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State of art review on conventional and advanced pyrolysis of macroalgae and microalgae for biochar, bio-oil and bio-syngas production
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“The proportions of these products vary depending on reactor conditions, with a higher heating rate and shorter residence times favouring the formation of higher levels of bio-oil [100].”
From Key Targets for Improving Algal Biofuel Production (2021) · cites this paper as [100]
In the citing paper
“However, relatively high oxygen and moisture content (due to release of internal moisture of the biomass and the dehydration process) affects its performances when directly using it as an energy source (Kung et al. 2022; Lee et al. 2020a).”
From Role of biochar toward carbon neutrality (2023) · cites this paper as Lee et al. 2020a
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1 retracted
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Pyrolysis of macroalgae: Insight into product yields and biochar morphology and stability
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Algal biorefinery: a potential solution to the food–energy–water–environment nexus
Talebi, S., Edalatpour, A., & Tavakoli, O. (2022) · Sustainable Energy & Fuels · doi:10.1039/d1se01740c · Cited by 23
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Bi, D., Wang, H., Liu, Y., Qin, Z., Song, X., & Liu, S. (2024) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2024.106723 · Cited by 20
Low-carbon biofuels from macroalgae towards a sustainable circular bioeconomy and green future
Joshiba, G. J., Nagarajan, D., Rathinam, B., & Chien, J.-R. C. (2024) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2024.107389 · Cited by 20
Jena, M. K., Liang, R., Dey, S. D., Gao, W., Prabakar, P. C. J., Yin, Y., Kamal, S., Gangawane, K. M., Sivagami, K., Shakir, M., et al. (2026) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2026.107829 · Cited by 21
Combined effects of earthworms and biochar on PAHs-contaminated soil remediation: A review
Hou, S., Wang, J., Dai, J., Boussafir, M., & Zhang, C. (2022) · Soil Ecology Letters · doi:10.1007/s42832-022-0158-y · Cited by 20
“Slow heating rate and long residence time in slow pyrolysis achieve a high production yield of biochar, while the fast heating rate (10–200 K s−1) and short residence time (0.5−10 s) in fast pyrolysis favors the production of bio-oil (Perego and Bosetti, 2011; Oni et al., 2019; Lee et al., 2020).”
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Shi, X., Wang, B., Hu, J., Chen, W., Chang, C., Pang, S., & Li, P. (2023) · Renewable Energy · doi:10.1016/j.renene.2023.119490 · Cited by 19
Self-citationEffects of hydrochloric acid washing on the structure and pyrolysis characteristics of tobacco stalk
Liang, M., Yang, T., Zhang, G., Zhang, K., Wang, L., Li, R., He, Y., Wang, J., & Zhang, J. (2021) · Biomass Conversion and Biorefinery · doi:10.1007/s13399-021-01616-5 · Cited by 18
Improving bio-oil chemical profile of seaweeds through anaerobic fermentation pre-treatment
Wahab, M. A., Kebelmann, K., Schartel, B., & Griffiths, G. J. (2021) · Energy Conversion and Management · doi:10.1016/j.enconman.2021.114632 · Cited by 18
Chemometric analysis unravelling the effect of key influencing factors on algal biochar yield
Kapoor, A., Krishnamoorthy, N., Pathy, A., & Balasubramanian, P. (2022) · Algal Research · doi:10.1016/j.algal.2022.102908 · Cited by 17
Exploring the evolution, trends and scope of microalgal biochar through scientometrics
Krishnamoorthy, N., Pathy, A., Kapoor, A., & Balasubramanian, P. (2022) · Algal Research · doi:10.1016/j.algal.2022.102944 · Cited by 18
Diatom Biochar Recovered Au(III) Efficiently from Both Synthetic and Real Electroplating Wastewaters
Wang, L., Li, J., Zhong, G., Li, J., Xiao, L., Wang, S., & Tang, Y. (2023) · ACS ES&T Water · doi:10.1021/acsestwater.3c00066 · Cited by 18
Biochar's Influence on Soil Microorganisms: Understanding the Impacts and Mechanisms
Srivastava, P., Gadi, Y., Supriya, S., Bhojendra, Lytand, W., Singh, B. V., & Katiyar, D. (2023) · International Journal of Plant & Soil Science · doi:10.9734/ijpss/2023/v35i183310 · Cited by 18
Net zero emission in circular bioeconomy from microalgae biochar production: A renewed possibility
Wu, G., Tham, P. E., Chew, K. W., Munawaroh, H. S. H., Tan, I. S., Wan‐Mohtar, W. A. A. Q. I., Sriariyanun, M., & Show, P. L. (2023) · Bioresource Technology · doi:10.1016/j.biortech.2023.129748 · Cited by 18
Li, G., Yang, T., Xiao, W., Yao, X., Su, M., Pan, M., Wang, X., & Lyu, T. (2023) · Chemosphere · doi:10.1016/j.chemosphere.2023.140137 · Cited by 18
“Pyrolysis can also effectively convert raw materials into products such as biogas, biofuel and biochar under anaerobic or harsh pyrolysis condi - tions (Lee et al., 2020).”
Characterization of Biochar from Beach-Cast Seaweed and Its Use for Amelioration of Acid Soils
Cárdenas-Aguiar, E., Gascó, G., Lado, M., Méndez, A., Paz‐Ferreiro, J., & González, A. P. (2024) · Land · doi:10.3390/land13060881 · Cited by 18
“In addition, reviews on algal BC production and on the use of algae for bio-oil production, bioenergy and bio-syngas are available [13,19,20] .”
BackgroundChen, B., & Yang, Y. (2023) · Journal of Thermal Analysis and Calorimetry · doi:10.1007/s10973-022-11895-3 · Cited by 17
Management of Plastic Wastes through Recent Advanced Pyrolysis Processes
Shareefdeen, Z. M., & Elgazar, A. (2024) · Applied Sciences · doi:10.3390/app14146156 · Cited by 17
A Review of Recent Advances in Biomass-Derived Porous Carbon Materials for CO2 Capture
Li, G., He, J., & Yao, J. (2025) · C – Journal of Carbon Research · doi:10.3390/c11040092 · Cited by 18
Microwave-Assisted Conversion of Carbohydrates
Kustov, L. M., Kustov, A. L., & Salmi, T. (2022) · Molecules · doi:10.3390/molecules27051472 · Cited by 16
“Pyrolysis of macroalgae or microalgae is now considered a robust source of chemicals and energy carriers [50].”
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“The rich composition of carbohydrates, lipids, proteins, nucleic acids, and unsaturated fatty acids in both macroalgae and microalgae contributes to the production of high-quality biochar, with its physical and chemical properties determining its overall quality [158].”
Volatile Compounds of Algal Biomass Pyrolysis
López-Aguilar, H. A., Quiroz-Cardoza, D., & Pérez-Hernández, A. (2022) · Journal of Marine Science and Engineering · doi:10.3390/jmse10070928 · Cited by 15
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“26 This variation in the biochemical arrangement of different species of green macroalgae will signi fi cantly in fl uence the pretreatment process and the subsequent biogas yield.”
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Bio-Oil Production and Characterization from Corn Cob and Sunflower Stem Pyrolysis
Zubiolo, C., Santana, H. E. P., Pereira, L. L., Ruzene, D. S., Silva, D. P., & Freitas, L. D. S. (2023) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.3c03337 · Cited by 15
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Valorization of Algal Biomass to Biofuel: A Review
Amalapridman, V., Ofori, P. A., & Abbey, L. (2025) · Biomass · doi:10.3390/biomass5020026 · Cited by 16
“Pyrolysis of algal biomass is a thermochemical process (Figure 8) during which the algal biomass is subjected to moderate temperatures in the absence of oxygen to produce valuable end-products such as bio-oil, biochar, and bio-syngas [149–151]. to produce bio-oil via pyrolysis [144,152].”
Circular bioeconomy approaches for sustainability and carbon mitigation in microalgal biorefinery
Nagarajan, D., Lee, D., & Chang, J. (2022) · Elsevier eBooks · doi:10.1016/b978-0-323-89855-3.00009-1 · Cited by 14
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Valorisation of macroalgae for biofuels in Indonesia: an integrated biorefinery approach
Suhartini, S., Pangestuti, M. B., Elviliana, E., Rohma, N. A., Junaidi, M. A., Paul, R., Nurika, I., Rahmah, N. L., & Melville, L. (2024) · Environmental Technology Reviews · doi:10.1080/21622515.2024.2336894 · Cited by 17
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“…main types of macroalgae, Enteromorpha prolifera and Ulva lactuca , which have higher content of carbohydrates and proteins than other macroalgae (Lee et al. 2020), were selected and co-pyrolyzed with oyster shell, Ostreidae , to obtain NPBs. Batch sorption experiments were conducted to…”
Potential of pyrolyzed and co-pyrolyzed biomass-derived biochar for the removal of ciprofloxacin
Paul, S., & Selvasembian, R. (2024) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2024.106884 · Cited by 13
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“In any case, the different nature of organic components strongly affects the pyrolysis products yields and composition, as well as the presence of inorganic elements catalyzing their decomposition pathways [7,19,20].”
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“83 m2/g with increasing pyrolysis temperature [29].”
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“These metabolic processes are contained within the algal cell wall, highlighting the potential of algae as a renewable resource for biodiesel production biochar, and syngas (Lee et al. 2020; Brindhadevi et al. 2021; Elgarahy et al. 2021; Xia et al. 2022).”
Production of valuable platform chemicals through microalgal routes utilizing waste streams
Devi, A., Patil, K., Kumar, A., Gupta, N., Malik, A., & Pabbi, S. (2022) · Bioresource Technology Reports · doi:10.1016/j.biteb.2022.101071 · Cited by 12
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Experimental Study of the Corrosiveness of Ternary Blends of Biodiesel Fuel
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“Biooil extraction requires high-energy input and intensification process (Lee et al., 2020).”
BackgroundRecent Advances in using Lipomyces starkeyi for the Production of Single-Cell Oil
Jacob, A., & Mathew, J. (2023) · Journal of Pure and Applied Microbiology · doi:10.22207/jpam.17.2.06 · Cited by 13
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“Microalgae include green (Chlorophyceae), blue-green (Cyanobacteria), yellow-green (Xanthophyceae), golden (Chrysophy-ceae), and diatoms (Bacillariophyceae), while macroalgae include brown (Phaeophyceae), red (Rhodophyceae), and green algae (Chlorophyceae) [10].”
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Enhancing sustainable energy production through biomass gasification gas technology: a review
Alabi, O. O., Gbadeyan, O. J., Towoju, O. A., & Deenadayalu, N. (2024) · F1000Research · doi:10.12688/f1000research.147958.1 · Cited by 14
Global insights into biomass pyrolysis mechanisms: A scientometric and mechanistic approach
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Transforming disposable masks to sustainable gasoline-like fuel via pyrolysis
Sari, M. M., Inoue, T., Salsabilla, V. C., Septiariva, I. Y., Mulyana, R., Prayogo, W., Arifianingsih, N. N., Suhardono, S., & Suryawan, I. W. K. (2023) · Environmental Advances · doi:10.1016/j.envadv.2023.100466 · Cited by 11
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Microalgae and Macroalgae for Third-Generation Bioethanol Production
Veza, I., Hoang, A. T., Mujtaba, M. A., Tamaldin, N., Idris, M., Djamari, D. W., Sule, A., Maulana, E., Putra, N. R., & Opia, A. C. (2022) · Biofuel and biorefinery technologies · doi:10.1007/978-3-031-01241-9_14 · Cited by 13
Hydrocarbon generation through pyrolysis of high-lipid-content microalgae within a dual-catalyst bed
Rossi, R. A. D. S., Vieira, L. G. M., Hori, C. E., & Barrozo, M. A. S. (2024) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2024.106682 · Cited by 10
Ramandani, A. A., Lee, S. Y., Jambrak, A. ., Chen, W., Lim, J. W., & Khoo, K. S. (2025) · Process Biochemistry · doi:10.1016/j.procbio.2025.01.006 · Cited by 12
Self-citationBiochar for carbon-negative hydrogen production from fossil fuel reservoirs
Yan, K., Yang, X., & Yuan, Q. (2025) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2025.145463 · Cited by 12
Solar Pyrolysis of Spirulina platensis Assisted by Fresnel Lens Using Hydrocalumite-Type Precursors
Martins, M. P. B., Hori, C. E., Barrozo, M. A. S., & Vieira, L. G. M. (2022) · Energies · doi:10.3390/en15207590 · Cited by 10
Chen, C., Zeng, T., He, J., Qi, Q., Feng, J., Zhao, J. M., & Fan, D. (2021) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2021.106762 · Cited by 10
Sarkar, S., Mankad, J., Padhihar, N., Manna, M. S., Bhowmick, T. K., & Gayen, K. (2022) · Preparative Biochemistry & Biotechnology · doi:10.1080/10826068.2022.2033995 · Cited by 11
“Microalgae biomass was able to produce 50% w/w bio-oil with comparable energy content (48MJ/kg) to the conventional fuel using the hydropyrolysis technique.([9]) Copyrolysis of protein-rich Chlorella sp.”
MethodBiofuels production using pyrolysis techniques
Hu, B., Liu, J., Xie, W.-L., Li, Y., & Lü, Q. (2023) · Elsevier eBooks · doi:10.1016/b978-0-323-95076-3.00010-7 · Cited by 10
Shim, H., Khani, Y., Valizadeh, B., Ko, C. H., Chen, W., Hussain, M., & Park, Y. (2024) · Chemical Engineering Journal · doi:10.1016/j.cej.2024.149209 · Cited by 9
Self-citationElsafi, M., Ho, Y., Guan, B. H., Leong, W. H., & Rashid, N. M. (2025) · Biomass Conversion and Biorefinery · doi:10.1007/s13399-024-06441-0 · Cited by 10
Innovations in microalgae pyrolysis: Driving circular economy and clean energy goals: Review
Elsafi, M., Ho, Y., Beh, H. G., Leong, W. H., & Rashid, N. M. (2025) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2025.108327 · Cited by 9
Yang, R., Chen, C., Zhao, S., Wan, S., & He, S. (2025) · Energy · doi:10.1016/j.energy.2025.138375 · Cited by 9
Biochar application for soil amendment and water remediation: A critical review
Mendioroz, P., Volpe, M. A., & Casoni, A. I. (2025) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2025.107417 · Cited by 10
Study on the mechanism of hydrogen production by catalytic pyrolysis of bagasse over CaO/Na2CO3
Zhang, S., Liang, D., Li, X., Fan, Y., Huang, H., He, X., Wang, L., Li, Z., & Dong, Y. (2026) · Progress in Reaction Kinetics and Mechanism · doi:10.48130/prkm-0025-0026 · Cited by 9
Biofuels and bioproducts from seaweeds
Nagula, K. N., Sati, H., Trivedi, N., & Reddy, C. R. K. (2022) · Elsevier eBooks · doi:10.1016/b978-0-323-88427-3.00012-x · Cited by 9
Sarkar, S., Bhowmick, T. K., & Gayen, K. (2023) · Preparative Biochemistry & Biotechnology · doi:10.1080/10826068.2023.2241898 · Cited by 9
“[13] Co-pyrolysis with polypropylene of Chlorella sp. was demonstrated to manufacture an enhanced quality of bio-oil with less oxygen and nitrogen.”
BackgroundMethodMari Selvam, S., Prabhakar, M. R., & Balasubramanian, P. (2023) · Biomass Conversion and Biorefinery · doi:10.1007/s13399-023-04987-z · Cited by 9
“This is owing to the difference in biochemical composition of feedstock where algae contain mostly volatile matter and less fixed carbon content than agro-residues and thereby results in lower yield than later [48].”
Qu, J., Yu, R., Liu, X., Peng, W., Bi, F., Liu, X., An, Q., Zhang, Y., Hu, Q., & Zhang, Y. (2025) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2025.115350 · Cited by 9
Rabah, M., Ali, L., Kuttiyathil, M. S., & Altarawneh, M. (2025) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2025.107848 · Cited by 8
Advances in biochar production from microalgae: techniques, challenges, and environmental benefits
Sridhar, N., & Manian, R. (2025) · Clean Technologies and Environmental Policy · doi:10.1007/s10098-025-03192-y · Cited by 10
“The rapid growth rate of algae, which ranges from 10 to 27 g/m 2 day (Lee et al., 2020), and high yield, which ranges from roughly 36% to 68%, are further benefits of using algae as a feedstock for biochar.”
Wan, Z., Xie, X., Ma, Y., Zhu, G., Jin, R., Lin, B., & Zheng, M. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.170735 · Cited by 8
Recent Development of Biomass and Plastic Co-Pyrolysis for Syngas Production
Mensah, I., Ahiekpor, J. C., Bensah, E. C., Narra, S., Amponsem, B., & Antwi, E. (2022) · Chemical Science International Journal · doi:10.9734/csji/2022/v31i130275 · Cited by 8
“[27] found that pyrolysis syngas requires no additional upgrading methods compared to bio-oil and char and can be used to directly fuel gas turbines, gas engines, boilers, etc.”
BackgroundMethodCheah, S. A., Chai, C. Y., Tan, I. S., Foo, H. C. Y., & Lam, M. K. (2022) · Progress in Energy and Environment · doi:10.37934/progee.21.1.1928 · Cited by 8
Metadata
- Authors
- Lee, X. J., Ong, H. C., Gan, Y. Y., Chen, W.-H., & Mahlia, T. M. I.
- Affiliations
- University of Malaya (MY)
- University of Technology Sydney (AU)
- Tunghai University (TW)
- Corresponding author
- Ong, Hwai Chyuan
- Venue
- Energy Conversion and Management
- Publisher
- Elsevier BV
- Published
- 2020-04
- Volume
- 210
- Pages
- 112707
- ISSN
- 0196-8904 (ISSN-L)
- OpenAlex
- W3011277252
- Cited by
- 465
- References
- 238
- Citations by year
- 2026: 40 · 2025: 78 · 2024: 88 · 2023: 79 · 2022: 86 · 2021: 63 · 2020: 31
- FWCI
- 20.37
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Energy Conversion and Management (publishedVersion)
- UTS ePRESS (University of Technology Sydney) (submittedVersion)
- Topics
- Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Algal biology and biofuel production
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Keywords
- seaweed, microalgae, algal biomass, pyrolysis, biochar, bio-oil, bio-syngas, catalytic pyrolysis, co-pyrolysis, hydropyrolysis, microwave pyrolysis, flash pyrolysis, intermediate pyrolysis, biofuel production, energy content
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