Making Insoluble Polymer Networks Malleable via Olefin Metathesis
Abstract
Covalently cross-linked polymers have many technological applications for their excellent properties, but they suffer from the lack of processability and adaptive properties. We report a simple, efficient method of generating adaptive cross-linked polymers via olefin metathesis. By introducing a very low level of the Grubbs' second-generation Ru metathesis catalyst, a chemically cross-linked polybutadiene network becomes malleable at room temperature while retaining its insolubility. The stress relaxation capability increases with increasing level of catalyst loading. In sharp contrast, catalyst-free control samples with identical network topology and cross-linking density do not show any adaptive properties. This chemistry should offer a possibility to combine the dimensional stability and solvent resistance of cross-linked polymers and the processability/adaptibility of thermoplastics.
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- Authors
- Lu, Y.-X., Tournilhac, F., Leibler, L., & Guan, Z.
- Affiliations
- Department of Chemistry, University of California, Irvine, California 92697, United States
- Centre National de la Recherche Scientifique (FR)
- Matière Molle et Chimie, ESPCI-CNRS, 75005 Paris, France
- University of California, Irvine (US)
- Corresponding author
- Guan, Zhibin
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-05-11
- Volume
- 134
- Issue
- 20
- Pages
- 8424-8427
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2321324100
- Cited by
- 568
- References
- 34
- Citations by year
- 2026: 20 · 2025: 37 · 2024: 48 · 2023: 40 · 2022: 66 · 2021: 66 · 2020: 63 · 2019: 57 · 2018: 53 · 2017: 37 · 2016: 32 · 2015: 21 · 2014: 12 · 2013: 14 · 2012: 2
- FWCI
- 7.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Synthetic Organic Chemistry Methods
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- olefin metathesis, Grubbs second-generation catalyst, stress relaxation, catalyst loading, solvent resistance, dimensional stability
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