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Role of chemical activation in the development of carbon porosity
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“A redox reaction has taken place during KOH activation, where the carbon is oxidized to CO or CO2, thus generating pores [59].”
From Preparation of Microporous Carbon from Sargassum horneri by Hydrothermal Carbonization and KOH Activation for CO2 Capture (2018) · cites this paper as [59]
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Self-citationChar Products From Bamboo Waste Pyrolysis and Acid Activation
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Toward sustainable hydrogen storage and carbon dioxide capture in post-combustion conditions
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Parabens Adsorption onto Activated Carbon: Relation with Chemical and Structural Properties
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“This confirms that the reagent used in the impregnation is used as a template for the creation of porosity [24].”
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Ferromagnetism at room temperature in activated graphene oxide
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“The activation process typically occurs via crosslinking, dehydration, exfoliation, or gasification of the precursor matrix depending on the type of activation agent [73].”
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Chemical activations of herringbone-type nanofibers
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A Non-Conventional Adsorbent for the Removal of Clofibric Acid from Aqueous Phase
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“Chemical activation reduces tar formation and increases carbon yield (24, 25).”
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“Among the electrode materials, porous carbon materials were the first to be studied and the most mature for technical application [1,2].”
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HIERARCHICAL POROUS MATERIALS: CAPILLARIES IN NANOPOROUS CARBON
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“Before the process, raw materials are initially impregnated with an acid/oxidizing agent and further dehydrating chemicals, which activate pyrolytic degradation, improve the activated carbon yield, while causing changes in the thermal precursor’s decomposition, giving rise to the formation of porous carbon materials […”
BackgroundCatalytic upgrading of ex-situ heavy coal tar over modified activated carbon
Xia, M., Zhu, J., Wei, B., Hu, H., & Jin, L. (2021) · Fuel · doi:10.1016/j.fuel.2021.122912 · Cited by 22
Towards the new generation of courtyard buildings as a healthy living concept for post-pandemic era
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Sustainability of microporous polymers and their applications
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Oxidation of Different Microporous Carbons by Chemical and Electrochemical Methods
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Application of pervious alkali-activated slag concrete to adsorb runoff contaminants
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KOLUR, N. A., & Kaghazchi, T. (2012) · Adsorption · doi:10.1007/s10450-012-9437-8 · Cited by 21
“4 Time dependence of mercury adsorption capacity of AC (- -•- -) and AC-S (— —) Molina-Sabio and Rodríguez-Reinoso 2004), it is probable that in the process of AC-S production, the trapped sulfur, filling some space and narrowing the produced mesoporosity, facilitates the converting of large micro-…”
BackgroundSynthesis of dimethyl carbonate over starch-based Carbon-supported Cu nanoparticles catalysts
Ren, J., Guo, C., Yang, L., & Li, Z. (2013) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(12)60640-8 · Cited by 21
The effect of wetting on pore texture and methane storage ability of NaOH activated anthracite
Celzard, A., Perrin, A., Albiniak, A., Broniek, E., & Mareche, J. F. (2006) · Fuel · doi:10.1016/j.fuel.2006.05.033 · Cited by 21
Ranguin, R., Durimel, A., Karioua, R., & Gaspard, S. (2017) · Environmental Science and Pollution Research · doi:10.1007/s11356-017-9542-z · Cited by 21
“Chemical activation using phosphoric acid (H3PO4) 85% is realized for 24 h under various impregnation XP (mass phosphoric acid/precursor mass) 0.5:1, 1:1, and 1.5:1 (Durimel et al. 2013; Baquero et al. 2003; Díaz-Díez et al. 2004; Molina-Sabio and Rodríguez-Reinoso 2004).”
MethodInfluentialExhaust characteristics during the pyrolysis of ZnCl2 immersed biosludge
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Subha, R., & Namasivayam, C. (2010) · Bioremediation Journal · doi:10.1080/10889860903455360 · Cited by 21
Lu, X., Jiang, J., Sun, K., & Xie, X. (2014) · Bulletin of the Korean Chemical Society · doi:10.5012/bkcs.2014.35.1.103 · Cited by 20
Characterization of carbon materials with the help of NMR methods
Kruteva, M., Grinberg, F., Furtado, F., Galvosas, P., Jörg Kärger, A., Silvestre‐Albero, A., Sepúlveda‐Escribano, A., Silvestre‐Albero, J., & Rodríguez-Reinoso, F. (2008) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2008.12.016 · Cited by 20
Self-citationKamaraj, M., Tareke, K., Gezehegn, M., Kebede, M., Yazie, A., & Diyana, G. (2019) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1007/s10904-019-01101-7 · Cited by 20
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Adsorption of organic compounds on activated carbons
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“Chemical activation is usually undertaken by pyrolysis of the carbon precursor and chemical agent, such as phosphoric acid, zinc chloride and alkaline hydroxide [3], at a lower pyrolysis temperature and with a shorter processing time than those in physical activation.”
MethodNemchi, F., Bestani, B., Benderdouche, N., Belhakem, M., & Duclaux, L. (2017) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2017.03.027 · Cited by 20
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“Researchers have modified biomass-derived CMs through functionalization [117], doping [118], activation [119], and metal-oxide impregnation [26] to improve their CO 2 adsorption capacities.”
Cesano, F., Cravanzola, S., Brunella, V., Damin, A., & Scarano, D. (2019) · Frontiers in Materials · doi:10.3389/fmats.2019.00084 · Cited by 19
“, 2018) and performing simple processes, such as chemical and thermal treatments (Molina-Sabio and Rodriguez-Reinoso, 2004; Zhang et al., 2010; Rosas et al., 2014).”
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“Pure microporous carbons or a mixture of micro- and mesoporous carbons can be obtained by varying the activating agent and the preparation conditions [14,15].”
BackgroundEnvironmental benefits of Agricultural Waste-Derived catalysts in diesel Desulfurization: A review
Mohammed, A. E., Mohammed, W. T., & Gheni, S. A. (2024) · Cleaner Materials · doi:10.1016/j.clema.2024.100262 · Cited by 19
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“S2a in the Supplementary Information) exhibit a macroporous texture, which could be assigned both to the high production of gas during KOH activation process and the structure of the starting biomass precursor [35, 50, 51].”
BackgroundFoam and granular olive stone-derived activated carbons for NO2 filtration from indoor air
Bader, N., Sager, U., Schneiderwind, U., & Ouederni, A. (2019) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2019.103005 · Cited by 19
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Activated coconut shell charcoal carbon using chemical-physical activation
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“When ZnCl2 is used the activated carbon obtained has larger surface area and greater micro pore structure [24, 25].”
BackgroundLi, J., Li, J., Lai, Y., Song, H., Zhang, Z., & Liu, Y. (2006) · Journal of Central South University of Technology · doi:10.1007/s11771-006-0049-x · Cited by 18
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“indicates the micropore filling and monolayer adsorption phase [49].”
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A Review of Recent Advances in Biomass-Derived Porous Carbon Materials for CO2 Capture
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“With an equivalent loading of H3PO4 only, one would expect purely microporous samples as demonstrated by the work of Molina-Sabio and Rodríguez-Reinoso [22].”
BackgroundResultInfluentialEnhanced interfacial interaction of epoxy nanocomposites with activated graphene nanosheets
Deng, H., Wu, F., Chen, L., Xu, Z., Liu, L., Yang, C., Mai, W., & Cheng, B. (2014) · Journal of Applied Polymer Science · doi:10.1002/app.41164 · Cited by 16
Radwan, E. K., El‐Wakeel, S. T., & Gad‐Allah, T. A. (2018) · Journal of Dispersion Science and Technology · doi:10.1080/01932691.2018.1467327 · Cited by 16
“Noteworthy that, chemical activation by H3PO4 produces ACs of significantly higher surface area than those produced by KOH, which is consistent with the literature.([40,41]) Consequently, H3PO4 will be selected for investigating other parameters that affect the activation process.”
ResultEffect of Coffee Grounds/Coffee Ground Biochar on Cement Hydration and Adsorption Properties
Chen, Y., Guo, R., Ma, F., Zhou, H., Zhang, M., & Ma, Q. (2024) · Materials · doi:10.3390/ma17040907 · Cited by 15
“This further augments CGB’s adsorption capacity [4].”
BackgroundInfluentialBhattarai, D. P., Aryal, S., Mishra, P. K., Shrestha, T., Homagai, P. L., Oli, H. B., & Shrestha, R. L. (2025) · Carbon Trends · doi:10.1016/j.cartre.2025.100467 · Cited by 15
Padya, B., Kali, R., Enaganti, P. K., Narasaiah, N., & Jain, P. K. (2020) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2020.125587 · Cited by 15
Tochetto, G. A., da Silva, T. C., Bampi, J., Moreira, R. D. F. P. M., da Luz, C., Pasquali, G. D. L., & Dervanoski, A. (2022) · Water Air & Soil Pollution · doi:10.1007/s11270-022-05737-z · Cited by 17
Chimi, T., Hannah, B. U., Lincold, N. M., Jacques, M. B., Tomé, S., Dzoujo, H. T., Shikuku, V. O., Bissoué, A. N., Tchieta, G. P., & Meva, F. E. (2022) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-022-02675-9 · Cited by 15
Hirunpraditkoon, S., Srinophakun, P., Sombun, N., & Moore, E. J. (2014) · Chemical Engineering Communications · doi:10.1080/00986445.2013.828611 · Cited by 15
Carbon Materials for Supercapacitors
Zhou, W., Liu, X., Zhou, K., & Jia, J. F. (2016) · Nanostructure science and technology · doi:10.1007/978-3-319-26082-2_8 · Cited by 15
Guo, F., Peng, K., Zhao, X., Jiang, X., Lin, Q., Guo, C., & Rao, Z. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.10.013 · Cited by 15
Comparison of by-product gas composition by activations of activated carbon
Lee, G. B., Park, J. E., Hwang, S. Y., Kim, J. H., Kim, S., Kim, H., & Hong, B. U. (2019) · Carbon letters · doi:10.1007/s42823-019-00030-2 · Cited by 15
Kenyota, N., Jarernboon, W., & Laokul, P. (2023) · Materials Science and Engineering B · doi:10.1016/j.mseb.2023.116293 · Cited by 14
Bougainvillea flower-biochar for zinc-ion hybrid super-capacitor: role of chemical activator
Gautam, M., Patodia, T., Sachdev, K., & Kushwaha, H. S. (2024) · Biomass Conversion and Biorefinery · doi:10.1007/s13399-024-05547-9 · Cited by 14
“During activation, the carbon surface may interact with oxidizing reagent solutions, such as KOH and H 3 PO 4 , to add surface-generated oxygen functional groups to the carbon [17].”
Metadata
- Authors
- Molina-Sabio, M., & Rodrı́guez-Reinoso, F.
- Venue
- Colloids and Surfaces A: Physicochemical and Engineering Aspects
- Publisher
- Elsevier BV
- Published
- 2004-07
- Volume
- 241
- Issue
- 1-3
- Pages
- 15-25
- ISSN
- 0927-7757 (ISSN-L)
- OpenAlex
- W2020304143
- Cited by
- 663
- References
- 42
- Citations by year
- 2026: 36 · 2025: 36 · 2024: 24 · 2023: 36 · 2022: 54 · 2021: 50 · 2020: 36 · 2019: 41 · 2018: 33 · 2017: 38 · 2016: 33 · 2015: 28 · 2014: 27 · 2013: 34 · 2012: 23
- FWCI
- 38.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Colloids and Surfaces A Physicochemical and Engineering Aspects (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Adsorption, diffusion, and thermodynamic properties of materials
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Keywords
- chemical activation, carbon porosity, granular activated carbon, lignocellulosic precursors, olive stones, peach stones, phosphoric acid, zinc chloride, potassium hydroxide, microporosity, mesoporosity, pore size distribution, impregnation ratio, methane adsorption
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