Ce(Ⅲ) activates peroxymonosulfate for the degradation of substituted PAHs
Abstract
Substituted polycyclic aromatic hydrocarbons (SPAHs) are being intensively investigated, considering their high toxicity. Additionally, the mechanism of the effect of substituents on the removal of SPAHs and the activation of Ce(III) ions on peroxymonosulfate (PMS) have not been explored. Here we evaluated the removal efficiency of SPAHs in the oxidation system constructed by Ce(Ⅲ) ions and PMS, with emphasized the effect of substituents on SPAHs degradation. Ce(Ⅲ) has high catalytic performance for PMS, and the degradation percentage of all pollutants was higher than 92%. The significantly negative correlation between the reaction rate constants of SPAHs and the highest occupied molecular orbital-the lowest unoccupied molecular orbital gap, confirms that substituents lead to the differences in the degradation of SPAHs. The generation of reactive oxygen species (SO 4•-, •OH, and 1 O 2) is based on the electron transfer between Ce(Ⅲ) and PMS, and the contribution of ROS to substituted naphthalene varies due to the role of substituents. The Ce(Ⅳ)/Ce(Ⅲ) cycle accelerates the activation of PMS. Based on the transformation products and condensed Fukui function, the possible degradation pathways are inferred. In addition, inorganic anions and organic matter have little effect on the Ce(Ⅲ)/PMS system, which is a prerequisite for applying this system to real-world waste-water for SPAHs removal. This work demonstrates a new model of the degradation mechanism of SPAHs in the Ce(Ⅲ)/PMS system.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Functional groups such as -NO2 and -CH3 attached to NAP improved the degradation efficiency through their effect on the charge distribution of NAP derivatives.
“The results indicate that the functional groups, such as -NO2 and -CH3 attached to NAP, improved the degradation efficiency through their effect on the charge distribution of NAP derivatives [70].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [70]
In Ce(III)/PMS, the degradation rates of NAP, 1-MN, 1-NN were 0.0080, 0.0086, 0.0119 min-1, and increased to 0.0131 min-1 for NAP, 0.0096 min-1 for 1-MN, and 0.0133 min-1 for 1-NN.
“The degradation rates of NAP, 1-MN, 1-NN in Ce(III)/PMS, were 0.0080, 0.0086, 0.0119, and it was increased to 0.0131 min -1 for NAP, 0.0096 min -1 for 1-MN, and 0.0133 min -1 for 1-NN.”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [70]
Cites
Multiwfn: A multifunctional wavefunction analyzer
Lu, T., & Chen, F. (2011) · Journal of Computational Chemistry · doi:10.1002/jcc.22885 · Cited by 45,749 · see citing works
Wang, J., & Wang, S. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.11.059 · Cited by 4,087 · see citing works
Radical Generation by the Interaction of Transition Metals with Common Oxidants
Anipsitakis, G. P., & Dionysiou, D. D. (2004) · Environmental Science & Technology · doi:10.1021/es035121o · Cited by 3,088 · see citing works
Reactive species in advanced oxidation processes: Formation, identification and reaction mechanism
Wang, J., & Wang, S. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126158 · Cited by 1,598 · see citing works
Wang, J., & Wang, S. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.128392 · Cited by 1,332 · see citing works
Removal of 2-MIB and geosmin using UV/persulfate: Contributions of hydroxyl and sulfate radicals
Xie, P., Ma, J., Liu, W., Zou, J., Yue, S., Li, X., Wiesner, M. R., & Fang, J. (2014) · Water Research · doi:10.1016/j.watres.2014.11.029 · Cited by 592 · see citing works
Dong, X., Ren, B., Sun, Z., Li, C., Zhang, X., Kong, M., Zheng, S., & Dionysiou, D. D. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.04.052 · Cited by 551 · see citing works
Xu, M., Li, J., Yan, Y., Zhao, X., Yan, J., Zhang, Y., Lai, B., Chen, X., & Song, L. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.03.075 · Cited by 513 · see citing works
Self-citationGuo, S., Wang, H., Yang, W., Hussain, F., You, L., & Zhou, K. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118250 · Cited by 500 · see citing works
Surface controlled generation of reactive radicals from persulfate by carbocatalysis on nanodiamonds
Duan, X., Su, C., Zhou, L., Sun, H., Suvorova, A. A., Odedairo, T., Zhu, Z., Shao, Z., & Wang, S. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.043 · Cited by 489 · see citing works
Nitrated polycyclic aromatic hydrocarbons (nitro-PAHs) in the environment – A review
Bandowe, B. A. M., & Meusel, H. (2017) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2016.12.115 · Cited by 428 · see citing works
Beyond the obvious: Environmental health implications of polar polycyclic aromatic hydrocarbons
Idowu, O., Semple, K. T., Ramadass, K., O’Connor, W. A., Hansbro, P. M., & Thavamani, P. (2019) · Environment International · doi:10.1016/j.envint.2018.12.051 · Cited by 388 · see citing works
Degradation of Ofloxacin by Perylene Diimide Supramolecular Nanofiber Sunlight-Driven Photocatalysis
Chen, P., Blaney, L. M., Cagnetta, G., Huang, J. G., Wang, B., Wang, Y., Deng, S., & Yu, G. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.8b05827 · Cited by 382 · see citing works
Fenton-Like Reaction Catalyzed by the Rare Earth Inner Transition Metal Cerium
Heckert, E. G., Seal, S., & Self, W. T. (2008) · Environmental Science & Technology · doi:10.1021/es8001508 · Cited by 371 · see citing works
Li, J., Wan, Y., Li, Y., Yao, G., & Lai, B. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.117782 · Cited by 356 · see citing works
Zheng, H., Bao, J., Huang, Y., Xiang, L., Faheem, M., Ren, B., Du, J., Nadagouda, M. N., & Dionysiou, D. D. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118056 · Cited by 328 · see citing works
Liu, H., Bruton, T. A., Li, W., Buren, J. V., Prasse, C., Doyle, F. M., & Sedlak, D. L. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b04815 · Cited by 327 · see citing works
Overview of Polycyclic Aromatic Compounds (PAC)
Achten, C., & Andersson, J. T. (2015) · Polycyclic aromatic compounds · doi:10.1080/10406638.2014.994071 · Cited by 300 · see citing works
C−H Carboxylation of Aromatic Compounds through CO2 Fixation
Luo, J., & Larrosa, I. (2017) · ChemSusChem · doi:10.1002/cssc.201701058 · Cited by 236 · see citing works
Removal of carbamazepine from urban wastewater by sulfate radical oxidation
Matta, R., Tlili, S., Chirón, S., & Barbati, S. (2010) · Environmental Chemistry Letters · doi:10.1007/s10311-010-0285-z · Cited by 202 · see citing works
Comparative study on the methods for predicting the reactive site of nucleophilic reaction
Cao, J., Ren, Q., Chen, F., et al. (2015) · Science China Chemistry · doi:10.1007/s11426-015-5494-7 · Cited by 200 · see citing works
Han, S., & Xiao, P. (2022) · Separation and Purification Technology · doi:10.1016/j.seppur.2022.120533 · Cited by 182 · see citing works
Hong, W., Jia, H.-L., Li, Y.-F., Sun, Y.-Q., Liu, X.-J., & Wang, L. (2016) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2016.02.003 · Cited by 165 · see citing works
Ji, Q., Cheng, X., Wu, Y., et al. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119579 · Cited by 163 · see citing works
Wang, Y., Yan, P., Dou, X., et al. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120048 · Cited by 124 · see citing works
You, Y., Zhao, Z., Song, Y., Li, J., Li, J., & Cheng, X. (2020) · Separation and Purification Technology · doi:10.1016/j.seppur.2020.117977 · Cited by 100 · see citing works
Zeng, G., You, H., Du, M., Zhang, Y., Ding, Y., Xu, C., Liu, B., Chen, B., & Pan, X. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.128498 · Cited by 100 · see citing works
Nano-MoO2 activates peroxymonosulfate for the degradation of PAH derivatives
Chen, X., Vione, D. V., Borch, T., Wang, J., & Gao, Y. (2021) · Water Research · doi:10.1016/j.watres.2021.116834 · Cited by 95 · see citing works
Self-citationArlt, V. M., Stiborová, M., Hewer, A. J., et al. (2003) · PubMed · Cited by 84 · see citing works
Qiao, M., Fu, L., Li, Z., et al. (2019) · Environmental Pollution · doi:10.1016/j.envpol.2019.113600 · Cited by 81 · see citing works
Jaafarzadeh, N., Ghanbari, F., & Zahedi, A. (2018) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2018.01.020 · Cited by 79 · see citing works
Khajeh, M., Amin, M. M., Fatehizadeh, A., & Aminabhavi, T. M. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.129163 · Cited by 79 · see citing works
Qiao, M., Qi, W.-X., Liu, H.-J., & Qu, J. (2014) · Water Research · doi:10.1016/j.watres.2013.12.032 · Cited by 73 · see citing works
Nováková, Z., Novák, J., Kitanovski, Z., Kukučka, P., Smutná, M., Wietzoreck, M., Lammel, G., & Hilscherová, K. (2020) · Environment International · doi:10.1016/j.envint.2020.105634 · Cited by 73 · see citing works
Shen, Y., Lei, L., Zhang, X., et al. (2007) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2007.05.024 · Cited by 69 · see citing works
Tan, W., Ruan, Y., Diao, Z.-H., Song, G., Su, M., Hou, L., Chen, D., Kong, L., & Deng, H. (2021) · Chemosphere · doi:10.1016/j.chemosphere.2021.130626 · Cited by 69 · see citing works
Loading and removal of PAHs in a wastewater treatment plant in a separated sewer system.
Ozaki, N., Takamura, Y., Kojima, K., & Kindaichi, T. (2015) · Water Research · doi:10.1016/j.watres.2015.05.002 · Cited by 68 · see citing works
Wang, Y., Nie, M., Diwu, Z., et al. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2021.125657 · Cited by 68 · see citing works
Qian, Y., Zhou, X., Zhang, Y., et al. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.05.053 · Cited by 67 · see citing works
Guo, J., Gao, Q., Yang, S., Zheng, F. Y., Du, B., Wen, S., & Wang, D. (2020) · Process Safety and Environmental Protection · doi:10.1016/j.psep.2020.12.003 · Cited by 62 · see citing works
Feng, Y., Sang, W., Deng, Z., et al. (2021) · Separation and Purification Technology · doi:10.1016/j.seppur.2021.119783 · Cited by 58 · see citing works
Kong, J., Dai, Y., Han, M., et al. (2020) · Journal of Environmental Sciences · doi:10.1016/j.jes.2020.09.025 · Cited by 56 · see citing works
Liu, X., Xu, P., Fu, Q., et al. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.131679 · Cited by 52 · see citing works
Yu, Y., Li, S., Peng, X., et al. (2016) · Environmental Chemistry Letters · doi:10.1007/s10311-016-0573-3 · Cited by 50 · see citing works
Buren, J. V., Cuthbertson, A. A., Ocasio, D., et al. (2021) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.1c00316 · Cited by 50 · see citing works
Yang, L., Zhang, L., Chen, L., et al. (2021) · Environmental Pollution · doi:10.1016/j.envpol.2021.117360 · Cited by 41 · see citing works
Yao, Y., Hu, H., Yin, H., Yu, M., Zheng, H., Zhang, Y., & Wang, S. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119333 · Cited by 36 · see citing works
So, H. L., Chu, W., & Wang, Y. (2018) · Chemosphere · doi:10.1016/j.chemosphere.2018.11.091 · Cited by 34 · see citing works
Xu, X., Liu, D., Chen, W., et al. (2018) · Environmental Chemistry Letters · doi:10.1007/s10311-018-0748-1 · Cited by 29 · see citing works
Trentin, A., Harb, S. V., Uvida, M. C., et al. (2021) · Corrosion Science · doi:10.1016/j.corsci.2021.109581 · Cited by 27 · see citing works
Catalytic degradation of orange G under microwave irradiation with a novel nanohybrid catalyst
Riaz, U., Ashraf, S. M., & Ruhela, A. (2014) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2014.06.010 · Cited by 24 · see citing works
Amino and hydroxy substitution influences pyrene–DNA binding
Qin, C., Hu, X., Waigi, M. G., et al. (2020) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2020.138542 · Cited by 24 · see citing works
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
Rayaroth, M. P., Boczkaj, G., Aubry, O., Aravind, U. K., & Aravindakumar, C. T. (2023) · Water · doi:10.3390/w15081615 · Cited by 171 · see citing works
Advanced oxidation processes for the removal of mono and polycyclic aromatic hydrocarbons—A review
Rayaroth, M. P., Marchel, M., & Boczkaj, G. (2023) · Science of The Total Environment · doi:10.1016/j.scitotenv.2022.159043 · Cited by 158 · see citing works
- Authors
- Chen, X., Wang, P., Peng, F., Zhou, Z., Waigi, M. G., & Ling, W.
- Affiliations
- Nanjing Agricultural University (CN)
- Corresponding author
- Ling, Wanting
- Venue
- Chemosphere
- Publisher
- Elsevier BV
- Published
- 2022-11
- Volume
- 306
- Pages
- 135525
- ISSN
- 0045-6535 (ISSN-L)
- OpenAlex
- W4283727099
- Cited by
- 36
- References
- 52
- Citations by year
- 2026: 4 · 2025: 9 · 2024: 13 · 2023: 8 · 2022: 2
- FWCI
- 2.34
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Chemosphere (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- peroxymonosulfate activation, cerium(III) catalysis, substituent effects, HOMO-LUMO gap, reactive oxygen species, sulfate radicals, hydroxyl radicals, singlet oxygen, degradation intermediates, Fukui function, degradation mechanism, wastewater treatment
- MeSH terms
- Peroxides, Polycyclic Aromatic Hydrocarbons, Water Pollutants, Chemical, Wastewater
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review