The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
High entropy alloy as a highly active and stable electrocatalyst for hydrogen evolution reaction
Abstract
Abstract Transition metals and their alloys are expected to have high catalytic activities for hydrogen evolution reaction due to their partially filled d orbitals fitting for the gain and loss of electrons. The poor corrosion resistance, however, limits their applications as electrocatalysts in acidic and alkaline electrolytes. In this work, we report that high entropy alloy (HEA, Ni 20 Fe 20 Mo 10 Co 35 Cr 15 ) with high corrosion resistance can be functioned as highly active and stable electrocatalyst for the hydrogen evolution reaction in both acidic and basic electrolytes. The HEA requires an overpotential of only 107 mV in acidic solutions and 172 mV in the basic solution at current density of 100 mA cm −2 , which are much better than that of the dual-phase counterpart and even comparable to that of Pt sheet and most reported nanostructured noble-metal-free catalysts, for hydrogen evolution reaction in both acidic and alkaline solutions.
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Cites
Opportunities and challenges for a sustainable energy future
Chu, S., & Majumdar, A. (2012) · Nature · doi:10.1038/nature11475 · Cited by 12,550
Ni–Mo Nanopowders for Efficient Electrochemical Hydrogen Evolution
McKone, J. R., Sadtler, B. F., Werlang, C. A., Lewis, N. S., & Gray, H. B. (2013) · ACS Catalysis · doi:10.1021/cs300691m · Cited by 798
Jakšić, M. M. (2000) · Electrochimica Acta · doi:10.1016/s0013-4686(00)00525-9 · Cited by 116
Cited by
Oses, C., Toher, C., & Curtarolo, S. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0170-8 · Cited by 2,081
High-entropy energy materials: challenges and new opportunities
Ma, Y., Ma, Y., Wang, Q., Schweidler, S., Botros, M., Fu, T., Hahn, H., Brezesinski, T., & Breitung, B. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00505g · Cited by 963
(2020) · doi:10.1038/s41467-020-19277-9 · Cited by 690
Recent progress of high-entropy materials for energy storage and conversion
Amiri, A., & Shahbazian-Yassar, R. (2021) · Journal of Materials Chemistry A · doi:10.1039/d0ta09578h · Cited by 592
Fan, L., Ji, Y., Wang, G., Chen, J., Chen, K., Liu, X., & Wen, Z. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c13740 · Cited by 554
Metadata
- Authors
- Zhang, G., Ming, K., Kang, J., Huang, Q., Zhang, Z., Zheng, X., & Bi, X.
- Venue
- Electrochimica Acta
- Publisher
- Elsevier BV
- Published
- 2018-07
- Volume
- 279
- Pages
- 19-23
- ISSN
- 0013-4686 (ISSN-L)
- OpenAlex
- W2801886803
- Cited by
- 366
- References
- 3
- FWCI
- 4.47
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, G., Ming, K., Kang, J., Huang, Q., Zhang, Z., Zheng, X., & Bi, X. (2018). High entropy alloy as a highly active and stable electrocatalyst for hydrogen evolution reaction. Electrochimica Acta. https://doi.org/10.1016/j.electacta.2018.05.035
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