Impacts of redox-mediator type on trace organic contaminants degradation by laccase: Degradation efficiency, laccase stability and effluent toxicity
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Activity of laccases increased with mediators such as ABTS, HBT, HPI, TEMPO, ACS, VA, SA, and vanillin.
“Activity of laccases increased with mediators such as ABTS (most widely used), 1-hydroxybenzotriazole (HBT), hydroxyphthalimide (HPI), 2,2,6,6-tetramethyl-1-piperidnyloxy (TEMPO), acetosyringone (ACS), violuric acid (VA), syringaldehyde (SA), and vanillin (VA) [15,267,276,277] (Table 7).”
From A Brief History of Colour, the Environmental Impact of Synthetic Dyes and Removal by Using Laccases (2021) · cites this paper as [267]
Mediators are low molecular weight compounds that upon oxidation generate cation radicals that oxidize more complex compounds through a redox cycle by mechanisms such as hydrogen atom transfer, electron transfer or ionic mechanisms.
“Mediators are low molecular weight compounds that oxidation, generate cation radicals that oxidize more complex compounds through a redox cycle by mechanisms such as hydrogen atom transfer, electron transfer or ionic mechanisms [20,267].”
From A Brief History of Colour, the Environmental Impact of Synthetic Dyes and Removal by Using Laccases (2021) · cites this paper as [267]
Each mediator requires different optimal conditions for reaction with a target compound and can oxidize the substrate by hydrogen atom transfer, electron transfer or ionic mechanisms.
“Each mediator requires different optimal conditions for reaction with a target compound and can oxidize the substrate by some of the three reported mechanisms (hydrogen atom transfer, electron transfer and ionic mechanisms) [267].”
From A Brief History of Colour, the Environmental Impact of Synthetic Dyes and Removal by Using Laccases (2021) · cites this paper as [267]
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- Authors
- Ashe, B., Nguyen, L. N., Hai, F. I., Lee, D.-J., van de Merwe, J. P., Leusch, F. D. L., Price, W. E., & Nghiem, L. D.
- Affiliations
- University of Wollongong (AU)
- National Taiwan University (TW)
- Corresponding author
- Hai, Faisal I.
- Venue
- International Biodeterioration & Biodegradation
- Publisher
- Elsevier BV
- Published
- 2016-09
- Volume
- 113
- Pages
- 169-176
- ISSN
- 0964-8305 (ISSN-L)
- OpenAlex
- W2371904355
- Cited by
- 133
- References
- 36
- Citations by year
- 2026: 2 · 2025: 14 · 2024: 14 · 2023: 14 · 2022: 20 · 2021: 16 · 2020: 14 · 2019: 22 · 2018: 5 · 2017: 10 · 2016: 2
- FWCI
- 15.23
- Type
- journal article
- Language
- en
- Open access
- green
- figshare.com
- Locations
- International Biodeterioration & Biodegradation (publishedVersion)
- Figshare (submittedVersion, cc-by)
- Research Online (University of Wollongong) (submittedVersion)
- Griffith Research Online (submittedVersion)
- Funders
- University of Wollongong
- GeoQuEST Research Centre
- Topics
- Life Sciences › Agricultural and Biological Sciences › Plant Science › Enzyme-mediated dye degradation
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Enzyme Catalysis and Immobilization
- Keywords
- laccase, redox mediators, trace organic contaminants, Pleurotus ostreatus, white-rot fungi, tempo, ABTS, violuric acid, 1-hydroxybenzotriazole, N-hydroxyphthalimide, syringaldehyde, vanillin, benzophenone-3, pentachlorophenol, naproxen, atrazine, phenolic compounds, effluent toxicity, free radical oxidation
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