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Mechanism analysis of heavy metal lead captured by natural-aged microplastics

Fu, Qianmin, Tan, Xiaofei, Ye, Shujing, Ma, Lili, Gu, Yanling, Zhang, Peng, Chen, Qiang, Yang, Yuanyuan, Tang, Yuanqiang·2021·Chemosphere

Abstract

In this paper, the mechanism of lead (Pb(II)) captured by natural-aged microplastics in aqueous medium was explored. Compared with pristine microplastics, the natural-aged microplastics were more efficient for adsorbing Pb(II). After treated by hydrochloric acid (HCl) or sodium hydroxide (NaOH), the organic film was damaged and the adsorption efficiency decreased obviously, which proved that the organic film played an important role in Pb(II) capture. The fitting results of the isothermal adsorption model showed that this adsorption process was more in line with Langmuir model than with Freundlich model, and the maximum adsorption amount (13.60 mg/g) could also be obtained from the Langmuir model. Based on the comprehensive analysis of XRD, XPS and FTIR results, it was found that Pb(II) capture by natural-aged microplastics was mainly determined by the oxygen containing functional groups (carboxyl and hydroxyl groups) on the organic film. Besides, the measurement results of Zeta potential and pH effect showed that electrostatic interaction was mainly responsible for the Pb(II) capture process.

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Metadata

Authors
Fu, Q., Tan, X., Ye, S., Ma, L., Gu, Y., Zhang, P., Chen, Q., Yang, Y., & Tang, Y.
Venue
Chemosphere
Publisher
Elsevier BV
Published
2021-05
Volume
270
Pages
128624
ISSN
0045-6535 (ISSN-L)
OpenAlex
W3092943414
Cited by
256
References
3
FWCI
7.49
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Mechanism analysis of heavy metal lead captured by natural-aged microplastics. https://app.cochat.ai/papers/10.1016/j.chemosphere.2020.128624
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Fu, Q., Tan, X., Ye, S., Ma, L., Gu, Y., Zhang, P., Chen, Q., Yang, Y., & Tang, Y. (2021). Mechanism analysis of heavy metal lead captured by natural-aged microplastics. Chemosphere. https://doi.org/10.1016/j.chemosphere.2020.128624

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