Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode
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In comparative studies of the lithium metal anode in liquid electrolytes the self-enforcing heterogeneity of lithium deposition and dissolution is understood in a model of different stages.
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High irreversible capacity on the first cycle can be attributed to the extraction of residual sodium and formation of an SEI layer.
“High irreversible capacity on the first cycle as explained previously can be attributed to the extraction of residual sodium and formation of an SEI layer30.”
From High-performance Na3V2(PO4)3/C cathode for efficient low-temperature lithium-ion batteries (2025) · cites this paper as [30]
The Results and discussion section reports that Coulombic efficiency increases during the first lithium-plating cycles, indicating formation of a passivating film. That supports the SEI-formation part, but the paper does not address extraction of residual sodium or establish it as a cause of high first-cycle irreversible capacity. (LLM, conf=0.78)
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Cites
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Tomaszewska, A., Chu, Z., Feng, X., O'Kane, S., Liu, X., Chen, J., Ji, C., Endler, E., Li, R., Liu, L., et al. (2019) · eTransportation · doi:10.1016/j.etran.2019.100011 · Cited by 1,592 · see citing works
High-performance Na3V2(PO4)3/C cathode for efficient low-temperature lithium-ion batteries
Mukushev, I., Tyan, Y., Kalimuldina, G., Mukanova, A., Jakupova, Z., Kim, S.-S., Bakenov, Z., & Nurpeissova, A. (2025) · NPG Asia Materials · doi:10.1038/s41427-025-00591-x · Cited by 11 · see citing works
“3b, NVP/C//Li delivers an initial charge capacity of around 200 mAh g − 1 and a reversible discharge capacity of 102 mAh g − 1 at 0.2 C. High irreversible capacity on the fi rst cycle as explained previously can be attributed to the extraction of residual sodium and formation of an SEI layer 30 .”
Influential
- Authors
- Bieker, G., Winter, M., & Bieker, P.
- Affiliations
- University of Münster (DE)
- Corresponding author
- Bieker, Peter
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2015
- Volume
- 17
- Issue
- 14
- Pages
- 8670-8679
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2128315408
- Cited by
- 777
- References
- 1
- Citations by year
- 2026: 49 · 2025: 49 · 2024: 68 · 2023: 61 · 2022: 74 · 2021: 117 · 2020: 119 · 2019: 95 · 2018: 66 · 2017: 47 · 2016: 24 · 2015: 8
- FWCI
- 23.31
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- cc-by
- Locations
- Physical Chemistry Chemical Physics (publishedVersion, cc-by)
- PubMed (publishedVersion)
- Funders
- Bundesministerium für Bildung und Forschung (03X4634A)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- lithium metal anode, lithium dendrite growth, solid electrolyte interphase, lithium deposition and dissolution, lithium corrosion, carbonate electrolyte, LiPF6 electrolyte, tetraethylene glycol dimethyl ether, LiTFSI, dimethyl sulfoxide, electrolyte decomposition, lithium-oxygen batteries, self-discharge, overpotential, surface resistance, electrode surface morphology
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