Utilization of rice husk ash as silica source for the synthesis of mesoporous silicas and their application to CO2 adsorption through TREN/TEPA grafting
Abstract
Mesoporous MCM-41, MCM-48 and SBA-15 were synthesized using Rice husk ash (RHA) as the silica source and their defective Si-OH sites were functionalized by 3-chloropropyltrimethoxysilane (CPTMS) which was subsequently grafted with amine compounds, Tris(2-aminoethyl)amine (TREN) and Tetraethylenepentamine (TEPA). X-ray powder diffraction (XRD) and BET results of the parent mesoporous silica suggested their closeness of structural properties to those obtained from conventional silica sources. CO(2) adsorption of branched amine TREN and straight chain amine TEPA at 25, 50 and 75 degrees C was obtained by Thermogravimetric Analyser (TGA) at atmospheric pressure. TREN grafted mesoporous silica showed 7% of CO(2) adsorption while TEPA grafted mesoporous silicas showed less CO(2) adsorption, which is due to the presence of isolated amine groups in TREN. TREN grafted mesoporous silicas were also observed to be selective towards CO(2), thermally stable and recyclable. The order of CO(2) adsorption with respect to amount of amine grafting was observed to be MCM-48/TREN>MCM-41/TREN>SBA-15/TREN.
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Self-citation
- Authors
- Bhagiyalakshmi, M., Yun, L. J., Anuradha, R., & Jang, H. T.
- Affiliations
- Hanseo University (KR)
- Corresponding author
- Jang, Hyun Tae
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2010-03
- Volume
- 175
- Issue
- 1-3
- Pages
- 928-938
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W2076301705
- Cited by
- 236
- References
- 46
- Citations by year
- 2026: 8 · 2025: 9 · 2024: 9 · 2023: 12 · 2022: 13 · 2021: 10 · 2020: 22 · 2019: 22 · 2018: 11 · 2017: 24 · 2016: 9 · 2015: 17 · 2014: 16 · 2013: 17 · 2012: 12
- FWCI
- 24.69
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Hazardous Materials (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- rice husk ash, mesoporous silica, CO2 adsorption, TREN, TEPA, amine grafting, 3-chloropropyltrimethoxysilane, MCM-41, MCM-48, SBA-15, silica source, CO2 capture, adsorbent reusability
- MeSH terms
- Adsorption, Amines, Carbon Dioxide, Ethylenediamines, Models, Chemical, Nitrogen, Magnetic Resonance Spectroscopy, Oryza, Silanes, Silicon Dioxide, Temperature, Thermogravimetry, X-Ray Diffraction, Porosity
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