The clumped-isotope geochemistry of exhumed marbles from Naxos, Greece
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The blocking temperature is independent of the original crystallisation temperature and peak burial temperature.
“This blocking temperature is independent of the original crystallisation temperature and peak burial temperature [7,22].”
From Clumped Isotope Reordering and Kinetic Differences in Co-Hosted Calcite and Dolomite Minerals throughout Burial Diagenesis and Exhumation (2023) · cites this paper as [22]
Section 1.1 describes blocking temperature as governed by cooling rate, and its Fig. 2 discussion says the initial temperature has negligible effect on the final isotope measurement when it exceeds the blocking temperature. The paper also says earlier isotope values can be erased after sufficiently hot, prolonged burial. The claim omits those conditions, so the paper does not establish unconditional independence from crystallisation and peak burial temperatures. (LLM, conf=0.84)
Experimental — accuracy not yet measuredThe ∆47 values measured for calcite and dolomite in Jabal Akhdar represent blocking (apparent equilibrium) temperatures sensitive only to the cooling rate, not maximum burial temperatures.
“The ∆ 47 values measured for calcite and dolomite in Jabal Akhdar do not represent maximum burial temperatures but the blocking, or apparent equilibrium temperatures, which are sensitive only to the cooling rate [7,8,22].”
From Clumped Isotope Reordering and Kinetic Differences in Co-Hosted Calcite and Dolomite Minerals throughout Burial Diagenesis and Exhumation (2023) · cites this paper as [22]
Section 1.1 (page unavailable) explains that, during cooling from sufficiently high temperatures, Δ47 values can lock in at a blocking temperature that depends on cooling rate; it also says the initial temperature has negligible effect if it exceeds calcite’s blocking temperature. The paper studies Naxos, not Jabal Akhdar, and its Results and discussion describe measured values that cannot be explained by simple cooling alone. It therefore does not establish that the Jabal Akhdar measurements depend only on cooling rate. (LLM, conf=0.87)
Experimental — accuracy not yet measuredThe clumped isotope temperatures for dolomite in this study likely reflect dolomite formation temperatures because dolomite is relatively resistant to solid-state reordering at temperatures below 300°C.
“However, dolomite is relatively resistant to solidstate reordering at temperatures below 300°C, thus the temperatures in our study likely reflect the dolomite formation temperatures (e.g. Bonifacie et al., 2017; Ryb et al., 2017).”
From Ultramafic Rock Carbonation: Constraints From Listvenite Core BT1B, Oman Drilling Project (2020) · cites this paper as Ryb et al., 2017
Section 1.1 says dolomite is more resistant to isotopic reordering than calcite and has a typical blocking temperature near 300°C, supporting the resistance premise. But section 3.3 says a measured dolomite temperature of 290°C likely reflects reordering during cooling, not dolomite formation. The source therefore does not establish that the citing authors’ temperatures reflect formation temperatures. (LLM, conf=0.86)
Experimental — accuracy not yet measuredSuch models have been used to constrain temperature-time histories during burial and exhumation in sedimentary basins and metamorphic environments.
“To date, such models have been used to constrain the temperature-time (T-t) histories during burial and exhumation in sedimentary basins [10,11,13,15,[27][28][29] and metamorphic environments [16,22].”
From Clumped Isotope Reordering and Kinetic Differences in Co-Hosted Calcite and Dolomite Minerals throughout Burial Diagenesis and Exhumation (2023) · cites this paper as [22]
Solid-state reordering during exhumation can drive ∆47 values to record the apparent equilibrium or blocking temperature of the mineral, which is related to the cooling rate of the strata.
“Solid-state reordering during the exhumation process can drive the ∆ 47 values to record the apparent equilibrium or blocking temperature of the mineral [7,8,22], which is related to the cooling rate of the strata [8,23].”
From Clumped Isotope Reordering and Kinetic Differences in Co-Hosted Calcite and Dolomite Minerals throughout Burial Diagenesis and Exhumation (2023) · cites this paper as [22]
Rates of solid-state clumped isotope reordering are slower in dolomite than in calcite.
“The unaffected dolomite ∆ 47 was expected, as previous studies suggest that the rates of solid-state clumped isotope reordering are slower in dolomite than in calcite [16,22,123,124].”
From Clumped Isotope Reordering and Kinetic Differences in Co-Hosted Calcite and Dolomite Minerals throughout Burial Diagenesis and Exhumation (2023) · cites this paper as [22]
General estimates for calcite or dolomite Δ47 blocking temperatures during cooling range between 200 and 300 °C, respectively (e.g. Bonifacie et al., 2017; Ryb et al., 2017).
“General estimates for calcite or dolomite Δ 47 blocking temperatures during cooling range between 200 and 300 °C, respectively (e.g.Bonifacie et al., 2017;Ryb et al., 2017).”
From Calibration of the oxygen and clumped isotope thermometers for (proto-)dolomite based on synthetic and natural carbonates (2019) · cites this paper as Ryb et al., 2017
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Oxygen isotope composition of the Phanerozoic ocean and a possible solution to the dolomite problem
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“These include mineralogy (Stolper and Eiler, 2015; del Real et al., 2016; Lloyd et al., 2017, 2018; Ryb et al., 2017), minor and trace element substitution (Passey and Henkes, 2012; Henkes et al., 2014), deformation (Siman-tov et al., 2016; Ryb et al., 2017), the presence/absence of water (Passey…”
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Effects of oxygen plasma ashing treatment on carbonate clumped isotopes
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- Authors
- Ryb, U., Lloyd, M. K., Stolper, D. A., & Eiler, J. M.
- Affiliations
- Lawrence Berkeley National Laboratory (US)
- Corresponding author
- Ryb, U.
- Venue
- Earth and Planetary Science Letters
- Publisher
- Elsevier BV
- Published
- 2017-07
- Volume
- 470
- Pages
- 1-12
- ISSN
- 0012-821X (ISSN-L)
- OpenAlex
- W2610549620
- Cited by
- 41
- References
- 59
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 3 · 2023: 8 · 2022: 6 · 2021: 10 · 2020: 4 · 2019: 2 · 2018: 4
- FWCI
- 1.95
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Locations
- Earth and Planetary Science Letters (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- eScholarship (California Digital Library) (submittedVersion)
- Funders
- O.K. Earl Scholarship
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geophysical Studies Worldwide
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- clumped isotopes, marble, exhumation, retrograde metamorphism, calcite, dolomite, Δ47, carbonate isotopes, dynamic recrystallization, deformation fabrics, water-rock interaction, hydrothermal alteration, metamorphic core complexes, Naxos, cooling rate, blocking temperature, thermal shock, controlled heating
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