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Characterization and antimicrobial activity studies of polypropylene films with carvacrol and thymol for active packaging
Abstract
Antimicrobial active films based on polypropylene (PP) were prepared by incorporating thymol and carvacrol at three different concentrations: 4, 6 and 8wt.% of both additives as well as an equimolar mixture of them. A complete thermal, structural, mechanical and functional characterization of all formulations was carried out. SEM micrographs showed certain porosity for films with high additives concentrations. A decrease in elastic modulus was obtained for the active formulations compared with neat PP. The presence of additives did not affect the thermal stability of PP samples, but decreased PP crystallinity and oxygen barrier properties. The presence of thymol and carvacrol also increased stabilization against thermo-oxidative degradation, with higher oxidation induction parameters. Finally, thymol showed higher inhibition against bacterial strain present in food compared with carvacrol, leading to higher antimicrobial activity. The obtained results proved the permanence of certain amounts of the studied additives in the polymer matrix after processing making them able to be used as active additives in PP formulations.
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The pH of the film-forming solution affects the release of carvacrol and thymol from edible starch films.
“In this case, amylose polymer and pH affect the release of carvacrol and thymol due to many factors like electrostatic interactions, osmosis, structural changes, and environmental conditions [19,33].”
From Starch Edible Films/Coatings Added with Carvacrol and Thymol: In Vitro and In Vivo Evaluation against Colletotrichum gloeosporioides (2021) · cites this paper as [19]
Citations
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Active packaging by extrusion processing of recyclable and biodegradable polymers
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Cited by
Sorted by citations
Ochoa-Velasco, C. E., Pérez-Pérez, J. C., Varillas-Torres, J. M., Navarro-Cruz, A. R., Hernández-Carranza, P., Munguía-Pérez, R., Cid-Pérez, T. S., & Avila-Sosa, R. (2021) · Foods · doi:10.3390/foods10010175 · Cited by 61
“An inconvenience of EO direct application on food surfaces by dipping, powdering or spraying; is that antimicrobial compounds can be neutralized, evaporated or rapidly diffused from the surface into the product [18,19].”
Background
Metadata
- Authors
- Ramos, M., Jiménez, A., Peltzer, M., & Garrigós, M. C.
- Affiliations
- University of Alicante (ES)
- Corresponding author
- Ramos, Marina
- Venue
- Journal of Food Engineering
- Publisher
- Elsevier BV
- Published
- 2012-04
- Volume
- 109
- Issue
- 3
- Pages
- 513-519
- ISSN
- 0260-8774 (ISSN-L)
- OpenAlex
- W2036547928
- Cited by
- 403
- References
- 2
- Citations by year
- 2026: 12 · 2025: 19 · 2024: 22 · 2023: 17 · 2022: 34 · 2021: 41 · 2020: 39 · 2019: 27 · 2018: 28 · 2017: 44 · 2016: 29 · 2015: 43 · 2014: 23 · 2013: 19 · 2012: 6
- FWCI
- 6.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Food Engineering (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › Nanocomposite Films for Food Packaging
- Life Sciences › Immunology and Microbiology › Applied Microbiology and Biotechnology › Antimicrobial agents and applications
- Life Sciences › Agricultural and Biological Sciences › Food Science › Essential Oils and Antimicrobial Activity
- Keywords
- polypropylene film, carvacrol, thymol, active packaging, antimicrobial activity, essential oils, food packaging, crystallinity, oxygen barrier properties, thermal stability, oxidation induction time, elastic modulus, porosity, bacterial growth inhibition
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