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Degradation of antipyrine by UV, UV/H2O2 and UV/PS
Abstract
Degradation of antipyrine (AP) in water by three UV-based photolysis processes (i.e., direct UV, UV/H₂O₂, UV/persulfate (UV/PS)) was studied. For all the oxidation processes, the AP decomposition exhibited a pseudo-first-order kinetics pattern. Generally, UV/H₂O₂ and UV/PS significantly improved the degradation rate relevant to UV treatment alone. The pseudo-first-order degradation rate constants (kobs) were, to different degrees, affected by initial AP concentration, oxidant dose, pH, UV irradiation intensity, and co-existing chemicals such as humic acid, chloride, bicarbonate, carbonate and nitrate. The three oxidation processes followed the order in terms of treatment costs: UV/PS>UV>UV/H₂O₂ if the energy and chemical costs are considered. Finally, the AP degradation pathways in the UV/H₂O₂ and UV/PS processes are proposed. Results demonstrated that UV/H₂O₂ and UV/PS are potential alternatives to control water pollution caused by emerging contaminants such as AP.
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“Tan et al. compared the effect of carbonate species in various UV-based AOPs for the degradation of antipyrine. The rate constant for the degradation in the UV system without HCO3 -addition was 1.455 ± 0.005 h -1 . A slight decrease in the rate to 1.4 h -1 was observed with the addition of 200 mM HCO3 -. In the UV/H2O2 system, the rate constant was 1.99 h -1 , and it was decreased to 1.27 h -1 in”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [128]
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Metadata
- Authors
- Tan, C., Gao, N., Deng, Y., Zhang, Y., Sui, M., Deng, J., & Zhou, S.
- Affiliations
- Tongji University (CN)
- Corresponding author
- Gao, Naiyun
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2013-09
- Volume
- 260
- Pages
- 1008-1016
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W1967091842
- Cited by
- 314
- References
- 44
- Citations by year
- 2026: 10 · 2025: 15 · 2024: 27 · 2023: 27 · 2022: 27 · 2021: 24 · 2020: 35 · 2019: 37 · 2018: 36 · 2017: 19 · 2016: 32 · 2015: 12 · 2014: 11 · 2013: 2
- FWCI
- 15.82
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Hazardous Materials (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (51178321)
- National Major Project of Science & Technology Ministry of China (2012ZX07403-001)
- Ministry of Housing and Urban-Rural Development (2009-K7-4)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Water Treatment and Disinfection
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Keywords
- antipyrine, UV/H2O2, UV/persulfate, UV photolysis, advanced oxidation processes, pseudo-first-order kinetics, degradation pathways, emerging contaminants, pharmaceuticals in water, treatment cost comparison, humic acid effects
- MeSH terms
- Anions, Antipyrine, Bicarbonates, Chlorides, Equipment Design, Humic Substances, Hydrogen Peroxide, Hydrogen-Ion Concentration, Kinetics, Nitrates, Photolysis, Sulfates, Time Factors, Ultraviolet Rays, Water Pollutants, Chemical, Oxidants, Sodium Compounds, Water Purification
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
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