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Simultaneous inner- and outer-sphere arsenate adsorption on corundum and hematite
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Catalano et al. showed that arsenate surface complexation was bimodal, with sorption occurring simultaneously as inner- and outer-sphere species.
“Through the use of X-ray scattering measurements to study metal(loid) binding on single crystal surfaces, indeed, Catalano et al. [22] showed that arsenate surface complexation was bimodal, with sorption occurring simultaneously as innerand outer-sphere species.”
From Chemical Processes Affecting the Mobility of Heavy Metals and Metalloids in Soil Environments (2016) · cites this paper as [22]
Catalano et al. (2008) showed that arsenate surface complexation was bimodal, with sorption occurring simultaneously as inner- and outer-sphere species.
“Recently, through the use of X-ray scattering measurements to study metal(loid) binding on single crystal surfaces, Catalano et al . (2008) showed that arsenate surface complexation was bimodal, with sorption occurring simultaneously as inner- and outer-sphere species.”
From MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS (2010) · cites this paper as Catalano et al. (2008)
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Metadata
- Authors
- Catalano, J. G., Park, C., Fenter, P., & Zhang, Z.
- Affiliations
- Argonne National Laboratory (US)
- Corresponding author
- Catalano, Jeffrey G.
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2008-04
- Volume
- 72
- Issue
- 8
- Pages
- 1986-2004
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W2051371902
- Cited by
- 245
- References
- 117
- Citations by year
- 2026: 2 · 2025: 9 · 2024: 9 · 2023: 10 · 2022: 6 · 2021: 12 · 2020: 26 · 2019: 9 · 2018: 14 · 2017: 7 · 2016: 17 · 2015: 17 · 2014: 20 · 2013: 9 · 2012: 20
- FWCI
- 14.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- Funders
- U.S. Department of Energy
- Office of Science
- Basic Energy Sciences
- Argonne National Laboratory
- Topics
- Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- arsenate adsorption, inner-sphere complexes, outer-sphere complexes, corundum, hematite, surface complexation, metal oxide surfaces, interfacial water, hydrogen bonding, arsenic speciation
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