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Cited by 221

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Recycling of cathode from spent lithium iron phosphate batteries

Open access
Yadav, Prasad, Jie, Chan Jun, Tan, Shermaine, Srinivasan, Madhavi·2020·Journal of Hazardous Materials

Abstract

We demonstrate the concept of fabricating new lithium ion batteries from recycled spent 18650 lithium ion batteries (LIB). LiFePO4 cathode was extracted from these spent LIB using combined approach of pre-treatment, mechanical treatment and hydrometallurgical process wherein weak organic acids, such as methyl sulfonic acid (MSA) and p-toluene sulfonic acid (TSA), were employed for the first time for leaching at room temperature of metal ions instead of conventional strong acids. High leaching efficiencies (95%) were obtained for extraction of Li and Fe using these acids from black mass. Reuse of these extracted metal ions is also demonstrated by precipitating them and synthesizing LiFePO4 cathode. Structural characterization showed the formation of single-phase LiFePO4 and electrochemical evaluation of this cathode in a LiFePO4/Li half-cell exhibited a capacity of 93 mA h/g and 80 mA h/g at 0.2C and 1C rate respectively with good cycle stability.

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Metadata

Authors
Yadav, P., Jie, C. J., Tan, S., & Srinivasan, M.
Venue
Journal of Hazardous Materials
Publisher
Elsevier BV
Published
2020-11
Volume
399
Pages
123068
ISSN
0304-3894 (ISSN-L)
OpenAlex
W3031239933
Cited by
221
References
2
FWCI
10.90
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Recycling of cathode from spent lithium iron phosphate batteries. https://app.cochat.ai/papers/10.1016/j.jhazmat.2020.123068
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Yadav, P., Jie, C. J., Tan, S., & Srinivasan, M. (2020). Recycling of cathode from spent lithium iron phosphate batteries. Journal of Hazardous Materials. https://doi.org/10.1016/j.jhazmat.2020.123068

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.