PLA, with increased degradation rate as PPC << PLA < PCL.
“They found that PPC was less susceptible to degradation in acidic medium than PCL and PLA, with increased degradation rate as PPC << PLA < PCL.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [425]
In contrast, PPC was more readily hydrolyzed in basic conditions, with increased degradation rate being PCL << PLA < PPC.
“In contrast, PPC was more readily hydrolyzed in basic conditions, with increased degradation rate being PCL << PLA < PPC.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [425]
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- Authors
- Jung, J. H., Ree, M., & Kim, H.
- Affiliations
- Pohang University of Science and Technology (KR)
- Dongguk University (KR)
- Corresponding author
- Ree, Moonhor
- Kim, Heesoo
- Venue
- Catalysis Today
- Publisher
- Elsevier BV
- Published
- 2006-06
- Volume
- 115
- Issue
- 1-4
- Pages
- 283-287
- ISSN
- 0920-5861 (ISSN-L)
- OpenAlex
- W2017895408
- Cited by
- 194
- References
- 24
- Citations by year
- 2026: 9 · 2025: 19 · 2024: 18 · 2023: 15 · 2022: 12 · 2021: 14 · 2020: 13 · 2019: 15 · 2018: 14 · 2017: 10 · 2016: 6 · 2015: 8 · 2014: 6 · 2013: 8 · 2012: 6
- FWCI
- 1.83
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Catalysis Today (publishedVersion)
- Open Access System for Information Sharing (Pohang University of Science and Technology) (submittedVersion)
- Funders
- Korea Science and Engineering Foundation (2005-01385)
- Ministry of Education
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
- Keywords
- poly(propylene carbonate), acid hydrolysis, alkaline hydrolysis, polycaprolactone, poly(D,L-lactide), aliphatic polycarbonates, aliphatic polyesters, carbon dioxide copolymerization, propylene oxide, degradation mechanism, pH-dependent degradation
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