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Cited by 469

The DOI matches its Crossref record; 58 of the 58 references it cites were found in a registry or an index.

Effect of temperature and aluminium on calcium (alumino)silicate hydrate chemistry under equilibrium conditions

Open access
Myers, Rupert J., L'Hôpital, Emilie, Provis, John L., Lothenbach, Barbara·2015·Cement and Concrete Research

Abstract

There exists limited information regarding the effect of temperature on the structure and solubility of calcium aluminosilicate hydrate (C–A–S–H). Here, calcium (alumino)silicate hydrate (C–(A–)S–H) is synthesised at Ca/Si = 1, Al/Si ≤ 0.15 and equilibrated at 7–80 °C. These systems increase in phase-purity, long-range order, and degree of polymerisation of C–(A–)S–H chains at higher temperatures; the most highly polymerised, crystalline and cross-linked C–(A–)S–H product is formed at Al/Si = 0.1 and 80 °C. Solubility products for C–(A–)S–H were calculated via determination of the solid-phase compositions and measurements of the concentrations of dissolved species in contact with the solid products, and show that the solubilities of C–(A–)S–H change slightly, within the experimental uncertainty, as a function of Al/Si ratio and temperature between 7 °C and 80 °C. These results are important in the development of thermodynamic models for C–(A–)S–H to enable accurate thermodynamic modelling of cement-based materials.

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Metadata

Authors
Myers, R. J., L'Hôpital, E., Provis, J. L., & Lothenbach, B.
Venue
Cement and Concrete Research
Publisher
Elsevier BV
Published
2015-02
Volume
68
Pages
83-93
ISSN
0008-8846 (ISSN-L)
OpenAlex
W1976446604
Cited by
469
References
58
FWCI
28.76
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Effect of temperature and aluminium on calcium (alumino)silicate hydrate chemistry under equilibrium conditions. https://app.cochat.ai/papers/10.1016/j.cemconres.2014.10.015
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Myers, R. J., L'Hôpital, E., Provis, J. L., & Lothenbach, B. (2015). Effect of temperature and aluminium on calcium (alumino)silicate hydrate chemistry under equilibrium conditions. Cement and Concrete Research. https://doi.org/10.1016/j.cemconres.2014.10.015

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