Electrochemical CO2 Reduction: Recent Advances and Current Trends
Abstract
With rising levels of CO 2 in our atmosphere, technologies capable of converting CO 2 into useful products have become more valuable. The field of electrochemical CO 2 reduction is reviewed here, with sections on mechanism, formate (formic acid) production, carbon monoxide production, reduction to higher products (methanol, methane, etc.), use of flow cells, high pressure approaches, molecular catalysts, non‐aqueous electrolytes, and solid oxide electrolysis cells. These diverse approaches to electrochemical CO 2 reduction are compared and contrasted, emphasizing potential processes that would be feasible for large‐scale use. Although the focus is on recent reports, highlights of older reports are also included due to their important contributions to the field, particularly for high‐rate electrolysis.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Larger cations Cs+ and K+ can improve selectivity towards multi-carbon products, especially C2H4.
“and improve selectivity towards multi-carbon products, especially C2H4.[212,213]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [212]
Cites
A comprehensive review on PEM water electrolysis
Carmo, M., Fritz, D., Mergel, J., & Stolten, D. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.01.151 · Cited by 5,588 · see citing works
(2012) · The Scientific World JOURNAL · doi:10.1100/tswj · Cited by 2,600 · see citing works
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140 · see citing works
Electrochemical CO2 Reduction on Metal Electrodes
Hori, Y. (2008) · Springer eBooks · doi:10.1007/978-0-387-49489-0_3 · Cited by 1,904 · see citing works
Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,661 · see citing works
Olah, G. A., Goeppert, A., & Prakash, G. K. S. (2008) · The Journal of Organic Chemistry · doi:10.1021/jo801260f · Cited by 1,609 · see citing works
Self-citationIonic Liquid–Mediated Selective Conversion of CO <sub>2</sub> to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558 · see citing works
Ormerod, R. M. (2002) · Chemical Society Reviews · doi:10.1039/b105764m · Cited by 1,535 · see citing works
A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,499 · see citing works
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO
Zhu, W., Michalsky, R., Metin, Ö., Lv, H., Guo, S., Wright, C. J., Sun, X., Peterson, A. A., & Sun, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409445p · Cited by 1,379 · see citing works
Anthropogenic Chemical Carbon Cycle for a Sustainable Future
Olah, G. A., Prakash, G. K. S., & Goeppert, A. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202642y · Cited by 1,378 · see citing works
Self-citationA Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst
Costentin, C., Drouet, S., Robert, M., & Savéant, J. (2012) · Science · doi:10.1126/science.1224581 · Cited by 1,319 · see citing works
Chen, Y., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2108799 · Cited by 982 · see citing works
Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation
DuBois, M. R., & DuBois, D. L. (2009) · Accounts of Chemical Research · doi:10.1021/ar900110c · Cited by 823 · see citing works
Electrochemical Reduction of CO at a Copper Electrode
Hori, Y., Takahashi, R., Yoshinami, Y., & Murata, A. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp970284i · Cited by 818 · see citing works
Beyond Oil and Gas: The Methanol Economy
Olah, G. A., Goeppert, A., & Prakash, G. K. S. (2009) · Wiley eBooks · doi:10.1002/9783527627806 · Cited by 792 · see citing works
Self-citationBarton, E. E., Rampulla, D. M., & Bocarsly, A. B. (2008) · Journal of the American Chemical Society · doi:10.1021/ja0776327 · Cited by 729 · see citing works
Hori, Y., Takahashi, I., Koga, O., & Hoshi, N. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp013478d · Cited by 679 · see citing works
Bourrez, M., Molton, F., Chardon‐Noblat, S., & Deronzier, A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103616 · Cited by 591 · see citing works
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
Fisher, B. J., & Eisenberg, R. (1980) · Journal of the American Chemical Society · doi:10.1021/ja00544a035 · Cited by 560 · see citing works
Gupta, N., Gattrell, M., & MacDougall, B. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-005-9058-y · Cited by 558 · see citing works
Cole, E. B., Lakkaraju, P. S., Rampulla, D. M., Morris, A. J., Abelev, E., & Bocarsly, A. B. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1023496 · Cited by 557 · see citing works
Structure effects on the energetics of the electrochemical reduction of CO2 by copper surfaces
Durand, W. J., Peterson, A. A., Studt, F., Abild‐Pedersen, F., & Nørskov, J. K. (2011) · Surface Science · doi:10.1016/j.susc.2011.04.028 · Cited by 552 · see citing works
Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces
Le, M., Ren, M.-Y., Zhang, Z., Sprunger, P. T., Kurtz, R. L., & Flake, J. C. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3561636 · Cited by 489 · see citing works
Kauffman, D. R., Alfonso, D. R., Matranga, C., Qian, H., & Jin, R. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303259q · Cited by 450 · see citing works
Delacourt, C., Ridgway, P. L., Kerr, J. B., & Newman, J. (2008) · Journal of The Electrochemical Society · doi:10.1149/1.2801871 · Cited by 442 · see citing works
Kazarian, S. G., Briscoe, B. J., & Welton, T. (2000) · Chemical Communications · doi:10.1039/b005514j · Cited by 433 · see citing works
“Deactivation of copper electrode” in electrochemical reduction of CO2
Hori, Y., Konishi, H., Futamura, T., Murata, A., Koga, O., Sakurai, H., & Oguma, K. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2005.03.015 · Cited by 432 · see citing works
High‐Yield Electrochemical Production of Formaldehyde from CO2 and Seawater
Nakata, K., Ozaki, T., Terashima, C., Fujishima, A., & Einaga, Y. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201308657 · Cited by 410 · see citing works
DiMeglio, J. L., & Rosenthal, J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4033549 · Cited by 386 · see citing works
Microfluidic Reactor for the Electrochemical Reduction of Carbon Dioxide: The Effect of pH
Whipple, D. T., Finke, E. C., & Kenis, P. J. A. (2010) · Electrochemical and Solid-State Letters · doi:10.1149/1.3456590 · Cited by 375 · see citing works
DeWulf, D. W., Jin, T., & Bard, A. J. (1989) · Journal of The Electrochemical Society · doi:10.1149/1.2096993 · Cited by 372 · see citing works
Ikeda, S., Takagi, T., & Ito, K. (1987) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.60.2517 · Cited by 371 · see citing works
Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single Crystals
Schouten, K. J. P., Gallent, E. P., & Koper, M. T. M. (2013) · ACS Catalysis · doi:10.1021/cs4002404 · Cited by 367 · see citing works
Kang, P., Chen, C., Chen, Z., Schauer, C. K., Meyer, T. J., & Brookhart, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja300543s · Cited by 330 · see citing works
Hara, K., Kudo, A., & Sakata, T. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)03935-a · Cited by 317 · see citing works
Homogeneous CO2 Reduction by Ni(cyclam) at a Glassy Carbon Electrode
Froehlich, J. D., & Kubiak, C. P. (2012) · Inorganic Chemistry · doi:10.1021/ic3001619 · Cited by 310 · see citing works
Electrochemical reduction of CO2 on single crystal electrodes of silver Ag(111), Ag(100) and Ag(110)
Hoshi, N., Kato, M., & Hori, Y. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(97)00447-6 · Cited by 304 · see citing works
Electrochemical Processing of Carbon Dioxide
Oloman, C. W., & Li, H. (2008) · ChemSusChem · doi:10.1002/cssc.200800015 · Cited by 288 · see citing works
Lamy, E., Nadjo, L., & Savéant, J. (1977) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(77)80143-5 · Cited by 284 · see citing works
Hori, Y., Murata, A., Kikuchi, K., & Suzuki, S. (1987) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39870000728 · Cited by 282 · see citing works
Costentin, C., Drouet, S., Passard, G., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4030148 · Cited by 279 · see citing works
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1995) · Surface Science · doi:10.1016/0039-6028(95)00441-6 · Cited by 276 · see citing works
Seshadri, G., Lin, C., & Bocarsly, A. B. (1994) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(94)03300-5 · Cited by 262 · see citing works
Syngas Production By Coelectrolysis of CO2/H2O: The Basis for a Renewable Energy Cycle
Zhan, Z., Kobsiriphat, W., Wilson, J. R., Pillai, M. R., Kim, I., & Barnett, S. A. (2009) · Energy & Fuels · doi:10.1021/ef900111f · Cited by 260 · see citing works
Ghadimkhani, G., de Tacconi, N. R., Chanmanee, W., Janáky, C., & Rajeshwar, K. (2012) · Chemical Communications · doi:10.1039/c2cc38068d · Cited by 257 · see citing works
Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes
Chen, Z., Chen, C., Weinberg, D. R., Kang, P., Concepcion, J. J., Harrison, D. P., Brookhart, M., & Meyer, T. J. (2011) · Chemical Communications · doi:10.1039/c1cc15071e · Cited by 238 · see citing works
Kita, H. (1966) · Journal of The Electrochemical Society · doi:10.1149/1.2423772 · Cited by 237 · see citing works
Jia, F., Yu, X., & Zhang, L. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.12.002 · Cited by 228 · see citing works
Silver Supported on Titania as an Active Catalyst for Electrochemical Carbon Dioxide Reduction
Ma, S., Lan, Y., Perez, G. M. J., Moniri, S., & Kenis, P. J. A. (2014) · ChemSusChem · doi:10.1002/cssc.201300934 · Cited by 222 · see citing works
Electrochemical reduction of CO2 on RuO2/TiO2 nanotubes composite modified Pt electrode
Jian-ping, Q., Zhang, X., Wang, Y., & Xie, C. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2004.11.061 · Cited by 213 · see citing works
Takahashi, I., Koga, O., Hoshi, N., & Hori, Y. (2002) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(02)01081-1 · Cited by 212 · see citing works
Electrochemical reduction of CO2 on platinum electrodes in acid solutions
Giner, J. (1963) · Electrochimica Acta · doi:10.1016/0013-4686(63)80054-7 · Cited by 197 · see citing works
Electrocatalytic conversion of CO2 to long carbon-chain hydrocarbons
Centi, G., Perathoner, S., Win, G., & Gangeri, M. (2007) · Green Chemistry · doi:10.1039/b615275a · Cited by 197 · see citing works
Yao, S. A., Ruther, R. E., Zhang, L., Franking, R. A., Hamers, R. J., & Berry, J. F. (2012) · Journal of the American Chemical Society · doi:10.1021/ja304783j · Cited by 197 · see citing works
Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO
Schneider, J. D., Jia, H., Kobiro, K., Cabelli, D. E., Muckerman, J. T., & Fujita, E. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22528j · Cited by 195 · see citing works
Syngas Production via High-Temperature Coelectrolysis of Steam and Carbon Dioxide
Stoots, C. M., O’Brien, J. E., Herring, J. S., & Hartvigsen, J. (2008) · Journal of Electrochemical Energy Conversion and Storage · doi:10.1115/1.2971061 · Cited by 194 · see citing works
Co-Electrolysis of Steam and Carbon Dioxide in Solid Oxide Cells
Ebbesen, S. D., Knibbe, R., & Mogensen, M. B. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.076208jes · Cited by 194 · see citing works
Kinetic studies of the electrolytic reduction of carbon dioxide on the mercury electrode
Paik, W., Andersen, T. N., & Eyring, H. B. (1969) · Electrochimica Acta · doi:10.1016/0013-4686(69)87019-2 · Cited by 192 · see citing works
Nitrogen-Based Catalysts for the Electrochemical Reduction of CO <sub>2</sub> to CO
Tornow, C. E., Thorson, M. R., Ma, S., Gewirth, A. A., & Kenis, P. J. A. (2012) · Journal of the American Chemical Society · doi:10.1021/ja308217w · Cited by 190 · see citing works
Electro-reduction of carbon dioxide to formate on lead electrode in aqueous medium
Innocent, B., Liaigre, D., Pasquier, D., Ropital, F., ́GER, J.-M. L., & Kokoh, K. B. (2008) · Journal of Applied Electrochemistry · doi:10.1007/s10800-008-9658-4 · Cited by 187 · see citing works
An electrochemical model for syngas production by co-electrolysis of H2O and CO2
Ni, M. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2011.11.080 · Cited by 184 · see citing works
Todoroki, M., Hara, K., Kudo, A., & Sakata, T. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)04010-l · Cited by 178 · see citing works
Theoretical Insights into Pyridinium-Based Photoelectrocatalytic Reduction of CO2
Keith, J. A., & Carter, E. A. (2012) · Journal of the American Chemical Society · doi:10.1021/ja300128e · Cited by 174 · see citing works
Comparative study of solvent properties for carbon dioxide absorption
Aschenbrenner, O., & Styring, P. (2010) · Energy & Environmental Science · doi:10.1039/c002915g · Cited by 173 · see citing works
Electrochemical reduction of CO2 over Sn-Nafion® coated electrode for a fuel-cell-like device
Prakash, G. K. S., Viva, F. A., & Olah, G. A. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.09.036 · Cited by 172 · see citing works
Self-citationHara, K., Tsuneto, A., Kudo, A., & Sakata, T. (1994) · Journal of The Electrochemical Society · doi:10.1149/1.2055067 · Cited by 169 · see citing works
Lim, C., Holder, A. M., & Musgrave, C. B. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3064809 · Cited by 167 · see citing works
Smith, B. D., Irish, D. E., Kedzierzawski, P., & Augustyński, J. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1838180 · Cited by 162 · see citing works
Morris, A. J., McGibbon, R. T., & Bocarsly, A. B. (2011) · ChemSusChem · doi:10.1002/cssc.201000379 · Cited by 161 · see citing works
Kang, P., Meyer, T. J., & Brookhart, M. (2013) · Chemical Science · doi:10.1039/c3sc51339d · Cited by 160 · see citing works
Collomb, M., Deronzier, A., & Ziessel, R. (1994) · Inorganic Chemistry · doi:10.1021/ic00091a040 · Cited by 158 · see citing works
Mahmood, M. N., Masheder, D., & Harty, C. J. (1987) · Journal of Applied Electrochemistry · doi:10.1007/bf01023599 · Cited by 158 · see citing works
Grodkowski, J., Dhanasekaran, T., Neta, P., Hambright, P., Brunschwig, B. S., Shinozaki, K., & Fujita, E. (2000) · The Journal of Physical Chemistry A · doi:10.1021/jp002709y · Cited by 157 · see citing works
Yano, H., Tanaka, T., Nakayama, M., & Ogura, K. (2003) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2003.10.021 · Cited by 153 · see citing works
Köleli, F., Atilan, T., Palamut, N., Gizir, A. M., Aydın, R., & Hamann, C. H. (2003) · Journal of Applied Electrochemistry · doi:10.1023/a:1024471513136 · Cited by 152 · see citing works
Electrochemical Reduction of CO2 to CO Catalyzed by a Bimetallic Palladium Complex
Raebiger, J. W., Turner, J. W., Noll, B. C., Curtis, C. J., Miedaner, A., Cox, B., & DuBois, D. L. (2006) · Organometallics · doi:10.1021/om060228g · Cited by 152 · see citing works
Alternative Cathode Material for CO 2 Reduction by High Temperature Solid Oxide Electrolysis Cells
Yue, X., & Irvine, J. T. S. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.040208jes · Cited by 152 · see citing works
Li, H., & Oloman, C. W. (2007) · Journal of Applied Electrochemistry · doi:10.1007/s10800-007-9371-8 · Cited by 151 · see citing works
Hori, Y., Koga, O., Yamazaki, H., & Matsuo, T. (1995) · Electrochimica Acta · doi:10.1016/0013-4686(95)00239-b · Cited by 149 · see citing works
Leung, K., Nielsen, I. M. B., Sai, N., Medforth, C. J., & Shelnutt, J. A. (2010) · The Journal of Physical Chemistry A · doi:10.1021/jp1012335 · Cited by 147 · see citing works
The Electro-Reduction of Carbon Dioxide in a Continuous Reactor
Li, H., & Oloman, C. W. (2005) · Journal of Applied Electrochemistry · doi:10.1007/s10800-005-7173-4 · Cited by 147 · see citing works
Narayanan, S. R., Haines, B., Soler, J., & Valdez, T. I. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3526312 · Cited by 145 · see citing works
Reduction of Carbon Dioxide on Mercury Cathodes
Teeter, T. E., & Rysselberghe, P. V. (1954) · The Journal of Chemical Physics · doi:10.1063/1.1740178 · Cited by 138 · see citing works
Electrochemical reduction of CO2 in a proton conducting solid oxide electrolyser
Xie, K., Zhang, Y., Meng, G., et al. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm02205e · Cited by 130 · see citing works
Canfield, D., & Frese, K. W. (1983) · Journal of The Electrochemical Society · doi:10.1149/1.2120090 · Cited by 128 · see citing works
Sonoyama, N., Kirii, M., & Sakata, T. (1999) · Electrochemistry Communications · doi:10.1016/s1388-2481(99)00041-7 · Cited by 127 · see citing works
Li, H., & Oloman, C. W. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-006-9194-z · Cited by 127 · see citing works
Hydricity of transition-metal hydrides and its role in CO2 reduction
DuBois, D. L., & Berning, D. E. (2000) · Applied Organometallic Chemistry · doi:10.1002/1099-0739(200012)14:12 · Cited by 126 · see citing works
Electrochemical reduction of CO2 in methanol with aid of CuO and Cu2O
Ohya, S., Kaneco, S., Katsumata, H., Suzuki, T., & Ohta, K. (2009) · Catalysis Today · doi:10.1016/j.cattod.2009.07.077 · Cited by 126 · see citing works
Storà, T., Lakey, J. H., & Vogel, H. (1999) · Angewandte Chemie International Edition · doi:10.1002/(sici)1521-3773(19990201)38:3 · Cited by 123 · see citing works
Pulsed Electroreduction of CO 2 on Copper Electrodes
Shiratsuchi, R., Aikoh, Y., & Nogami, G. (1993) · Journal of The Electrochemical Society · doi:10.1149/1.2221113 · Cited by 122 · see citing works
Kaneco, S., Katsumata, H., Suzuki, T., & Ohta, K. (2005) · Energy & Fuels · doi:10.1021/ef050274d · Cited by 118 · see citing works
Electrochemical reduction of CO2 by Cu2O-catalyzed carbon clothes
Chang, T.-Y., Liang, R.-M., Wu, P., Chen, J.-Y., & Hsieh, Y.-C. (2009) · Materials Letters · doi:10.1016/j.matlet.2009.01.067 · Cited by 117 · see citing works
Fe and Pt carbon nanotubes for the electrocatalytic conversion of carbon dioxide to oxygenates
Gangeri, M., Perathoner, S., Caudo, S., Centi, G., Amadou, J., Bégin, D., Pham-Huu, C., Ledoux, M. J., Tessonnier, J.-P., & Su, D. S. (2009) · Catalysis Today · doi:10.1016/j.cattod.2008.11.001 · Cited by 112 · see citing works
Silver-coated ion exchange membrane electrode applied to electrochemical reduction of carbon dioxide
Hori, Y., Ito, H., Okano, K., Nagasu, K., & SATO, S. (2003) · Electrochimica Acta · doi:10.1016/s0013-4686(03)00311-6 · Cited by 111 · see citing works
Köleli, F., & Kayan, D. B. (2004) · Applied Catalysis A General · doi:10.1016/j.apcata.2004.07.006 · Cited by 109 · see citing works
Shi, Y., Luo, Y., Cai, N., Qian, J., Wang, S., Li, W., & Wang, H. (2012) · Electrochimica Acta · doi:10.1016/j.electacta.2012.10.107 · Cited by 109 · see citing works
Electrochemical Reduction of Carbon Dioxide
Wu, J., Risalvato, F. G., Sharma, P. P., Pellechia, P. J., Ke, F., & Zhou, X. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.030309jes · Cited by 106 · see citing works
FTIR spectroscopy study of the reduction of carbon dioxide on lead electrode in aqueous medium
Innocent, B., Pasquier, D., Ropital, F., Hahn, F., ́GER, J.-M. L., & Kokoh, K. B. (2009) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2009.10.027 · Cited by 106 · see citing works
Hara, K., Kudo, A., Sakata, T., & Watanabe, M. (1995) · Journal of The Electrochemical Society · doi:10.1149/1.2044182 · Cited by 101 · see citing works
Isaacs, M. A., Armijo, F., Ramı́rez, G., TROLLUND, E., Biaggio, S. R., Costamagna, J., & Aguirre, M. J. (2005) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2004.11.026 · Cited by 96 · see citing works
Effect of solid polymer electrolyte on electrochemical reduction of CO2
Aeshala, L. M., Rahman, S. U., & Verma, A. (2012) · Separation and Purification Technology · doi:10.1016/j.seppur.2011.12.030 · Cited by 89 · see citing works
Energy storage by the electrochemical reduction of CO2 to CO at a porous Au film
Stevens, G. B., Reda, T., & Raguse, B. (2002) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(02)00688-5 · Cited by 89 · see citing works
Steffey, B. D., Curtis, C. J., & DuBois, D. L. (1995) · Organometallics · doi:10.1021/om00010a066 · Cited by 88 · see citing works
Hori, Y., Murata, A., Takahashi, R., et al. (1987) · Chemistry Letters · doi:10.1246/cl.1987.1665 · Cited by 87 · see citing works
Carbon Dioxide Reduction to Alcohols using Perovskite‐Type Electrocatalysts
Schwartz, M. A., Cook, R. L., Kehoe, V. M., MacDuff, R. C., Patel, J., & Sammells, A. F. (1993) · Journal of The Electrochemical Society · doi:10.1149/1.2056131 · Cited by 87 · see citing works
Magdesieva, T. V., Yamamoto, T., Tryk, D. A., & Fujishima, A. (2002) · Journal of The Electrochemical Society · doi:10.1149/1.1475690 · Cited by 86 · see citing works
Electrochemical Reduction of CO2at Cu Nanocluster / (1010) ZnO Electrodes
Andrews, E. M., Ren, M., Wang, F., Zhang, Z., Sprunger, P. T., Kurtz, R. L., & Flake, J. C. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.105311jes · Cited by 85 · see citing works
Mathematical Modeling of CO[sub 2] Reduction to CO in Aqueous Electrolytes
Delacourt, C., Ridgway, P. L., & Newman, J. S. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3502532 · Cited by 84 · see citing works
Yano, J., & Yamasaki, S. (2008) · Journal of Applied Electrochemistry · doi:10.1007/s10800-008-9622-3 · Cited by 84 · see citing works
Komatsu, S., Tanaka, M., Okumura, A., & Kungi, A. (1995) · Electrochimica Acta · doi:10.1016/0013-4686(94)00325-u · Cited by 83 · see citing works
Effect of sodium cation on the electrochemical reduction of CO2 at a copper electrode in methanol
Kaneco, S., Iiba, K., Katsumata, H., Suzuki, T., & Ohta, K. (2006) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-006-0185-0 · Cited by 82 · see citing works
Large Current Density CO2 Reduction under High Pressure Using Gas Diffusion Electrodes
Hara, K., & Sakata, T. (1997) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.70.571 · Cited by 82 · see citing works
Zhao, G., Jiang, T., Han, B., Li, Z., Zhang, J., Liu, Z., He, J. H., & Wu, W. (2004) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2003.12.015 · Cited by 76 · see citing works
Electrochemical Reduction of CO2 with High Current Density in a CO2-Methanol Medium
Saeki, T., Hashimoto, K., Fujishima, A., Kimura, N., & Omata, K. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100020a083 · Cited by 76 · see citing works
Electrochemical reduction of high pressure CO2 at a Cu electrode in cold methanol
Kaneco, S., Iiba, K., Katsumata, H., Suzuki, T., & Ohta, K. (2006) · Electrochimica Acta · doi:10.1016/j.electacta.2006.01.032 · Cited by 74 · see citing works
Catalytic Electrochemical Reduction of CO2 in Ionic Liquid EMIMBF3Cl
Snuffin, L. L., Whaley, L. W., & Yu, L. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3606487 · Cited by 73 · see citing works
Yano, H., Shirai, F., Nakayama, M., & Ogura, K. (2002) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(02)01078-1 · Cited by 73 · see citing works
Hirota, K., Tryk, D. A., Yamamoto, T., et al. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp9822945 · Cited by 72 · see citing works
Saeki, T., Hashimoto, K., Kimura, N., Omata, K., & Fujishima, A. (1996) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)04374-8 · Cited by 71 · see citing works
Kamrath, M. Z., Relph, R. A., & Johnson, M. A. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1073036 · Cited by 70 · see citing works
Bernatis, P. R., Miedaner, A., Haltiwanger, R. C., & DuBois, D. L. (1994) · Organometallics · doi:10.1021/om00024a029 · Cited by 65 · see citing works
Aydın, R., & Köleli, F. (2002) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(02)01151-8 · Cited by 65 · see citing works
Fixation of CO2 by Electrocatalytic Reduction and Electropolymerization in Ionic Liquid–H2O Solution
Chu, D., Qin, G., Yuan, X., Xu, M., Peng, Z., & Jia, L. (2008) · ChemSusChem · doi:10.1002/cssc.200700052 · Cited by 65 · see citing works
Shironita, S., Karasuda, K., Sato, K., & Umeda, M. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.04.034 · Cited by 63 · see citing works
Electrochemical reduction of CO2 on Au in KOH + methanol at low temperature
Kaneco, S., Iiba, K., Ohta, K., Mizuno, T., & Saji, A. (1998) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(97)00438-5 · Cited by 62 · see citing works
Electrochemical reduction of CO2 at an activated silver electrode
Kostecki, R. M., & Augustyński, J. (1994) · Berichte der Bunsengesellschaft für physikalische Chemie · doi:10.1002/bbpc.19940981203 · Cited by 61 · see citing works
Electroreduction of carbon dioxide at a lead electrode in propylene carbonate: A spectroscopic study
Innocent, B., Pasquier, D., Ropital, F., ́GER, J.-M. L., & Kokoh, K. B. (2010) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2010.05.003 · Cited by 61 · see citing works
Mathematical Modeling of CO[sub 2] Reduction to CO in Aqueous Electrolytes
Delacourt, C., & Newman, J. S. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3502533 · Cited by 58 · see citing works
Electrochemical reduction of CO2 at an Ag electrode in KOH-methanol at low temperature
Kaneco, S., Iiba, K., Ohta, K., Mizuno, T., & Saji, A. (1998) · Electrochimica Acta · doi:10.1016/s0013-4686(98)00178-9 · Cited by 58 · see citing works
Terunuma, Y., Saitoh, A., & Momose, Y. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(97)00122-8 · Cited by 56 · see citing works
Electrochemical reduction of CO2 in copper particle-suspended methanol
Kaneco, S., Ueno, Y., Katsumata, H., Suzuki, T., & Ohta, K. (2006) · Chemical Engineering Journal · doi:10.1016/j.cej.2006.03.030 · Cited by 50 · see citing works
Ali, M. M., Sato, H., Ali, M. M., Sato, H., Mizukawa, T., Tsuge, K., Haga, M., & Tanaka, K. (1998) · Chemical Communications · doi:10.1039/a707363a · Cited by 48 · see citing works
Electrochemical reduction of CO2 in methanol at −30°C
Mizuno, T., Naitoh, A., & Ohta, K. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)03936-b · Cited by 48 · see citing works
Pulsed Electroreduction of CO 2 on Silver Electrodes
Shiratsuchi, R., & Nogami, G. (1996) · Journal of The Electrochemical Society · doi:10.1149/1.1836484 · Cited by 48 · see citing works
Facile Electrochemical Fabrication of Large-Area ZnO Inverse Opals with Reduced Defects
Huang, Y.-J., Liao, C.-H., Huang, B.-H., Chen, W.-Y., & Wu, P. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3552604 · Cited by 46 · see citing works
Carbon Dioxide Recycling by High Temperature Co-electrolysis and Hydrocarbon Synthesis
Hartvigsen, J., Elangovan, S., Frost, L., et al. (2008) · ECS Transactions · doi:10.1149/1.2921588 · Cited by 45 · see citing works
Electrochemical Reduction of CO2 in a Mixed Supercritical Fluid
Abbott, A. P., & Eardley, C. A. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp9932867 · Cited by 44 · see citing works
Effect of Gaseous Impurities on the Electrochemical Reduction of CO2 on Copper Electrodes
Zhai, Y., Chiachiarelli, L., & Sridhar, N. (2009) · ECS Transactions · doi:10.1149/1.3220175 · Cited by 43 · see citing works
Kaneco, S., Iiba, K., Katsumata, H., Suzuki, T., & Ohta, K. (2006) · Chemical Engineering Journal · doi:10.1016/j.cej.2006.10.002 · Cited by 41 · see citing works
Influence of sputtering parameters on electrochemical CO2 reduction in sputtered Au electrode
Ohmori, T., Nakayama, A., Mametsuka, H., & Suzuki, E. (2001) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(01)00624-6 · Cited by 39 · see citing works
Momose, Y., Sato, K., & Ohno, O. (2002) · Surface and Interface Analysis · doi:10.1002/sia.1372 · Cited by 39 · see citing works
Schrebler, R., Cury, P., Suárez, C., et al. (2002) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(02)01086-0 · Cited by 38 · see citing works
Saravanakumar, D., Song, J., Jung, N., Jirimali, H. D., & Shin, W. (2012) · ChemSusChem · doi:10.1002/cssc.201100481 · Cited by 38 · see citing works
Cheung, K.-C., Guo, P., So, M., Lee, L. Y. S., Ho, K., Wong, W., Lee, K., Wong, W., Zhou, Z., & Wong, K. (2009) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2009.04.034 · Cited by 33 · see citing works
Christensen, P. A., & Higgins, S. J. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)03949-h · Cited by 30 · see citing works
Effects of the Electrolyte on Electrochemical Reduction of CO2 on Sn Electrode
Wu, J., Risalvato, F. G., & Zhou, X. (2012) · ECS Transactions · doi:10.1149/1.3702412 · Cited by 23 · see citing works
Effect of Electrolyte on the Electrochemical Reduction of CO2
Salazar-Villalpando, M. D. (2011) · ECS Transactions · doi:10.1149/1.3565504 · Cited by 23 · see citing works
Electrochemical Reduction of C02on Cu in 0.1 M KOH-Methanol
Mizuno, T., Ohta, K., Kawamoto, M., & Saji, A. (1997) · Energy Sources · doi:10.1080/00908319708908848 · Cited by 20 · see citing works
Electrochemical reduction of CO2 on hydrogen-enriched and hydrogen-depleted surfaces
Yoshitake, H., Takahashi, K., & Ota, K. (1994) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9949000155 · Cited by 19 · see citing works
Koga, O., Matsuo, T., Yamazaki, H., & Hori, Y. (1998) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.71.315 · Cited by 18 · see citing works
Ougitani, Y., Aizawa, T., Sonoyama, N., & Sakata, T. (2001) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.74.2119 · Cited by 14 · see citing works
Electrochemical Reduction of CO2 in Micropores
Yamamoto, T., Hirota, K., Tryk, D. A., Hashimoto, K., Fujishima, A., & Okawa, M. (1998) · Chemistry Letters · doi:10.1246/cl.1998.825 · Cited by 14 · see citing works
Regenerative Solid Oxide Fuel Cells for Mars Exploration
Sridhar, K. R., & Foerstner, R. (2000) · Journal of Propulsion and Power · doi:10.2514/2.5684 · Cited by 11 · see citing works
Electrochemical Reduction of CO2 at Temperatures Below 300 oC
Hallinder, J., Holtappels, P., & Mogensen, M. B. (2012) · ECS Transactions · doi:10.1149/1.3702413 · Cited by 9 · see citing works
Breedlove, B. K., Takayama, D., & Ito, T. (2004) · Chemistry Letters · doi:10.1246/cl.2004.1624 · Cited by 6 · see citing works
Matsubara, T., Oishi, T., & Katagiri, A. (2002) · Journal of The Electrochemical Society · Cited by 6 · see citing works
Ishihara, A., Fujimori, T., Motohira, N., et al. (2001) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.74.1517 · Cited by 4 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747 · see citing works
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594 · see citing works
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331 · see citing works
Metal‐Free Carbon Materials for CO<sub>2</sub> Electrochemical Reduction
Duan, X., Xu, J., Wei, Z., Ma, J., Guo, S., Wang, S., Liu, H., & Dou, S. (2017) · Advanced Materials · doi:10.1002/adma.201701784 · Cited by 754 · see citing works
Lum, Y., & Ager, J. W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710590 · Cited by 410 · see citing works
Investigating the Role of Copper Oxide in Electrochemical CO <sub>2</sub> Reduction in Real Time
Mandal, L., Yang, K. R., Motapothula, M. R., Ren, D., Lobaccaro, P., Patra, A., Sherburne, M., Batista, V. S., Yeo, B. S., Ager, J. W., et al. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b15418 · Cited by 269 · see citing works
Del Castillo, A., Alvarez-Guerra, M., Solla-Gullón, J., Sáez, A., Montiel, V., & Irabien, A. (2017) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2017.01.021 · Cited by 189 · see citing works
Hydronium-Induced Switching between CO2 Electroreduction Pathways
Seifitokaldani, A., Gabardo, C. M., Burdyny, T., Dinh, C.-T., Edwards, J. P., Kibria, M. G., Bushuyev, O. S., Kelley, S. O., Sinton, D., & Sargent, E. H. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b13542 · Cited by 179 · see citing works
Natsui, K., Iwakawa, H., Ikemiya, N., Nakata, K., & Einaga, Y. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712271 · Cited by 166 · see citing works
Electrochemical generation of syngas from water and carbon dioxide at industrially important rates
Liu, Z., Masel, R. I., Chen, Q., Kutz, R., Yang, H., Lewinski, K., Kaplun, M., Luopa, S., & Lutz, D. R. (2016) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2016.04.011 · Cited by 93 · see citing works
A pH-differential dual-electrolyte microfluidic electrochemical cells for CO2 utilization
Lu, X., Leung, D. Y. C., Wang, H., Maroto-Valer, M. M., & Xuan, J. (2016) · Renewable Energy · doi:10.1016/j.renene.2016.04.021 · Cited by 64 · see citing works
Design of Noble Metal Electrocatalysts on an Atomic Level
Chao, T., Hu, Y., Hong, X., & Li, Y. (2019) · ChemElectroChem · doi:10.1002/celc.201801189 · Cited by 62 · see citing works
Monroe, M. M., Lobaccaro, P., Lum, Y., & Ager, J. W. (2017) · Journal of Physics D: Applied Physics · doi:10.1088/1361-6463/aa6359 · Cited by 30 · see citing works
- Authors
- Jones, J., Prakash, G. K. S., & Olah, G. A.
- Affiliations
- University of Southern California (US)
- Corresponding author
- Prakash, G. K. Surya
- Venue
- Israel Journal of Chemistry
- Publisher
- Wiley
- Published
- 2014-09-09
- Volume
- 54
- Issue
- 10
- Pages
- 1451-1466
- ISSN
- 0021-2148 (ISSN-L)
- 1869-5868
- OpenAlex
- W2093193003
- Cited by
- 425
- References
- 159
- Citations by year
- 2026: 9 · 2025: 19 · 2024: 38 · 2023: 40 · 2022: 38 · 2021: 49 · 2020: 39 · 2019: 61 · 2018: 54 · 2017: 37 · 2016: 30 · 2015: 10 · 2014: 1
- FWCI
- 8.57
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Israel Journal of Chemistry (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, CO2 conversion, formate production, carbon monoxide production, methanol synthesis, methane production, flow cell, high-pressure electrolysis, molecular catalysts, non-aqueous electrolytes, solid oxide electrolysis cells, reaction mechanism
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review