The DOI matches its Crossref record; 53 of the 53 references it cites were found in a registry or an index.
Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity
Open accessAbstract
Summary Nanozymes are promising alternatives to natural enzymes, but their use remains limited owing to poor specificity. Overcoming this and controlling the targeted enzyme-like performance of traditional nanozymes is extremely challenging due to the intrinsic structural complexity of these systems. We report theoretical design and experimental realization of a series of heterogeneous molybdenum single-atom nanozymes (named MoSA–Nx–C), wherein we find that the peroxidase-like specificity is well regulated by the coordination numbers of single Mo sites. The resulting MoSA–N3–C catalyst shows exclusive peroxidase-like behavior. It achieves this behavior via a homolytic pathway, whereas MoSA–N2–C and MoSA–N4–C catalysts have a different heterolytic pathway. The mechanism of this coordination-number-dependent enzymatic specificity is attributed to geometrical structure differences and orientation relationships of the frontier molecular orbitals toward these MoSA–Nx–C peroxidase mimics. This study demonstrates the rational design of peroxidase-specific nanozymes and precise regulation of their enzymatic properties.
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Self-citationZhang, T., Jin, J., Chen, J., Fang, Y., Han, X., Chen, J., Li, Y., Wang, Y., Liu, J., & Wang, L. (2022) · Nature Communications · doi:10.1038/s41467-022-34619-5 · Cited by 296
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Defect engineering in nanozymes
Wu, Y., Xu, W., Jiao, L., Tang, Y., Chen, Y., Gu, W., & Zhu, C. (2022) · Materials Today · doi:10.1016/j.mattod.2021.10.032 · Cited by 269
Atomically Dispersed MoO x on Rhodium Metallene Boosts Electrocatalyzed Alkaline Hydrogen Evolution
Wu, J., Fan, J., Zhao, X., Wang, Y., Wang, D., Liu, H., Gu, L., Zhang, Q., Zheng, L., Singh, D. J., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202207512 · Cited by 123
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Metadata
- Authors
- Wang, Y., Jia, G., Cui, X., Zhao, X., Zhang, Q., Gu, L., Zheng, L., Li, L. H., Wu, Q., Singh, D. J., Matsumura, D., Tsuji, T., Cui, Y.-T., Zhao, J., & Zheng, W.
- Venue
- Chem
- Publisher
- Elsevier BV
- Published
- 2021-02
- Volume
- 7
- Issue
- 2
- Pages
- 436-449
- ISSN
- 2451-9294 (ISSN-L)
- OpenAlex
- W3101877203
- Cited by
- 417
- References
- 53
- FWCI
- 18.37
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Wang, Y., Jia, G., Cui, X., Zhao, X., Zhang, Q., Gu, L., Zheng, L., Li, L. H., Wu, Q., Singh, D. J., Matsumura, D., Tsuji, T., Cui, Y.-T., Zhao, J., & Zheng, W. (2021). Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity. Chem. https://doi.org/10.1016/j.chempr.2020.10.023
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