Advanced oxidation processes for the removal of mono and polycyclic aromatic hydrocarbons—A review
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Aromatic hydrocarbons (AHs) are toxic environmental contaminants presented in most of the environmental matrices. Advanced oxidation processes (AOPs) for the removal of AHs in the account of complete mineralization from various environmental matrices have been reviewed in this paper. An in-depth discussion on various AOPs for mono (BTEX) and polyaromatic hydrocarbons (PAHs) and their derivatives is presented. Most of the AOPs were effective in the removal of AHs from the aquatic environment. A comparative study on the degradation of various AHs revealed that the oxidation of the AHs is strongly dependent on the number of aromatic rings and the functional groups attached to the ring. The formation of halogenated and nitrated derivatives of AHs in the real contaminated water containing chloride, nitrite, and nitrate ions seems to be a challenge in using the AOPs in real systems. The phenolic compounds, quinone, alcohols, and aliphatic acids are the important byproducts formed during the oxidation of AHs, initiated by the attack of reactive oxygen species (ROS) on their electron-rich center. In conclusion, AOPs are the adaptable method for the removal of AHs from different environmental matrices. The persulfate-based AOPs were applied in the soil phase removal as an in situ chemical oxidation of AHs. Moreover, the combination of AOPs will be a conclusive solution to avoid or minimize unexpected or other toxic intermediate products and to obtain rapid oxidation of AHs.
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Degradation of organic contaminants by AOPs such as UV/H2O2 photolysis, photocatalysis, Fenton, electro-Fenton or cavitation-based methods results in good degradation and mineralization efficiency.
“The degradation of contaminants and their derivatives by various AOPs, such as UV/H2O2 photolysis, photocatalysis, Fenton, electro-Fenton or cavitation-based methods, etc., resulted in good degradation and mineralization efficiency [11-16].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [11]
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Cited by
Sorted by citations
Rayaroth, M. P., Boczkaj, G., Aubry, O., Aravind, U. K., & Aravindakumar, C. T. (2023) · Water · doi:10.3390/w15081615 · Cited by 171 · see citing works
“The degradation of contaminants and their derivatives by various AOPs, such as UV/H 2 O 2 photolysis, photocatalysis, Fenton, electro-Fenton or cavitation-based methods, etc., resulted in good degradation and mineralization ef-ficiency [11–16].”
Self-citation
- Authors
- Rayaroth, M. P., Marchel, M., & Boczkaj, G.
- Affiliations
- Université d'Orléans (FR)
- Gdańsk University of Technology (PL)
- Corresponding author
- Boczkaj, Grzegorz
- Venue
- Science of The Total Environment
- Publisher
- Elsevier BV
- Published
- 2023-01
- Volume
- 857
- Issue
- Pt 2
- Pages
- 159043
- ISSN
- 0048-9697 (ISSN-L)
- OpenAlex
- W4297399391
- Cited by
- 158
- References
- 166
- Citations by year
- 2026: 26 · 2025: 50 · 2024: 48 · 2023: 34
- FWCI
- 1.98
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- The Science of The Total Environment (publishedVersion, cc-by)
- PubMed (publishedVersion)
- Funders
- Narodowe Centrum Nauki (UMO-2017/25/B/ST8/01364)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Keywords
- advanced oxidation processes, aromatic hydrocarbons, polycyclic aromatic hydrocarbons, BTEX, mineralization, reactive oxygen species, oxidation by-products, soil remediation, in situ chemical oxidation, persulfate, contaminated water treatment
- MeSH terms
- Hydrocarbons, Aromatic, Oxidation-Reduction, Polycyclic Aromatic Hydrocarbons, Soil, Soil Pollutants
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