Cited by 110Ionic liquids properties and applicationsElectrochemical Analysis and ApplicationsAnalytical chemistry methods development

Chemical and electrochemical properties of a hydrophobic deep eutectic solvent

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Ruggeri, S., Poletti, F., Zanardi, C., Pigani, L., Zanfrognini, B., Corsi, E., Dossi, N., Salomäki, M. +3 more·2019·Electrochimica Acta

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Crossref · 10.1016/j.electacta.2018.10.086

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  • Ruggeri et al. demonstrated that addition of small water to tetrabutylammonium chloride and decanoic acid HDES (1:2) improved the electrical conductivity and viscosity of the solvent.

    “For example, in exploring the electrochemical behavior of ferrocenes, for the first time, Ruggeri et al. [73] demonstrated that addition of small water to tetrabutylammonium chloride and decanoic acid HDES (1:2) improved the electrical conductivity and viscosity of the solvent.”
  • Water disrupts the hydrogen bond between the donor and the acceptor to enhance the free flow of ions in the medium.

    “Water disrupts the hydrogen bond between the donor and the acceptor to enhance the free flow of ions in the medium.”
  • An aqueous solution containing a salt of metallic cation, Cr(VI), could be extracted by using a hydrophobic DES.

    “In addition, the researchers showed that an aqueous solution containing a salt of metallic cation, Cr(VI), could be extracted by using a hydrophobic DES [73].”
  • Water content above 2% w/w in HDES enables effective mass transfer to and from the electrode surface.

    “Water content above 2% w/w in HDES enables effective mass transfer to and from the electrode surface [73].”

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Authors
Ruggeri, S., Poletti, F., Zanardi, C., Pigani, L., Zanfrognini, B., Corsi, E., Dossi, N., Salomäki, M., Kivelä, H., Lukkari, J., & Terzi, F.
Affiliations
  • University of Modena and Reggio Emilia (IT)
  • University of Udine (IT)
  • University of Turku (FI)
Corresponding author
Terzi, F.
Venue
Electrochimica Acta
Publisher
Elsevier BV
Published
2019-02
Volume
295
Pages
124-129
ISSN
0013-4686 (ISSN-L)
OpenAlex
W2898309131
Cited by
110
References
22
Citations by year
2026: 13 · 2025: 21 · 2024: 8 · 2023: 13 · 2022: 18 · 2021: 20 · 2020: 11 · 2019: 6
FWCI
2.14
Type
journal article
Language
en
Open access
Locations
  • Electrochimica Acta (publishedVersion)
  • IRIS UNIMORE (University of Modena and Reggio Emilia) (submittedVersion, cc-by)
  • Institutional Research Information System (University of Udine) (submittedVersion)
  • ARCA (Università Ca' Foscari Venezia) (submittedVersion)
Topics
  • Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
  • Physical Sciences › Chemistry › Electrochemistry › Electrochemical Analysis and Applications
  • Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
Keywords
hydrophobic deep eutectic solvents, tetrabutylammonium chloride, capric acid, electrochemical properties, electrical conductivity, viscosity, moisture content, solvent extraction, hexavalent chromium, amperometric detection, aqueous-organic extraction

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