The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Dendrite-free lithium metal anode enabled by separator engineering via uniform loading of lithiophilic nucleation sites
Abstract
Abstract Despite promising high-capacity of lithium metal anode, one major obstacle for its wide application is the uncontrolled dendrite growth, causing low Coulombic efficiency (CE), irreversible capacity loss and short circuit. Here, we report a facile separator engineering to suppress Li dendrites growth through single-side deposition of magnesium (Mg) nanoparticles. The lithiophilic Mg nanoparticles on the separator, servering as heterogeneous nucleation sites, exhibits a strong guiding effect to form inerratic Li crystal seeds in the early plating process, resulting in a dense Li anode with dendrite-free morphology after long cycling. The unique characteristics of this functional separator are further demonstrated in Li|LiCoO2 full cells with a high capacity retention (>80% after 400 cycles). Accordingly, our strategy offers a scalable low-cost and efficient approach for advanced rechargeable Li metal batteries.
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Citations
Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Where do batteries end and supercapacitors begin?
Simon, P., Gogotsi, Y., & Dunn, B. (2014) · Science · doi:10.1126/science.1249625 · Cited by 5,634
Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode
Bieker, G., Winter, M., & Bieker, P. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp05865h · Cited by 777
Cited by
Lithium metal anodes: Present and future
Wang, R., Cui, W., Chu, F., & Wu, F. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.12.024 · Cited by 544
Safer Lithium‐Ion Batteries from the Separator Aspect: Development and Future Perspectives
Liu, Z., Jiang, Y., Hu, Q., Guo, S., Yu, L., Li, Q., Liu, Q., & Hu, X. (2021) · ENERGY & ENVIRONMENTAL MATERIALS · doi:10.1002/eem2.12129 · Cited by 253
Metadata
- Authors
- Liu, Y., Xiong, S., Wang, J., Jiao, X., Li, S., Zhang, C., Song, Z., & Song, J.
- Venue
- Energy Storage Materials
- Publisher
- Elsevier BV
- Published
- 2019-05
- Volume
- 19
- Pages
- 24-30
- ISSN
- 2405-8289 (ISSN-L)
- 2405-8297
- OpenAlex
- W2898758256
- Cited by
- 227
- References
- 4
- FWCI
- 7.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, Y., Xiong, S., Wang, J., Jiao, X., Li, S., Zhang, C., Song, Z., & Song, J. (2019). Dendrite-free lithium metal anode enabled by separator engineering via uniform loading of lithiophilic nucleation sites. Energy Storage Materials. https://doi.org/10.1016/j.ensm.2018.10.015
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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