Thermally activated persulfate-based Advanced Oxidation Processes—Recent progress and challenges in mineralization of persistent organic chemicals: A review
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Thermally activated persulfate (TAP) finds application in Advanced Oxidation Processes for the removal of pollutants from contaminated water and soil. This paper reviewed the various cases of TAP in the environmental remediation. The pollutants such as individual pharmaceuticals, biocides, cyclic organic compounds, and dyes are considered in this review. It is interesting to note that most of the organic compounds undergo complete degradation at a high temperature of 70°C with a first-order reaction kinetics. The influence of operating parameters such as temperature, persulfate concentration, initial pH, and degradation behavior in the presence of natural water constituents are also discussed. In addition, several processes to reduce the temperature of TAP are highlighted.
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A similar negative effect is reported for other pharmaceuticals, such as simazine, losartan, carbamazepine, thiamethoxam, etc.
“A similar effect is reported for other pharmaceuticals, such as simazine, losartan, carbamazepine, thiamethoxam, etc., [116-120].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [120]
Cites
Wang, J., & Wang, S. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.11.059 · Cited by 4,087 · see citing works
Chemistry of persulfates in water and wastewater treatment: A review
Wacławek, S., Lutze, H. V., Grübel, K., Padil, V. V. T., Černík, M., & Dionysiou, D. D. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.07.132 · Cited by 1,883 · see citing works
Advanced Oxidation Processes for Wastewater Treatment: Formation of Hydroxyl Radical and Application
WANG, J. L., & XU, L. J. (2012) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643389.2010.507698 · Cited by 1,586 · see citing works
Wastewater treatment by means of advanced oxidation processes at basic pH conditions: A review
Boczkaj, G., & Fernandes, A. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.03.084 · Cited by 1,568 · see citing works
Self-citationActivated persulfate for organic chemical degradation: A review
Matzek, L. W., & Carter, K. E. (2016) · Chemosphere · doi:10.1016/j.chemosphere.2016.02.055 · Cited by 1,492 · see citing works
Identification of Sulfate and Hydroxyl Radicals in Thermally Activated Persulfate
Liang, C., & Su, H.-W. (2009) · Industrial & Engineering Chemistry Research · doi:10.1021/ie9002848 · Cited by 1,308 · see citing works
Kolthoff, I. M., & Miller, I. K. (1951) · Journal of the American Chemical Society · doi:10.1021/ja01151a024 · Cited by 1,115 · see citing works
Oxidation of Chlorinated Ethenes by Heat-Activated Persulfate: Kinetics and Products
Waldemer, R. H., Tratnyek, P. G., Johnson, R. L., & Nurmi, J. T. (2006) · Environmental Science & Technology · doi:10.1021/es062237m · Cited by 757 · see citing works
Fedorov, K., Plata-Gryl, M., Khan, J. A., & Boczkaj, G. (2020) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.122804 · Cited by 678 · see citing works
Self-citationCritical review of the science and sustainability of persulphate advanced oxidation processes
Ike, I. A., Linden, K. G., Orbell, J. D., & Duke, M. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.01.034 · Cited by 625 · see citing works
Combination of hydrodynamic cavitation and SR-AOPs for simultaneous degradation of BTEX in water
Fedorov, K., Sun, X., & Boczkaj, G. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.128081 · Cited by 616 · see citing works
Self-citationJi, Y., Dong, C., Kong, D., Lu, J., & Zhou, Q. (2014) · Chemical Engineering Journal · doi:10.1016/j.cej.2014.10.097 · Cited by 554 · see citing works
Rayaroth, M. P., Aravindakumar, C. T., Shah, N. S., & Boczkaj, G. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.133002 · Cited by 532 · see citing works
Self-citationDegradation of chloramphenicol by thermally activated persulfate in aqueous solution
Nie, M., Yang, Y., Zhang, Z., Yan, C., Wang, X., Li, H., & Dong, W. (2014) · Chemical Engineering Journal · doi:10.1016/j.cej.2014.02.047 · Cited by 469 · see citing works
Ushani, U., Lü, X., Wang, J., Zhang, Z., Dai, J.-J., Tan, Y., Wang, S., Li, W., Niu, C., Cai, T., et al. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126232 · Cited by 457 · see citing works
Fan, Y., Ji, Y., Kong, D., Lu, J., & Zhou, Q. (2015) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2015.06.058 · Cited by 452 · see citing works
Kinetics and Mechanism of Ultrasonic Activation of Persulfate: An in Situ EPR Spin Trapping Study
Wei, Z., Villamena, F. A., & Weavers, L. K. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.6b05392 · Cited by 426 · see citing works
Oxidation of bisoprolol in heated persulfate/H2O systems: Kinetics and products
Ghauch, A., & Tuqan, A. M. (2011) · Chemical Engineering Journal · doi:10.1016/j.cej.2011.12.048 · Cited by 415 · see citing works
Effect and mechanism of persulfate activated by different methods for PAHs removal in soil
Zhao, D., Liao, X., Yan, X., Huling, S. G., Chai, T., & Tao, H. (2013) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2013.03.056 · Cited by 405 · see citing works
Qian, Y.-J., Guo, X., Zhang, Y.-L., Peng, Y., Sun, P., Huang, C.-H., Niu, J., Zhou, X., & Crittenden, J. (2016) · Environmental Science and Technology · doi:10.1021/acs.est.5b03715 · Cited by 334 · see citing works
Ibuprofen removal by heated persulfate in aqueous solution: A kinetics study
Ghauch, A., Tuqan, A. M., & Kibbi, N. (2012) · Chemical Engineering Journal · doi:10.1016/j.cej.2012.05.051 · Cited by 333 · see citing works
Heat-activated persulfate oxidation of diuron in water
Tan, C., Gao, N., Deng, Y., An, N., & Deng, J. (2012) · Chemical Engineering Journal · doi:10.1016/j.cej.2012.07.005 · Cited by 307 · see citing works
Thermally activated persulfate (TAP) oxidation of antiepileptic drug carbamazepine in water
Deng, J., Shao, Y., Gao, N., Deng, Y., Zhou, S., & Hu, X. (2013) · Chemical Engineering Journal · doi:10.1016/j.cej.2013.05.044 · Cited by 268 · see citing works
Zhen, G., Lü, X., Su, L., Kobayashi, T., Kumar, G., Zhou, T., Xu, K., Li, Y., Zhu, X., & Zhao, Y. (2018) · Water Research · doi:10.1016/j.watres.2018.01.072 · Cited by 257 · see citing works
Naproxen abatement by thermally activated persulfate in aqueous systems
Ghauch, A., Tuqan, A. M., & Kibbi, N. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.05.067 · Cited by 244 · see citing works
Wang, Q., Lu, X., Cao, Y., Ma, J., Jiang, J., Bai, X., & Hu, T. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.07.041 · Cited by 217 · see citing works
Park, S., Lee, L., Medina, V. F., Zull, A., & Waisner, S. A. (2015) · Chemosphere · doi:10.1016/j.chemosphere.2015.11.097 · Cited by 214 · see citing works
Methylene blue discoloration by heated persulfate in aqueous solution
Ghauch, A., Tuqan, A. M., Kibbi, N., et al. (2012) · Chemical Engineering Journal · doi:10.1016/j.cej.2012.09.122 · Cited by 203 · see citing works
Sulfate radicals induced degradation of Triclosan in thermally activated persulfate system
Gao, H., Chen, J., Zhang, Y., & Zhou, X. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.07.080 · Cited by 200 · see citing works
Activation of persulfate with biochar for degradation of bisphenol A in soil
Liu, J., Jiang, S., Chen, D., Dai, G., Wei, D., & Shu, Y. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.122637 · Cited by 189 · see citing works
Degradation of p-nitrophenol by heat and metal ions co-activated persulfate
Zhang, M., Chen, X., Zhou, H., Murugananthan, M., & Zhang, Y. (2014) · Chemical Engineering Journal · doi:10.1016/j.cej.2014.11.060 · Cited by 188 · see citing works
Liu, L., Lin, S., Zhang, W., Farooq, U., Shen, G., & Hu, S. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.04.068 · Cited by 186 · see citing works
Amasha, M., Baalbaki, A., & Ghauch, A. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.05.118 · Cited by 182 · see citing works
Heat-activated persulfate oxidation of methyl- and ethyl-parabens: Effect, kinetics, and mechanism
Chen, Y., Deng, P., Xie, P., Shang, R., Wang, Z., & Wang, S. (2016) · Chemosphere · doi:10.1016/j.chemosphere.2016.11.143 · Cited by 168 · see citing works
Wu, Y., Bu, L., Duan, X., Zhu, S., Kong, M., Zhu, N., & Zhou, S. (2020) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2020.123065 · Cited by 154 · see citing works
Milh, H., Schoenaers, B., Stesmans, A. L., Cabooter, D., & Dewil, R. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.122234 · Cited by 143 · see citing works
Liu, C., Higgins, C. P., Wang, F., & Shih, K. (2011) · Separation and Purification Technology · doi:10.1016/j.seppur.2011.09.047 · Cited by 134 · see citing works
Rayaroth, M. P., Lee, C.-S., Aravind, U. K., Aravindakumar, C. T., & Chang, Y.-S. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.01.031 · Cited by 126 · see citing works
Self-citationOxidation of bisphenol A in water by heat-activated persulfate
Potakis, N., Frontistis, Z., Αντωνοπούλου, Μ., Konstantinou, I., & Mantzavinos, D. (2016) · Journal of Environmental Management · doi:10.1016/j.jenvman.2016.05.045 · Cited by 113 · see citing works
Degradation of ibuprofen by thermally activated persulfate in soil systems
Liu, Y., Wang, S., Wu, Y., Chen, H., Shi, Y., Liu, M., & Dong, W. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.09.002 · Cited by 113 · see citing works
Yang, P., Ji, Y., Lu, J., & Huang, Q. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.8b06967 · Cited by 104 · see citing works
Li, Y., Zhang, J.-J., Li, Y., Chen, J., & Du, W.-Y. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.131336 · Cited by 98 · see citing works
Patidar, R., & Srivastava, V. C. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.125736 · Cited by 96 · see citing works
Kinetics of uncatalyzed peroxydisulfate oxidation of organic material in fresh water
Goulden, P. D., & Anthony, D. H. J. (1978) · Analytical Chemistry · doi:10.1021/ac50029a032 · Cited by 94 · see citing works
Sun, Y., Zhao, J. W., Zhang, B., Li, J., Shi, Y., & Zhang, Y. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.02.208 · Cited by 94 · see citing works
Investigation of iohexol degradation kinetics by using heat-activated persulfate
Hu, C., Hou, Y.-Z., Lin, Y., et al. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.122403 · Cited by 94 · see citing works
Luo, C., Wu, D., Gan, L., Cheng, X., Ma, Q., Tan, F., Gao, J., Zhou, W., Wang, S., Zhang, F., et al. (2020) · Separation and Purification Technology · doi:10.1016/j.seppur.2020.116839 · Cited by 91 · see citing works
Shuchi, S. B., Suhan, M. B. K., Humayun, S. B., et al. (2020) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2020.101690 · Cited by 87 · see citing works
García-Cervilla, R., Santos, A., Romero, A., et al. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.124646 · Cited by 85 · see citing works
Ahmadi, S., Igwegbe, C. A., & Rahdar, S. (2019) · International Journal of Industrial Chemistry · doi:10.1007/s40090-019-0188-1 · Cited by 79 · see citing works
Ioannidi, A., Arvaniti, O. S., Nika, M.-C., Aalizadeh, R., Thomaidis, N. S., Mantzavinos, D., & Frontistis, Z. (2022) · Chemosphere · doi:10.1016/j.chemosphere.2021.131952 · Cited by 75 · see citing works
Ren, W., Huang, X., Wang, L., Liu, X., Zhou, Z., Wang, Y., Lin, C., He, M., & Ouyang, W. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.131876 · Cited by 75 · see citing works
Lebik-Elhadi, H., Frontistis, Z., Ait-Amar, H., Madjene, F., & Mantzavinos, D. (2020) · Process Safety and Environmental Protection · doi:10.1016/j.psep.2019.11.041 · Cited by 71 · see citing works
Yabalak, E. (2021) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2021.105201 · Cited by 66 · see citing works
Rayaroth, M. P., Aravind, U. K., & Aravindakumar, C. T. (2018) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2018.07.009 · Cited by 62 · see citing works
Self-citationWang, Z., Shao, Y., Gao, N., Lu, X. J., & An, N. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.11.075 · Cited by 62 · see citing works
Domínguez, C. M., Romero, A., Lorenzo, D., & Santos, A. (2020) · Journal of Environmental Management · doi:10.1016/j.jenvman.2020.110240 · Cited by 62 · see citing works
Zhou, T., Du, J., Wang, Z., Xiao, G., Luo, L., Faheem, M., Ling, H., & Bao, J. (2021) · Chemical Engineering Journal Advances · doi:10.1016/j.ceja.2021.100200 · Cited by 61 · see citing works
Shojaei, M., Kumar, N., Chaobol, S., Wu, K., Crimi, M. L., & Guelfo, J. L. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.0c08069 · Cited by 56 · see citing works
Duan, X., Indrawirawan, S., Kang, J., Tian, W., Zhang, H., Duan, X., Zhou, X., Sun, H., & Wang, S. (2020) · Catalysis Today · doi:10.1016/j.cattod.2019.02.051 · Cited by 55 · see citing works
Domínguez, C. M., Checa-Fernández, A., Romero, A., & Santos, A. (2021) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2021.105668 · Cited by 51 · see citing works
Liu, L., Yang, C., Tan, W., et al. (2020) · ACS Omega · doi:10.1021/acsomega.0c00903 · Cited by 50 · see citing works
Ji, Y., Shi, Y., Kong, D., & Lu, J. (2016) · RSC Advances · doi:10.1039/c6ra17764f · Cited by 47 · see citing works
Manz, K. E., Adams, T. J., & Carter, K. E. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.07.142 · Cited by 47 · see citing works
Rayaroth, M. P., Oh, D., Lee, C.-S., Kang, Y.-G., & Chang, Y. (2020) · Chemosphere · doi:10.1016/j.chemosphere.2020.127117 · Cited by 47 · see citing works
Self-citationCheca-Fernández, A., Santos, A., Romero, A., et al. (2021) · Separation and Purification Technology · doi:10.1016/j.seppur.2021.118795 · Cited by 42 · see citing works
Recent Developments in Advanced Oxidation Processes for Organics-Polluted Soil Reclamation
Calenciuc, C., Fdez-Sanromán, A., Lama, G., Annamalai, S., Sanromán, M. Á., & Pazos, M. M. (2022) · Catalysts · doi:10.3390/catal12010064 · Cited by 41 · see citing works
Yabalak, E., & Elneccar, F. (2021) · Journal of Environmental Management · doi:10.1016/j.jenvman.2021.114311 · Cited by 36 · see citing works
Wang, Z., Shao, Y., Gao, N., et al. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.122660 · Cited by 33 · see citing works
Soltani, R. D. C., Mahmoudi, M., Boczkaj, G., & Khataee, A. (2020) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2020.08.006 · Cited by 33 · see citing works
Self-citationCan‐Güven, E., Güvenç, S. Y., & Varank, G. (2021) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2021.102202 · Cited by 33 · see citing works
Kinetic oxidation of antipyrine in heat-activated persulfate
Tan, C., Gao, N., Deng, Y., et al. (2013) · Desalination and Water Treatment · doi:10.1080/19443994.2013.848414 · Cited by 32 · see citing works
Gao, Y.-Q., Fang, J.-N., Gao, N., Yi, X., Mao, W., & Zhang, J. (2018) · RSC Advances · doi:10.1039/c8ra08488b · Cited by 27 · see citing works
Yabalak, E., Özay, Y., Vatanpour, V., & Dızge, N. (2021) · Water and Environment Journal · doi:10.1111/wej.12718 · Cited by 25 · see citing works
Preethi, Banu, J. R., Sharmila, V. G., et al. (2021) · Bioresource Technology · doi:10.1016/j.biortech.2021.125810 · Cited by 24 · see citing works
Heat-Activated Persulfate Oxidation of Chlorinated Solvents in Sandy Soil
Liu, J., Gong, X., Song, S., Zhang, F., & Lü, C. (2014) · Journal of Spectroscopy · doi:10.1155/2014/578638 · Cited by 14 · see citing works
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Honarmandrad, Z., Sun, X., Wang, Z., Naushad, M., & Boczkaj, G. (2023) · Water Resources and Industry · doi:10.1016/j.wri.2022.100194 · Cited by 369 · see citing works
Self-citationRayaroth, M. P., Boczkaj, G., Aubry, O., Aravind, U. K., & Aravindakumar, C. T. (2023) · Water · doi:10.3390/w15081615 · Cited by 171 · see citing works
“A similar effect is reported for other pharmaceuticals, such as simazine, losartan, carba-mazepine, thiamethoxam, etc., [116–120].”
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- Authors
- Sonawane, S., Rayaroth, M. P., Landge, V. K., Fedorov, K., & Boczkaj, G.
- Affiliations
- National Institute of Technology Warangal (IN)
- Gdańsk University of Technology (PL)
- Corresponding author
- Sonawane, Shirish
- Boczkaj, Grzegorz
- Venue
- Current Opinion in Chemical Engineering
- Publisher
- Elsevier BV
- Published
- 2022-09
- Volume
- 37
- Pages
- 100839
- ISSN
- 2211-3398 (ISSN-L)
- OpenAlex
- W4281671599
- Cited by
- 91
- References
- 76
- Citations by year
- 2026: 16 · 2025: 29 · 2024: 24 · 2023: 15 · 2022: 7
- FWCI
- 1.13
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Current Opinion in Chemical Engineering (publishedVersion, cc-by)
- Funders
- Narodowe Centrum Nauki (UMO-2017/25/B/ST8/01364)
- Narodowa Agencja Wymiany Akademickiej (PPN/ULM/2020/1/00037/U/00001)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- thermally activated persulfate, advanced oxidation processes, mineralization, persistent organic chemicals, pharmaceuticals, biocides, dyes, environmental remediation, contaminated water, contaminated soil, first-order kinetics, operating conditions, temperature reduction
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