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Role of chemical activation in the development of carbon porosity
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“A redox reaction has taken place during KOH activation, where the carbon is oxidized to CO or CO2, thus generating pores [59].”
From Preparation of Microporous Carbon from Sargassum horneri by Hydrothermal Carbonization and KOH Activation for CO2 Capture (2018) · cites this paper as [59]
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“The other step (activation method) is usually carried out to enhance the diameters of the small pores by increasing the area and also to generate new pores [86,102].”
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“Lignocellulosic materials such as olive and peach stones have been also used as precursors for granular activated carbon, using phosphoric acid, zinc chloride and potassium hydroxide as activating agents [12].”
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“While in the use of K2CO3, KOH, and ZnCl2 the activated carbons had large surface areas and greater micropore structure [16-19], in the use of H3PO4 as a chemical activating agent, the pore size distributions were more heterogeneous for the activated carbons obtained from olive and peach stones as precursors [20].”
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“A large number of studies in the literature focused on the correlation between porosity development and activation process parameters including: activating reagent type [6,9]; mass ratio of activating reagent to substrate [5,7,10,11]; carbonization temperature [5,7,8,12]; flow rate of inert gas during carbonization [5…”
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“…activation is a commonly used method for the generation of AC based on the degradation/dehydration of the raw material, carbonization/aromatization of the carbonaceous skeleton, and the removal of tar from the biomass material to facilitate the development of the porous structure [78,93,111,112].”
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“With excessive impregnation with H3PO4, it might form an insulating layer which inhibits the activation process [27].”
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Metadata
- Authors
- Molina-Sabio, M., & Rodrı́guez-Reinoso, F.
- Venue
- Colloids and Surfaces A: Physicochemical and Engineering Aspects
- Publisher
- Elsevier BV
- Published
- 2004-07
- Volume
- 241
- Issue
- 1-3
- Pages
- 15-25
- ISSN
- 0927-7757 (ISSN-L)
- OpenAlex
- W2020304143
- Cited by
- 663
- References
- 42
- Citations by year
- 2026: 36 · 2025: 36 · 2024: 24 · 2023: 36 · 2022: 54 · 2021: 50 · 2020: 36 · 2019: 41 · 2018: 33 · 2017: 38 · 2016: 33 · 2015: 28 · 2014: 27 · 2013: 34 · 2012: 23
- FWCI
- 38.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Colloids and Surfaces A Physicochemical and Engineering Aspects (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Adsorption, diffusion, and thermodynamic properties of materials
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Keywords
- chemical activation, carbon porosity, granular activated carbon, lignocellulosic precursors, olive stones, peach stones, phosphoric acid, zinc chloride, potassium hydroxide, microporosity, mesoporosity, pore size distribution, impregnation ratio, methane adsorption
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