A review of performance enhancement of PCM based latent heat storage system within the context of materials, thermal stability and compatibility
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Paraffin has low thermal conductivity and density, a relatively large volume change, does not have a well-defined melting point, and can be flammable.
“However, they have low thermal conductivity and density, have a relatively large volume change, do not have a well-defined melting point, and can be flammable.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
The Classification table lists low thermal conductivity and density, high volume change, and inflammability as disadvantages of paraffins. Its statement that there is “no well-defined sharp melting point” appears under eutectics, not paraffins, so that part of the claim is not supported. (LLM, conf=0.87)
Experimental — accuracy not yet measuredSalt hydrates have a relatively small volume change, high density, and are inexpensive and readily available.
“Salt hydrates also have a relatively small volume change, high density, and are inexpensive and readily available.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
The salt-hydrates discussion (lines 117–120) says they cost less than paraffins, and Table 4 lists densities for several salt hydrates. Our copy does not establish that their volume change is relatively small or that they are readily available; the listed densities alone do not establish the comparative claim that they have high density. (LLM, conf=0.84)
Experimental — accuracy not yet measuredSalt hydrates lack thermal stability and can be toxic.
“They also lack thermal stability and can be toxic.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Section 3.1.2, “Salt Hydrates” (page not provided), reports that some salt hydrates lose thermal performance during cycling and need additives for long-term stability. The passages do not say that salt hydrates can be toxic; a search for toxicity found no supporting passage. (LLM, conf=0.86)
Experimental — accuracy not yet measuredLHTES systems are more convenient than other thermal storage methods.
“The higher thermal storage density, large array of PCMs, and nearly isothermal behavior of LHTES systems (shown in Figure 1b) make them more convenient than the other methods [2].”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
LHTES systems have higher thermal storage density than sensible heat storage (SHS).
“The higher thermal storage density, large array of PCMs, and nearly isothermal behavior of LHTES systems (shown in Figure 1b) make them more convenient than the other methods [2].”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
LHTES systems have nearly isothermal behavior.
“The higher thermal storage density, large array of PCMs, and nearly isothermal behavior of LHTES systems (shown in Figure 1b) make them more convenient than the other methods [2].”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
LHTES systems have a large array of PCMs.
“The higher thermal storage density, large array of PCMs, and nearly isothermal behavior of LHTES systems (shown in Figure 1b) make them more convenient than the other methods [2].”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Organic PCMs have no supercooling and high latent heat of fusion.
“Organic PCMs have the advantages of no supercooling and high latent heat of fusion.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Experimental — accuracy not yet measuredEutectic materials have relatively high thermal conductivity and latent heat of fusion.
“Other advantages of eutectic materials include relatively high thermal conductivity and latent heat of fusion.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Paraffin has the advantages of being non-toxic, chemically stable, compatible with metal containers, and inexpensive.
“Paraffin specifically has the advantages of being non-toxic, chemically stable, compatible with metal containers, and inexpensive.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Metallic PCMs have high cost, low specific heat, and low latent heat of fusion per weight unit.
“The main disadvantages of metallic PCMs include a high cost, low specific heat, and low latent heat of fusion per weight unit [1,2].”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Inorganic PCMs have higher thermal conductivity than organic PCMs.
“In general, both groups of inorganic PCMs have higher thermal conductivity and latent heat of fusion per volume than organic PCMs.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Eutectic materials have high cost.
“A disadvantage is their high cost [2].”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Fatty acids have a well-defined phase transition and easily reproduced phase change.
“Fatty acids have a well-defined phase transition and easily reproduced phase change.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Salt hydrates can cause supercooling, phase segregation, and corrosion on metal containers.
“However, salt hydrates can cause supercooling, phase segregation, and corrosion on metal containers.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Fatty acids have low thermal conductivity, toxicity, corrosivity, instability, flammability, and are much more expensive than paraffin.
“They also have the disadvantage of low thermal conductivity, as well as toxicity, corrosivity, instability, and flammability, while also being much more expensive than paraffin [1,2].”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
Inorganic PCMs have higher latent heat of fusion per volume than organic PCMs.
“In general, both groups of inorganic PCMs have higher thermal conductivity and latent heat of fusion per volume than organic PCMs.”
From Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review (2021) · cites this paper as [2]
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- Authors
- Khan, Z., Khan, Z., & Ghafoor, A.
- Affiliations
- Bournemouth University (GB)
- National University of Sciences and Technology (PK)
- Corresponding author
- Khan, Zakir
- Venue
- Energy Conversion and Management
- Publisher
- Elsevier BV
- Published
- 2016-05
- Volume
- 115
- Pages
- 132-158
- ISSN
- 0196-8904 (ISSN-L)
- OpenAlex
- W2293534651
- Cited by
- 765
- References
- 125
- Citations by year
- 2026: 68 · 2025: 92 · 2024: 93 · 2023: 88 · 2022: 88 · 2021: 89 · 2020: 78 · 2019: 60 · 2018: 53 · 2017: 42 · 2016: 14
- FWCI
- 43.74
- Type
- journal article
- Language
- en
- Open access
- Locations
- Energy Conversion and Management (publishedVersion)
- Bournemouth University Research Online (Bournemouth University) (submittedVersion)
- Funders
- Bournemouth University
- National University of Science and Technology
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Phase Change Materials Research
- Physical Sciences › Engineering › Mechanical Engineering › Adsorption and Cooling Systems
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- phase change materials, latent heat storage, alkanes, salt hydrates, thermal stability, thermal conductivity enhancement, PCM encapsulation, fins, latent heat storage capacity
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