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Degradation of anthraquinone dye C.I. Reactive Blue 19 in aqueous solution by ozonation
Abstract
This study investigated the degradation of anthraquinone reactive dye C.I. Reactive Blue 19 (RB-19) with initial concentration of 100mg L(-1) in aqueous solution by ozone oxidation. The results of UV/VIS and FTIR spectra showed that the anthraquinone structures, nitrogen linkages and amino groups of RB-19 were destroyed under direct ozone reaction. The identification by LC-MS and GC-MS analyses indicated that some organic acids (e.g., phthalic acids) and 1,3-indanone could be the primary degradation products, respectively. The Microtox toxicity of the ozonated RB-19 solution initially increased but subsequently decreased when ozonation time increased. This detoxification accompanied biodegradability enhancement revealed by BOD/COD ratio increasing from 0.15 to 0.33 after 10min of ozonation.
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Studies on Reactive Blue 19 using same starting concentration (100 mg/mL) but different combination of AOP showed highly different results.
“Studies on Reactive Blue 19 conducted by different groups, using the same starting concentration (100 mg/mL) but different combination of AOP, showed highly different results.”
From Degradation of anthraquinone dyes from effluents: A review focusing on enzymatic dye degradation with industrial potential (2020) · cites this paper as [69]
Using combination of methods such as Fenton reaction coupled with adsorption on pyrite ash, or ozonation coupled with UV radiation can be much more efficient compared to ozonation only.
“It was shown that using a combination of methods such as Fenton reaction coupled with adsorption on pyrite ash 67 , or ozonation coupled with UV radiation 68 can be much more efficient compared to ozonation only 69 , based on the .”
From Degradation of anthraquinone dyes from effluents: A review focusing on enzymatic dye degradation with industrial potential (2020) · cites this paper as [69]
Identified fragments for ozonation of Reactive Blue 19 ranged from a mixture of phenol, acetic acid and propandioic acid, to a mixture of phenol, acetic acid and oxalic acid, and to a mixture of phthalic acid and unspecified carboxylic acids.
“Identified fragments ranged from a mixture of phenol, acetic acid and propandioic acid 68 , to a mixture of phenol, acetic acid and oxalic acid 92 and to a mixture of phthalic acid and unspecified carboxylic acids 69 .”
From Degradation of anthraquinone dyes from effluents: A review focusing on enzymatic dye degradation with industrial potential (2020) · cites this paper as [69]
There is a lack of control over dye degradation reactions and existence of spontaneous reactions that can lead to the same lower fragments via multiple paths.
“This shows the lack of control over the dye degradation reactions and the existence of spontaneous reactions that can lead to the same lower fragments via multiple paths 69, 74 .”
From Degradation of anthraquinone dyes from effluents: A review focusing on enzymatic dye degradation with industrial potential (2020) · cites this paper as [69]
Fanchiang et al. used slightly higher ozone feed rate compared to the other studies, which might have been responsible for the higher mineralisation potential.
“Upon examination of the conditions used, Fanchiang et al. 69 used slightly higher ozone feed rate compared to the other studies, which might have been responsible for the higher mineralisation potential.”
From Degradation of anthraquinone dyes from effluents: A review focusing on enzymatic dye degradation with industrial potential (2020) · cites this paper as [69]
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Research works printed but not linked: 28
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Metadata
- Authors
- Fanchiang, J.-M., & Tseng, D.-H.
- Venue
- Chemosphere
- Publisher
- Elsevier BV
- Published
- 2009-09
- Volume
- 77
- Issue
- 2
- Pages
- 214-221
- ISSN
- 0045-6535
- Cited by
- 125
- References
- 0
- Language
- en
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