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Mechanisms of competitive adsorption of Pb, Cu, and Cd on peat
Open accessAbstract
Combined use of batch equilibration adsorption and X-ray absorption spectroscopy (XAS) was employed to study the mechanisms of competitive adsorption of Pb, Cu, and Cd on Danish and Heilongjiang peat in single- and multi-solute systems. The adsorption capacity and initial adsorption rate on the same peat in single-solute systems followed the order Pb>Cu>Cd. Both the adsorbed amount of each metal (q'm) and its initial adsorption rate were decreased in multi-solute systems. It was observed that the adsorbed amounts of metals at low-energy adsorption sites (qm,1) decreased pronouncedly compared to those at high-energy adsorption sites (qm,2), indicating that the competitive adsorption of Pb, Cu and Cd occurred mainly at the low-energy adsorption sites. XAS study revealed that both Pb and Cu were coordinated in peat predominantly to carboxylic moieties without excluding the hydroxyl groups, thereby providing an insight into the mechanism of competitive adsorption of Pb and Cu on peat.
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Strawn, D. G., & Sparks, D. L. (1999) · Journal of Colloid and Interface Science · doi:10.1006/jcis.1999.6330 · Cited by 283
Mutual effects of cadmium and phosphate on their adsorption and desorption by goethite
Wang, K., & Xing, B. (2004) · Environmental Pollution · doi:10.1016/s0269-7491(03)00262-8 · Cited by 95
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Lv, J., Zhang, S., Wang, S., Luo, L., Cao, D., & Christie, P. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.5b04996 · Cited by 573
Self-citationFutalan, C. M., Kan, C.-C., Dalida, M. L., Hsien, K.-J., Pascua, C., & Wan, M.-W. (2011) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2010.08.013 · Cited by 388
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Metadata
- Authors
- Qin, F., Wen, B., Shan, X.-Q., Xie, Y.-N., Liu, T., Zhang, S.-Z., & Khan, S. U.
- Venue
- Environmental Pollution
- Publisher
- Elsevier BV
- Published
- 2006-11
- Volume
- 144
- Issue
- 2
- Pages
- 669-680
- ISSN
- 0269-7491 (ISSN-L)
- OpenAlex
- W2015204322
- Cited by
- 259
- References
- 2
- FWCI
- 12.58
- Type
- journal article
- Language
- en
- Open access
- green
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- Qin, F., Wen, B., Shan, X.-Q., Xie, Y.-N., Liu, T., Zhang, S.-Z., & Khan, S. U. (2006). Mechanisms of competitive adsorption of Pb, Cu, and Cd on peat. Environmental Pollution. https://doi.org/10.1016/j.envpol.2005.12.036
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