RETRACTED: Incorporation of UiO-66-NH2 MOF into the PAN/chitosan nanofibers for adsorption and membrane filtration of Pb(II), Cd(II) and Cr(VI) ions from aqueous solutions
Abstract
In the present study, the UiO-66-NH 2 MOF synthesized by microwave heating method was incorporated into the PAN/chitosan nanofibers for the removal of Pb(II), Cd(II) and Cr(VI) ions through the adsorption and membrane filtration processes. The synthesized MOFs and nanofibers were characterized using XRD, BET, FTIR, SEM, and DSC analysis. The effect of UiO-66-NH 2 MOF content (0-15 wt.%), pH (2-7), contact time(5-90 min), metal ions initial concentration (20-1000 mg/L) and temperature (25-45 °C) was studied on the metal ions adsorption using PAN/chitosan/UiO-66-NH 2 nanofibrous adsorbent. The kinetic, isotherm and thermodynamic parameters were evaluated to understand the metal ions adsorption mechanism using nanofibers. The Pseudo-second-order kinetic and Redlich-Peterson isotherm model were well described the experimental sorption data. In the heavy metal ions membrane filtration process, the different parameters such as MOF concentration (2-15 wt.%), membrane thickness (10-70 μm), metal ions concentration (5-50 mg/L), temperature (25-45 °C) and filtration time (1-24 h) were investigated on the performance of PVDF/ PAN/chitosan/UiO-66-NH 2 nanofibrous membrane toward metal ions removal. The high water flux and high metal ions removal within 18 h filtration time showed the high potential of PVDF/ PAN/chitosan/UiO-66-NH 2 membrane for the removal of metal ions from aqueous solutions.
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The zirconium-MOFs family is promising nanostructure materials for sorption applications due to easy incorporation of functional groups and hydrolytic-thermal stability.
“Zirconium-MOFs family (such as UiO-66) is promising nanostructure materials for sorption applications due to the easy incorporation of functional groups and hydrolytic-thermal stability such as amine, carboxylic, hydroxyl, and oxygen 35 or by using the cross-linking method 36 .”
From Removal of heavy metal ions from wastewater: a comprehensive and critical review (2021) · cites this paper as [35]
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- Authors
- Jamshidifard, S., Koushkbaghi, S., Hosseini, S., Rezaei, S., Karamipour, A., Jafari rad, A., & Irani, M.
- Affiliations
- Iran University of Science and Technology (IR)
- Islamic Azad University, Yazd (IR)
- Babol Noshirvani University of Technology (IR)
- Amirkabir University of Technology (IR)
- University of Tehran (IR)
- Islamic Azad University, Tehran (IR)
- Corresponding author
- Irani, Mohammad
- ORCID
- Irani, Mohammad
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2019-04
- Volume
- 368
- Pages
- 10-20
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W2910441369
- Cited by
- 540
- References
- 57
- Citations by year
- 2026: 29 · 2025: 69 · 2024: 81 · 2023: 78 · 2022: 100 · 2021: 87 · 2020: 70 · 2019: 25
- FWCI
- 25.50
- Type
- journal article
- Language
- en
- Status
- Retracted
- Update notices
- Open access
- closed
- Locations
- Journal of Hazardous Materials (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Environmental Science › Water Science and Technology › Membrane Separation Technologies
- Keywords
- UiO-66-NH2, metal-organic frameworks, nanofibrous membranes, heavy metal adsorption, lead removal, cadmium removal, hexavalent chromium removal, PVDF membranes, microwave-assisted synthesis, adsorption kinetics, adsorption isotherms, adsorption thermodynamics, water treatment
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