Electrochemical reduction of high pressure CO2 at a Cu electrode in cold methanol
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Larger cations Cs+ and K+ can greatly increase the total current density in CO2RR.
“Studies have demonstrated that larger cations, Cs + and K + , can greatly increase the total current density, [209,210]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [209]
Larger, less hydrated cations adsorb easier on the catalyst surface, making the potential at the outer Helmholtz plane more positive and thereby reducing the concentration of H+ ions and impeding the formation of H2 and CH4.
“The larger, less hydrated, cations adsorb easier on the catalyst surface making the potential at the outer Helmholtz plane more positive and thereby reducing the concentration of H + ions and impeding the formation of H2 and CH4.[205,209,211,212,214]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [209]
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Self-citation
- Authors
- Kaneco, S., Iiba, K., Katsumata, H., Suzuki, T., & Ohta, K.
- Affiliations
- Mie University (JP)
- Corresponding author
- Kaneco, Satoshi
- Venue
- Electrochimica Acta
- Publisher
- Elsevier BV
- Published
- 2006-06
- Volume
- 51
- Issue
- 23
- Pages
- 4880-4885
- ISSN
- 0013-4686 (ISSN-L)
- OpenAlex
- W2056052058
- Cited by
- 74
- References
- 25
- Citations by year
- 2026: 4 · 2025: 3 · 2024: 3 · 2023: 5 · 2022: 6 · 2021: 6 · 2020: 5 · 2019: 4 · 2018: 2 · 2016: 3 · 2015: 6 · 2014: 8 · 2013: 4 · 2012: 2
- FWCI
- 2.07
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Electrochimica Acta (publishedVersion)
- Funders
- Ministry of Education
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- electrochemical CO2 reduction, high-pressure CO2, copper electrode, low-temperature electrolysis, methane production, ethylene, carbon monoxide, formic acid, current efficiency, hydrogen evolution suppression, Rectisol process, fuel gas production
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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