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Preparation of self-healing, recyclable epoxy resins and low-electrical resistance composites based on double-disulfide bond exchange

Zhou, Fengtao, Guo, Zijian, Wang, Wenyan, Lei, Xingfeng, Zhang, Baoliang, Zhang, Hepeng, Zhang, Qiuyu·2018·Composites Science and Technology

Abstract

Abstract Vitrimers have been emerged as a new class of polymers with many attractive properties of material processing such as reshaping, recycling and repairing. Herein, a new type of vitrimers (BDSER) based on thermosetting dynamic epoxy network with double disulfide bonds was synthesized by the reaction of a difunctional epoxy monomer containing disulfide bonds with 4,4′-disulfanediyldianiline (4-AFD). Our results demonstrated that the relaxation time of BDSER at 200 °C was as short as 9 s without any catalyst. The storage modulus of BDSER was up to about 2.2 GPa and its glass transition temperature was higher than 130 °C. Additionally, the thermodynamic and chemical properties of BDSER were no significant loss after 3 cycles of continuous breaking/compression molding. Furthermore, the resistance of CNT/PPy/Vitrimer composites (CPV), synthesized by doped BDSER with the polypyrrole (PPy) decorated multi-walled carbon nanotubes (WMCNTs), was decreased to 109 Ω even the mass ratio was only 1%wt, which could be used a promising candidate as self-repairing materials in the field of antistatic.

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Metadata

Authors
Zhou, F., Guo, Z., Wang, W., Lei, X., Zhang, B., Zhang, H., & Zhang, Q.
Venue
Composites Science and Technology
Publisher
Elsevier BV
Published
2018-10
Volume
167
Pages
79-85
ISSN
0266-3538 (ISSN-L)
OpenAlex
W2885671253
Cited by
225
References
4
FWCI
7.66
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Preparation of self-healing, recyclable epoxy resins and low-electrical resistance composites based on double-disulfide bond exchange. https://app.cochat.ai/papers/10.1016/j.compscitech.2018.07.041
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Zhou, F., Guo, Z., Wang, W., Lei, X., Zhang, B., Zhang, H., & Zhang, Q. (2018). Preparation of self-healing, recyclable epoxy resins and low-electrical resistance composites based on double-disulfide bond exchange. Composites Science and Technology. https://doi.org/10.1016/j.compscitech.2018.07.041

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