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Adsorptive performance of MOF nanocomposite for methylene blue and malachite green dyes: Kinetics, isotherm and mechanism

Alqadami, Ayoub Abdullah, Naushad, Mu., Alothman, Z.A., Ahamad, Tansir·2018·Journal of Environmental Management

Abstract

In the present study, Fe3O4@AMCA-MIL-53(Al) nanocomposite was utilized for the adsorptive removal of highly toxic MB and MG dyes from aqueous environment. The batch adsorption tests were performed at different contact time, pH, Fe3O4@AMCA-MIL-53(Al) dose, initial concentration of dyes and temperature. The maximum adsorption capacity of MB and MG dyes onto of Fe3O4@AMCA-MIL-53(Al) using Langmuir equation was 1.02 and 0.90 m mol/g, respectively. The isotherm and kinetic studies revealed that adsorption data were well fitted to Langmuir isotherm and pseudo-first-order kinetics models. Various thermodynamic parameters were also calculated and interpreted. The positive and negative values of ΔH° and ΔG° indicated that the adsorption was endothermic and spontaneous, respectively. The adsorptive binding of MB and MG on Fe3O4@AMCA-MIL53(Al) nanocomposite was directed by carboxylate and amide groups through electrostatic interaction, π-π interaction and hydrogen bonding. The desorption of both dyes from Fe3O4@AMCA-MIL-53(Al) was also performed using mixed solution of 0.01 M HCl/ethanol. Thus, we conclude that the Fe3O4@AMCA-MIL-53(Al) was an outstanding material for the removal of dyes from aqueous environment.

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Metadata

Authors
Alqadami, A. A., Naushad, M., Alothman, Z. A., & Ahamad, T.
Venue
Journal of Environmental Management
Publisher
Elsevier BV
Published
2018-10
Volume
223
Pages
29-36
ISSN
0301-4797 (ISSN-L)
OpenAlex
W2807441849
Cited by
390
References
3
FWCI
20.26
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Adsorptive performance of MOF nanocomposite for methylene blue and malachite green dyes: Kinetics, isotherm and mechanism. https://app.cochat.ai/papers/10.1016/j.jenvman.2018.05.090
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Alqadami, A. A., Naushad, M., Alothman, Z. A., & Ahamad, T. (2018). Adsorptive performance of MOF nanocomposite for methylene blue and malachite green dyes: Kinetics, isotherm and mechanism. Journal of Environmental Management. https://doi.org/10.1016/j.jenvman.2018.05.090

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