Reconstruction of early Cambrian ocean chemistry from Mo isotopes
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Intra-shelf basins, including the depositional site of the Zhongnan section, became anoxic or even euxinic.
“Intra-shelf basins, including the depositional site of the Zhongnan section, became anoxic or even euxinic, as suggested by the present and previous investigations18, 35.”
From Heterogenous oceanic redox conditions through the Ediacaran-Cambrian boundary limited the metazoan zonation (2017) · cites this paper as [35]
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Oceanic oxygenation events in the anoxic Ediacaran ocean
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“Most older Archean ORMs (3.4–2.7 Ga) have minimal Mo enrichments and δ98Mo values that are similar to or only slightly higher than igneous rocks.”
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“…deposited in early oceans suggest that late Neoproterozoic-early Cambrian oceans had similar seawater 98Mo to modern oceans (~2.3‰) (Lehmann et al., 2007; Wen et al., 2011, 2015; Kendall et al., 2015), which is consistent with full oxygenation of the oceans at that early stage (Chen et al., 2015).”
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Reorganisation of Earth’s biogeochemical cycles briefly oxygenated the oceans 520 Myr ago
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Black shale Mo isotope record reveals dynamic ocean redox during the Mesoproterozoic Era
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Meishucun phosphorite succession (SW China) records redox changes of the early Cambrian ocean
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Controls of discrepant REY enrichment in the early Cambrian phosphorites
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Self-citationStepwise oxygenation of early Cambrian ocean controls early metazoan diversification
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Early Cambrian ocean mixing recorded by phosphorite successions in the Nanhua Basin, South China
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“In fact, there is much evidence to suggest that deepwaters remained ferruginous in the late Neoproterozoic and possibly into the Palaeozoic (Dahl et al., 2010; Johnston et al., 2010; Li et al., 2010; Wen et al., 2015).”
BackgroundSalinity variation and hydrographic dynamics in the early Cambrian Nanhua Basin (South China)
Cheng, M., Zhang, Z., Jin, C., Wei, W., Wang, H., Algeo, T. J., & Li, C. (2023) · Science China Earth Sciences · doi:10.1007/s11430-022-1044-9 · Cited by 27 · see citing works
“…Cambrian Nanhua Basin (ECNB) in South China is one of the most intensively studied areas with regard to the Cambrian Explosion and its relationship to the oxygenation of Earth’s surface environments (e.g., Chen et al., 2015; Wen et al., 2015; Li et al., 2017; Wei et al., 2018; Cheng et al., 2020).”
BackgroundWei, W., Chen, X., Ling, H.-F., Wu, F., Dong, L.-H., Pan, S.-Q., Jing, Z., & Huang, F. (2023) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2022.117942 · Cited by 25 · see citing works
“…lower Niutitang, and lower Shuijingtuo Formations suggest that the ocean kept extensively oxygenated since ca. 551 Ma, and possibly reached the modern oxygenation level at ca. 521 Ma, in good agreement with the Mo and U isotope evidence (e.g., Wen et al., 2015; Chen et al., 2015; Wei et al., 2021).”
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Anomalously high enrichment of mercury in early Cambrian black shales in South China
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Oceanic chemistry recorded by cherts during the early Cambrian Explosion, South China
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“…data on early Cambrian environments, from which both recurrent water-column stratification (Canfield et al., 2008; Cremonese et al., 2013; Feng, Li, Huang, Chang, & Chu, 2014; Hammarlund et al., 2017; Wen, Fan, Zhang, Cloquet, & Carignan, 2015) and oxygenation (Chen et al., 2015) are inferred.”
BackgroundCr isotopic composition of the Laobao cherts during the Ediacaran–Cambrian transition in South China
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16 Good Golly, Why Moly? THE STABLE ISOTOPE GEOCHEMISTRY OF MOLYBDENUM
Kendall, B., Dahl, T. W., & Anbar, A. D. (2017) · De Gruyter eBooks · doi:10.1515/9783110545630-017 · Cited by 16 · see citing works
“The δ98Mo values in these 1282 ORMs are persistently high (2.1‰) and close to modern seawater (2.3‰), suggesting that 1283 expanded ocean anoxia was limited to the short duration (~100-200 kyr) of the warming events.”
BackgroundInfluentialHigh-precision molybdenum isotope analysis of low-Mo igneous rock samples by MC–ICP–MS
Fan, J., Li, J., Wang, Q., Zhang, L., Zhang, J., Zeng, X.-L., Ma, L., & Wang, Z. (2020) · Chemical Geology · doi:10.1016/j.chemgeo.2020.119648 · Cited by 27 · see citing works
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Tracking the evolution of seawater Mo isotopes through the Ediacaran–Cambrian transition
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Mo marine geochemistry and reconstruction of ancient ocean redox states
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Marine chemical structure during the Cambrian explosion
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Chemostratigraphy Across the Cretaceous‐Paleogene (K‐Pg) Boundary
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Precise Mo isotope ratio measurements of low-Mo (ng g −1 ) geological samples using MC-ICP-MS
Liu, J., Wen, H., Zhang, Y., Fan, H., & Zhu, C. (2016) · Journal of Analytical Atomic Spectrometry · doi:10.1039/c6ja00006a · Cited by 27 · see citing works
Self-citationNitrogen cycling and marine redox evolution during the Ediacaran–Cambrian transition
Chang, C., & Algeo, T. J. (2024) · Global and Planetary Change · doi:10.1016/j.gloplacha.2024.104679 · Cited by 13 · see citing works
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Self-citationXu, L.-G., Lehmann, B., Weyer, S., Wen, H., Mao, J., Neubert, N., & Jian, W. (2023) · Mineralium Deposita · doi:10.1007/s00126-023-01201-y · Cited by 13 · see citing works
“Molybdenum isotope measurements were done at the Institute of Geochemistry in Guiyang, China, with a Nu Plasma MC-ICP-MS following the methods of Wen et al. (2010, 2015).”
InfluentialSelf-citationZhang, Y.-N., Wang, Z.-W., Yang, X., Huang, L., Li, Y., & Qin, L. (2022) · Chemical Geology · doi:10.1016/j.chemgeo.2022.120812 · Cited by 13 · see citing works
Self-citationMolybdenum isotopic evidence for anoxic marine conditions during the end-Permian mass extinction
Zhang, Y.-X., Wen, H., Zhu, C.-W., Fan, H.-F., Xiao, J.-F., & Wen, J. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120259 · Cited by 13 · see citing works
Self-citationYao, C., Guo, W., Liu, J.-N., & Li, H. (2017) · International Journal of Geosciences · doi:10.4236/ijg.2017.88055 · Cited by 12 · see citing works
“Wen et al. (2015) reported δ98/95Mo values of early Cambrian black shales, which have a wide range of δ98/95Mo values (0.27‰ - 1.79‰) in carbonaceous shales and cherts (interval 1), and are from 0.11‰ to1.”
BackgroundMethodInfluentialMass Extinction Coincided With Expanded Continental Margin Euxinia During the Cambrian Age 4
Chang, C., Hu, W., Huang, K., Wang, Z., & Zhang, X. (2023) · Geophysical Research Letters · doi:10.1029/2023gl105560 · Cited by 13 · see citing works
“…black shales favoring euxinic sedimentary environments and require detailed investigation of local redox conditions using multiple proxies, such as iron speciation and redox-sensitive trace elements (e.g., Chen et al., 2015; Cheng et al., 2016; Ostrander et al., 2019; Wen et al., 2015).”
BackgroundMethodZhang, Q., Liu, E.-T., Pan, S., Wang, H., Jing, Z., Zhao, Z.-F., & Zhu, R. (2023) · Journal of Marine Science and Engineering · doi:10.3390/jmse11101907 · Cited by 11 · see citing works
Expanded deepwater euxinia recorded in the Ediacaran–Cambrian boundary interval in South China
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Developing a Rate Law for Ce(III) Oxidation by Manganese Oxides
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Chemostratigraphy as a Formal Stratigraphic Method
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“Mo is a redox‐sensitive element, scavenged from seawater into sediments in the form of MoSxO4−x 2−, under anoxic conditions [Wen et al., 2015].”
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Polymetallic mineralization in early Cambrian black shale: Insights from Guizhou, South China
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Coupling of shallow marine redox change and multi-stage animal radiations during the early Cambrian
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Self-citationDeep-water dissolved iron cycling and reservoir size across the Ediacaran-Cambrian transition
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“These include platform sections such as the Meishucun section (Wen et al., 2015), the Weng'an section (Jin et al.”
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Evidence for low sulfate and anoxic deep waters in early cambrian
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Rethinking Seawater Mo Isotope Mass‐Balance and the Sedimentary Mo Record
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“…al. (2017), Matthews et al. (2017), In sedimentary rocks from South China formed during these periods, Mo concentrations can approach wt % levels (e.g., Sahoo et al., 2016; Wen et al., 2015; Wille et al., 2008) and δ 98 Mo are sometimes lower than (cid:0) 2‰ (e.g., Ostrander, Sahoo, et al., 2019).”
InfluentialClemente, J. N. R., Fan, H., Ostrander, C. M., Zhang, H., Wen, H., Sperling, E. A., & Nielsen, S. G. (2025) · Geobiology · doi:10.1111/gbi.70028 · Cited by 4 · see citing works
“Contrary to previous suggestions of a shift to near-modern extents of marine oxygenation during Cambrian Age 3 (Chen et al. 2015; Li et al. 2021; Wen et al. 2015), the new Tl isotope data do not record modern extents of marine oxygenation as evidenced by modern Tl isotope compositions either…”
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- Authors
- Wen, H., Fan, H., Zhang, Y., Cloquet, C., & Carignan, J.
- Affiliations
- Chinese Academy of Sciences (CN)
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Wen, Hanjie
- Fan, Haifeng
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2015-09
- Volume
- 164
- Pages
- 1-16
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W307804840
- Cited by
- 131
- References
- 0
- Citations by year
- 2026: 7 · 2025: 21 · 2024: 14 · 2023: 13 · 2022: 10 · 2021: 14 · 2020: 13 · 2019: 6 · 2018: 12 · 2017: 13 · 2016: 3 · 2015: 5
- FWCI
- 8.34
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- HAL (submittedVersion)
- Funders
- 973 Program (2014CB440904)
- National Natural Science Foundation of China (40930425, 41173026, 41273024)
- CAS-SAFEA International Partnership Program for Creative Research Teams (KZZD-EW-TZ-20)
- State Key Laboratory of Ore-deposit Geochemistry, Chinese Academy of Sciences (SKLODG-ZY125-07)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Keywords
- molybdenum isotopes, Neoproterozoic-Cambrian transition, redox stratification, anoxic deep water, euxinia, ferruginous conditions, ocean circulation reorganization, Cambrian explosion, South China
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