The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Two-Dimensional Titanium and Molybdenum Carbide MXenes as Electrocatalysts for CO2 Reduction
Open accessAbstract
Electrocatalytic CO 2 reduction reaction (CO 2 RR) is an attractive way to produce renewable fuel and chemical feedstock, especially when coupled with efficient CO 2 capture and clean energy sources. On the fundamental side, research on improving CO 2 RR activity still revolves around late transition metal-based catalysts, which are limited by unfavorable scaling relations despite intense investigation. Here, we report a combined experimental and theoretical investigation into electrocatalytic CO 2 RR on Ti- and Mo-based MXene catalysts. Formic acid is found as the main product on Ti 2 CT x and Mo 2 CT x MXenes, with peak Faradaic efficiency of over 56% on Ti 2 CT x and partial current density of up to −2.5 mA cm −2 on Mo 2 CT x . Furthermore, simulations reveal the critical role of the T x group: a smaller overpotential is found to occur at lower amounts of –F termination. This work represents an important step toward experimental demonstration of MXenes for more complex electrocatalytic reactions in the future.
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What would it take for renewably powered electrosynthesis to displace petrochemical processes?
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Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
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Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution
Seh, Z. W., Fredrickson, K. D., Anasori, B., Kibsgaard, J., Strickler, A. L., Lukatskaya, M. R., Gogotsi, Y., Jaramillo, T. F., & Vojvodic, A. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00247 · Cited by 1,482
Self-citationHighly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
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Cited by
Lim, K. R. G., Handoko, A. D., Nemani, S. K., Wyatt, B., Jiang, H.-Y., Tang, J., Anasori, B., & Seh, Z. W. (2020) · ACS Nano · doi:10.1021/acsnano.0c05482 · Cited by 585
Self-citation2H-MoS2 on Mo2CTx MXene Nanohybrid for Efficient and Durable Electrocatalytic Hydrogen Evolution
Lim, K. R. G., Handoko, A. D., Johnson, L. R., Meng, X., Lin, M., Subramanian, G. S., Anasori, B., Gogotsi, Y., Vojvodic, A., & Seh, Z. W. (2020) · ACS Nano · doi:10.1021/acsnano.0c08671 · Cited by 267
Self-citationDensity functional theory studies of transition metal carbides and nitrides as electrocatalysts
Tian, D., Denny, S. R., Li, K., Wang, H., Kattel, S., & Chen, J. G. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00590a · Cited by 266
Metadata
- Authors
- Handoko, A. D., Chen, H., Lum, Y., Zhang, Q., Anasori, B., & Seh, Z. W.
- Venue
- iScience
- Publisher
- Elsevier BV
- Published
- 2020-06
- Volume
- 23
- Issue
- 6
- Pages
- 101181
- ISSN
- 2589-0042 (ISSN-L)
- OpenAlex
- W3026710733
- Cited by
- 190
- References
- 8
- FWCI
- 5.59
- Type
- journal article
- Language
- en
- Open access
- gold
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- Handoko, A. D., Chen, H., Lum, Y., Zhang, Q., Anasori, B., & Seh, Z. W. (2020). Two-Dimensional Titanium and Molybdenum Carbide MXenes as Electrocatalysts for CO2 Reduction. iScience. https://doi.org/10.1016/j.isci.2020.101181
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