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Degradation of antipyrine by UV, UV/H2O2 and UV/PS
Abstract
Degradation of antipyrine (AP) in water by three UV-based photolysis processes (i.e., direct UV, UV/H₂O₂, UV/persulfate (UV/PS)) was studied. For all the oxidation processes, the AP decomposition exhibited a pseudo-first-order kinetics pattern. Generally, UV/H₂O₂ and UV/PS significantly improved the degradation rate relevant to UV treatment alone. The pseudo-first-order degradation rate constants (kobs) were, to different degrees, affected by initial AP concentration, oxidant dose, pH, UV irradiation intensity, and co-existing chemicals such as humic acid, chloride, bicarbonate, carbonate and nitrate. The three oxidation processes followed the order in terms of treatment costs: UV/PS>UV>UV/H₂O₂ if the energy and chemical costs are considered. Finally, the AP degradation pathways in the UV/H₂O₂ and UV/PS processes are proposed. Results demonstrated that UV/H₂O₂ and UV/PS are potential alternatives to control water pollution caused by emerging contaminants such as AP.
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“Tan et al. compared the effect of carbonate species in various UV-based AOPs for the degradation of antipyrine. The rate constant for the degradation in the UV system without HCO3 -addition was 1.455 ± 0.005 h -1 . A slight decrease in the rate to 1.4 h -1 was observed with the addition of 200 mM HCO3 -. In the UV/H2O2 system, the rate constant was 1.99 h -1 , and it was decreased to 1.27 h -1 in”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [128]
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Self-citation
Metadata
- Authors
- Tan, C., Gao, N., Deng, Y., Zhang, Y., Sui, M., Deng, J., & Zhou, S.
- Affiliations
- Tongji University (CN)
- Corresponding author
- Gao, Naiyun
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2013-09
- Volume
- 260
- Pages
- 1008-1016
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W1967091842
- Cited by
- 314
- References
- 44
- Citations by year
- 2026: 10 · 2025: 15 · 2024: 27 · 2023: 27 · 2022: 27 · 2021: 24 · 2020: 35 · 2019: 37 · 2018: 36 · 2017: 19 · 2016: 32 · 2015: 12 · 2014: 11 · 2013: 2
- FWCI
- 15.82
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Hazardous Materials (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (51178321)
- National Major Project of Science & Technology Ministry of China (2012ZX07403-001)
- Ministry of Housing and Urban-Rural Development (2009-K7-4)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Water Treatment and Disinfection
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Keywords
- antipyrine, UV/H2O2, UV/persulfate, UV photolysis, advanced oxidation processes, pseudo-first-order kinetics, degradation pathways, emerging contaminants, pharmaceuticals in water, treatment cost comparison, humic acid effects
- MeSH terms
- Anions, Antipyrine, Bicarbonates, Chlorides, Equipment Design, Humic Substances, Hydrogen Peroxide, Hydrogen-Ion Concentration, Kinetics, Nitrates, Photolysis, Sulfates, Time Factors, Ultraviolet Rays, Water Pollutants, Chemical, Oxidants, Sodium Compounds, Water Purification
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