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Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles
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“This small-molecule ionic isolation lattices (SMILES) transfers the optical properties of typical cationic dyes directly and reliably from solution to high-density molecular crystals (Figure 8a).157,158”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [157]
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“SMILES crystals are formed with most cationic dyes, including cyanines, oxazines, and rhodamines, which deliver predictable optical properties and high fluorescence brightness with high dye densities (one dye per ∼4 nm3).”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [157]
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“An alternative approach is based on hierarchical coassembly using a scaffold ensuring spatial and electronic isolation to prohibit fluorescence quenching in an aggregate state.”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [157]
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Metadata
- Authors
- Benson, C. R., Kacenauskaite, L., VanDenburgh, K. L., Zhao, W., Qiao, B., Sadhukhan, T., Pink, M., Chen, J., Borgi, S., Chen, C.-H., Davis, B. J., Simon, Y. C., Raghavachari, K., Laursen, B. W., & Flood, A. H.
- Affiliations
- Indiana University Bloomington (US)
- University of Copenhagen (DK)
- University of Southern Mississippi (US)
- Corresponding author
- Laursen, Bo W.
- Flood, Amar H.
- ORCID
- Venue
- Chem
- Publisher
- Elsevier BV
- Published
- 2020-08
- Volume
- 6
- Issue
- 8
- Pages
- 1978-1997
- ISSN
- 2451-9294 (ISSN-L)
- OpenAlex
- W3047531788
- Cited by
- 226
- References
- 63
- Citations by year
- 2026: 13 · 2025: 41 · 2024: 47 · 2023: 42 · 2022: 39 · 2021: 40 · 2020: 3
- FWCI
- 12.06
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Chem (publishedVersion)
- Research at the University of Copenhagen (University of Copenhagen) (publishedVersion, cc-by-nc-nd)
- Aquila Digital Community (University of Southern Mississippi) (submittedVersion)
- Funders
- Forskerakademiet (DFF-6111-00483)
- National Science Foundation (DMR-1533988, DGE-149999)
- College of Arts and Sciences, Boston University
- Københavns Universitet
- Indiana University
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Crystallography and molecular interactions
- Keywords
- fluorescent dyes, fluorescence quenching, concentration quenching, organic light-emitting diodes, polymer additives, xanthene, oxazines, cyanine dyes, wide band gap, optical materials
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