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Alkaline residues and the environment: a review of impacts, management practices and opportunities.
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Around two billion tonnes of alkaline residues are produced globally each year by industries such as steel production, alumina refining and coal-fired power generation, with a total production estimate of 90 billion tonnes since industrialisation. These wastes are frequently stored in waste piles or landfills, and can be an environmental hazard if allowed to generate dust, or if rainwater infiltrates the waste. This review will focus on the environmental impacts associated with alkaline residues, with emphasis on the leachates produced by rainwater ingress. Many alkaline industrial wastes can produce leachates that are enriched with trace metals that form oxyanions (e.g. As, Cr, Mo, Se, V), which can be very mobile in alkaline water. The management options for the residues and their leachates are also discussed, distinguishing active and passive treatment options. Potential reuses of these materials, in construction materials, as agricultural amendments, and in environmental applications are identified. The mechanisms of carbon sequestration by alkaline residues are assessed, and the potential for enhancing its rate as a climate change off-setting measure for the industry is evaluated. The potential for recovery of metals critical to e-technologies, such as vanadium, cobalt, lithium and rare earths, from alkaline residues is considered. Finally research needs are identified, including the need to better understand the biogeochemistry of highly alkaline systems in order to develop predictable passive remediation and metal recovery technologies.
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“There are several estimates of the global quantities of suitable industrial wastes for mineral carbonation (e.g., Gomes et al., 2016), and suitable arisings are likely to be ≥2 Gt each year.”
From Mineralization Technology for Carbon Capture, Utilization, and Storage (2020) · cites this paper as Gomes et al., 2016
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Mineralization Technology for Carbon Capture, Utilization, and Storage
Hills, C. D., Tripathi, N., & Carey, P. J. (2020) · Frontiers in Energy Research · doi:10.3389/fenrg.2020.00142 · Cited by 180
Basic oxygen furnace slag: Review of current and potential uses
Naidu, T. S., Sheridan, C. M., & van Dyk, L. D. (2020) · Minerals Engineering · doi:10.1016/j.mineng.2020.106234 · Cited by 166
Metadata
- Authors
- Gomes, H. I., Mayes, W. M., Rogerson, M., Stewart, D. I., & Burke, I. T.
- Affiliations
- University of Hull (GB)
- University of Leeds (GB)
- Corresponding author
- Gomes, Helena I.
- Venue
- Journal of Cleaner Production
- Publisher
- Elsevier BV
- Published
- 2016-01
- Volume
- 112
- Pages
- 3571-3582
- ISSN
- 0959-6526 (ISSN-L)
- OpenAlex
- W2167622655
- Cited by
- 413
- References
- 5
- Citations by year
- 2026: 51 · 2025: 51 · 2024: 56 · 2023: 41 · 2022: 46 · 2021: 48 · 2020: 36 · 2019: 29 · 2018: 21 · 2017: 22 · 2016: 12
- FWCI
- 18.01
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Journal of Cleaner Production (publishedVersion, cc-by-nc-nd)
- Repository@Nottingham (University of Nottingham) (publishedVersion, other-oa)
- White Rose Research Online (University of Leeds, The University of Sheffield, University of York) (acceptedVersion)
- Northumbria Research Link (Northumbria University) (acceptedVersion)
- Repository@Hull (Worktribe) (University of Hull) (submittedVersion, cc-by-nc-nd)
- Repository@Nottingham (University of Nottingham) (submittedVersion, cc-by-nc-nd)
- Funders
- Natural Environment Research Council (NE/L014211/1, NE/K015648/1, NE/L01405X/1)
- Topics
- Physical Sciences › Environmental Science › Waste Management and Disposal › Bauxite Residue and Utilization
- Physical Sciences › Environmental Science › Waste Management and Disposal › Waste Management and Environmental Impact
- Physical Sciences › Engineering › Building and Construction › Recycling and utilization of industrial and municipal waste in materials production
- Keywords
- leachate, steel slag, coal ash, passive remediation, carbon sequestration, metal recovery, vanadium, rare earth elements, critical metals, waste reuse
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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