Investigation of Epitaxial LaNiO3-x Thin Films by High-Energy XPS
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The La/Ni fluctuations are likely formed due to NiO evaporation and interaction of film surface with environment during heat treatment.
“These fluctuations are likely formed due to NiO evaporation and an interaction of the film surface with the environment during the heat treatment [50,51,52,53,54,55].”
From Control of Columnar Grain Microstructure in CSD LaNiO3 Films (2023) · cites this paper as [52]
The Results and discussion and Conclusions report oxide and hydroxide species in films aged in the atmosphere, with hydroxides concentrated near the surface. This supports interaction with the environment, but the paper does not link that interaction to La/Ni fluctuations or report NiO evaporation as a cause. Its film measurements concern long-term atmospheric aging, not heat treatment. (LLM, conf=0.84)
Experimental — accuracy not yet measuredThe film surface changes in composition due to NiO evaporation and interaction with atmosphere.
“As it was pointed earlier (see Figure 2), the film surface changes in composition due to NiO evaporation and interaction with the atmosphere [50,51,52,53,54,55].”
From Control of Columnar Grain Microstructure in CSD LaNiO3 Films (2023) · cites this paper as [52]
The Results and discussion and Conclusions report oxide and hydroxide species in LaNiO3-x films aged in atmosphere, with hydroxide concentrated near the surface. This supports atmospheric interaction affecting the surface, but the paper does not attribute a compositional change to NiO evaporation (searched: “NiO evaporation” and “evaporation of NiO”). (LLM, conf=0.86)
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Research works printed but not linked: 2
- V. Vengalis, A.K. Oginskas, V. Lisauskas, R. Butkutė, A. Maneikis, L. Dap- kus, V. Jasutis, N. Shiktorov, Thin Films Deposition of Oxide Multilayers. Industrial-Scale Processing: Proceedings of the International Conference, Vilnius, Lithuania, 2000, p. 45.
- J. Choisnet, N. Abadzhieva, P. Stefanov, D. Klissurski, J.M. Bas- sat, V. Rives, L. Minchev, J. Chem. Soc. Faraday Trans. 90 (1994) 1987.
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Duan, Z., Cui, Y., Yang, Z., Li, K., Wan, Y., Lu, Z., Xie, Y., & Zhang, J. (2018) · Ceramics International · doi:10.1016/j.ceramint.2017.09.230 · Cited by 32 · see citing works
Control of Columnar Grain Microstructure in CSD LaNiO3 Films
Atanova, A. V., Seregin, D. S., Zhigalina, O. M., Khmelenin, D. N., Orlov, G. A., Turkina, D. I., Sigov, A. S., & Vorotilov, K. A. (2023) · Molecules · doi:10.3390/molecules28041938 · Cited by 5 · see citing works
- Authors
- Mickevičius, S., Grebinskij, S., Bondarenka, V., Vengalis, B., Šliužienė, K., Orlowski, B. A., Osinniy, V., & Drube, W.
- Affiliations
- Center for Physical Sciences and Technology (LT)
- Institute of Physics (PL)
- Deutsches Elektronen-Synchrotron DESY (DE)
- Corresponding author
- Mickevičius, S.
- ORCID
- Drube, W.
- Venue
- Journal of Alloys and Compounds
- Publisher
- Elsevier BV
- Published
- 2006-10
- Volume
- 423
- Issue
- 1-2
- Pages
- 107-111
- ISSN
- 0925-8388 (ISSN-L)
- OpenAlex
- W2082673351
- Cited by
- 259
- References
- 0
- Citations by year
- 2026: 34 · 2025: 29 · 2024: 33 · 2023: 28 · 2022: 27 · 2021: 13 · 2020: 17 · 2019: 18 · 2018: 14 · 2017: 10 · 2016: 10 · 2015: 3 · 2014: 6 · 2013: 4 · 2012: 2
- FWCI
- 0.98
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Journal of Alloys and Compounds (publishedVersion)
- Desy Publications Database (Deutsches Elektronen-Synchrotron DESY) (submittedVersion, other-oa)
- Funders
- Deutsches Elektronen-Synchrotron
- Topics
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › Electron and X-Ray Spectroscopy Techniques
- Physical Sciences › Materials Science › Materials Chemistry › Electronic and Structural Properties of Oxides
- Physical Sciences › Physics and Astronomy › Radiation › X-ray Spectroscopy and Fluorescence Analysis
- Keywords
- epitaxial thin films, perovskite oxides, oxygen vacancies, hydroxyl groups, surface hydroxylation, adsorbed water, nickel valence state, reactive magnetron sputtering
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