High-Entropy Alloys as a Discovery Platform for Electrocatalysis

Nanostructured High‐Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes

Yeh, J. ‐., Chen, S. ‐., Lin, S. ‐., Gan, J. ‐., Chin, T. ‐., Shun, T. ‐., Tsau, C. ‐., & Chang, S. ‐. (2004) · Advanced Engineering Materials · doi:10.1002/adem.200300567 · Cited by 15,281 · see citing works

Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode

Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153 · see citing works

Microstructural development in equiatomic multicomponent alloys

Cantor, B., Chang, I. T. H., Knight, P., & Vincent, A. J. B. (2004) · Materials Science and Engineering A · doi:10.1016/j.msea.2003.10.257 · Cited by 10,215 · see citing works

A critical review of high entropy alloys and related concepts

Miracle, D. B., & Senkov, O. N. (2016) · Acta Materialia · doi:10.1016/j.actamat.2016.08.081 · Cited by 9,065 · see citing works

Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals

Hammer, B., Hansen, L. B., & Nørskov, J. K. (1999) · Physical Review B · doi:10.1103/physrevb.59.7413 · Cited by 8,270 · see citing works

The atomic simulation environment—a Python library for working with atoms

Larsen, A. H., Mortensen, J. J., Blomqvist, J., Castelli, I. E., Christensen, R., Dułak, M., Friis, J., Groves, M. N., Hammer, B., Hargus, C., et al. (2017) · Journal of Physics Condensed Matter · doi:10.1088/1361-648x/aa680e · Cited by 4,549 · see citing works

Improved Oxygen Reduction Activity on Pt ₃ Ni(111) via Increased Surface Site Availability

Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421 · see citing works

Theoretical surface science and catalysis—calculations and concepts

Hammer, B., & Nørskov, J. K. (2000) · Advances in Catalysis · doi:10.1016/s0360-0564(02)45013-4 · Cited by 3,972 · see citing works

Solid‐Solution Phase Formation Rules for Multi‐component Alloys

Zhang, Y., Zhou, Y., Lin, J., Chen, G. L., & Liaw, P. K. (2008) · Advanced Engineering Materials · doi:10.1002/adem.200700240 · Cited by 3,484 · see citing works

Alloys of platinum and early transition metals as oxygen reduction electrocatalysts

Greeley, J., Stephens, I. E. L., Bondarenko, A. S., Johansson, T. P., Hansen, H. A., Jaramillo, T. F., Rossmeisl, J., Chorkendorff, I., & Nørskov, J. K. (2009) · Nature Chemistry · doi:10.1038/nchem.367 · Cited by 3,203 · see citing works

Prediction of high-entropy stabilized solid-solution in multi-component alloys

Yang, X. M., & Zhang, Y. (2012) · Materials Chemistry and Physics · doi:10.1016/j.matchemphys.2011.11.021 · Cited by 2,950 · see citing works

Vegard’s law

Denton, A. R., & Ashcroft, N. W. (1991) · Physical Review A · doi:10.1103/physreva.43.3161 · Cited by 2,606 · see citing works

Electronic structure calculations with GPAW: a real-space implementation of the projector augmented-wave method

Enkovaara, J., Rostgaard, C., Mortensen, J. J., Chen, J., Dułak, M., Ferrighi, L., Gavnholt, J., Glinsvad, C., Haikola, V., Hansen, H. A., et al. (2010) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/22/25/253202 · Cited by 2,196 · see citing works

Real-space grid implementation of the projector augmented wave method

Mortensen, J. J., Hansen, L. B., & Jacobsen, K. W. (2005) · Physical Review B · doi:10.1103/physrevb.71.035109 · Cited by 2,050 · see citing works

Carbothermal shock synthesis of high-entropy-alloy nanoparticles

Yao, Y.-G., Huang, Z.-N., Xie, P.-F., Lacey, S., Jacob, R., Xie, H., Chen, F.-J., Nie, A.-M., Pu, T., Rehwoldt, M. C., et al. (2018) · Science · doi:10.1126/science.aan5412 · Cited by 1,742 · see citing works

Effects of Al addition on the microstructure and mechanical property of AlxCoCrFeNi high-entropy alloys

Wang, W.-R., Wang, W., Wang, S.-C., Tsai, Y.-C., Lai, C.-H., & Yeh, J. (2012) · Intermetallics · doi:10.1016/j.intermet.2012.03.005 · Cited by 1,524 · see citing works

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen

Alayoǧlu, S., Nilekar, A. U., Mavrikakis, M., & Eichhorn, B. W. (2008) · Nature Materials · doi:10.1038/nmat2156 · Cited by 1,244 · see citing works

Understanding the electrocatalysis of oxygen reduction on platinum and its alloys

Stephens, I. E. L., Bandarenka, A. S., Vej-Hansen, U. G., Rossmeisl, J., & Chorkendorff, I. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03590a · Cited by 1,179 · see citing works

Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction

Escudero-Escribano, M., Malacrida, P., Hansen, M. H., Vej-Hansen, U. G., Velázquez-Palenzuela, A., Tripkovic, V., Schiøtz, J., Rossmeisl, J., Stephens, I. E. L., & Chorkendorff, I. (2016) · Science · doi:10.1126/science.aad8892 · Cited by 1,057 · see citing works

Surface segregation energies in transition-metal alloys

Ruban, A. V., Skriver, H. L., & Nørskov, J. K. (1999) · Physical review. B, Condensed matter · doi:10.1103/physrevb.59.15990 · Cited by 1,033 · see citing works

Finding optimal surface sites on heterogeneous catalysts by counting nearest neighbors

Calle‐Vallejo, F., Tymoczko, J., Čolić, V., Vũ, Q. H., Pohl, M. D., Morgenstern, K., Loffreda, D., Sautet, P., Schuhmann, W. W., & Bandarenka, A. S. (2015) · Science · doi:10.1126/science.aab3501 · Cited by 944 · see citing works

Introducing structural sensitivity into adsorption–energy scaling relations by means of coordination numbers

Calle‐Vallejo, F., Loffreda, D., Koper, M. T. M., & Sautet, P. (2015) · Nature Chemistry · doi:10.1038/nchem.2226 · Cited by 834 · see citing works

Catalyst Design by Interpolation in the Periodic Table: Bimetallic Ammonia Synthesis Catalysts

Jacobsen, C. J. H., Dahl, S., Clausen, B. S., Bahn, S. R., Logadóttir, Á., & Nørskov, J. K. (2001) · Journal of the American Chemical Society · doi:10.1021/ja010963d · Cited by 832 · see citing works

Role of Steps in N 2 Activation on Ru(0001)

Dahl, S., Logadóttir, Á., Egeberg, R. C., Larsen, J. H., Chorkendorff, I., Törnqvist, E., & Nørskov, J. K. (1999) · Physical Review Letters · doi:10.1103/physrevlett.83.1814 · Cited by 789 · see citing works

Water adsorption and the wetting of metal surfaces

Hodgson, A., & Haq, S. (2009) · Surface Science Reports · doi:10.1016/j.surfrep.2009.07.001 · Cited by 779 · see citing works

Discovery of a Multinary Noble Metal–Free Oxygen Reduction Catalyst

Löffler, T., Meyer, H., Savan, A., Wilde, P., Manjón, A. G., Chen, Y., Ventosa, E., Scheu, C., Ludwig, A., & Schuhmann, W. W. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201802269 · Cited by 379 · see citing works

Hume-Rothery Rules for Structurally Complex Alloy Phases

Mizutani, U. (2010) · CRC Press eBooks · doi:10.1201/b10324 · Cited by 279 · see citing works

First hexagonal close packed high-entropy alloy with outstanding stability under extreme conditions and electrocatalytic activity for methanol oxidation

Yusenko, K. V., Riva, S., Carvalho, P. A., Yusenko, M. V., Arnaboldi, S., Sukhikh, A. S., Hanfland, M., & Gromilov, S. А. (2017) · Scripta Materialia · doi:10.1016/j.scriptamat.2017.05.022 · Cited by 256 · see citing works

High Throughput Experimental and Theoretical Predictive Screening of Materials − A Comparative Study of Search Strategies for New Fuel Cell Anode Catalysts

Strasser, P., Fan, Q., Devenney, M., Weinberg, W. H., Liu, P., & Nørskov, J. K. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp030508z · Cited by 255 · see citing works

Mechanism of electrochemical oxidation of ammonia

Bunce, N. J., & Bejan, D. (2011) · Electrochimica Acta · doi:10.1016/j.electacta.2011.07.078 · Cited by 255 · see citing works

Steady state oxygenreduction and cyclic voltammetry

Rossmeisl, J., Karlberg, G. S., Jaramillo, T. F., & Nørskov, J. K. (2008) · Faraday Discussions · doi:10.1039/b802129e · Cited by 251 · see citing works

Recent advances in electrocatalysts for electro-oxidation of ammonia

Zhong, C. M., Hu, W., & Cheng, Y. F. (2012) · Journal of Materials Chemistry A · doi:10.1039/c2ta00607c · Cited by 242 · see citing works

Toward an Active and Stable Catalyst for Oxygen Evolution in Acidic Media: Ti‐Stabilized MnO2

Frydendal, R., Paoli, E. A., Chorkendorff, I., Rossmeisl, J., & Stephens, I. E. L. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500991 · Cited by 229 · see citing works

Development of a novel high-entropy alloy with eminent efficiency of degrading azo dye solutions

Lv, Z. Y., Liu, X. J., Jia, B., Wang, H., Wu, Y., & Lü, Z. (2016) · Scientific Reports · doi:10.1038/srep34213 · Cited by 183 · see citing works

Orbitalwise Coordination Number for Predicting Adsorption Properties of Metal Nanocatalysts

Ma, X., & Xin, H. (2017) · Physical Review Letters · doi:10.1103/physrevlett.118.036101 · Cited by 172 · see citing works

Learning from Data: A Short Course

Abu‐Mostafa, Y. S., Magdon‐Ismail, M., & Lin, H.-T. (2012) · Cited by 149 · see citing works

Multi-component nanoporous platinum–ruthenium–copper–osmium–iridium alloy with enhanced electrocatalytic activity towards methanol oxidation and oxygen reduction

Chen, X., Si, C., Gao, Y., Frenzel, J. A., Sun, J., Eggeler, G., & Zhang, Z. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.09.076 · Cited by 125 · see citing works

Electrochemical oxidation of ammonia in alkaline solutions: its application to an amperometric sensor

de Mishima, B. A. L., Lescano, D. E., Holgado, T. M., & Mishima, H. T. (1998) · Electrochimica Acta · doi:10.1016/s0013-4686(97)00061-3 · Cited by 117 · see citing works

Elucidation of the Oxygen Reduction Volcano in Alkaline Media using a Copper–Platinum(111) Alloy

Jensen, K. D., Tymoczko, J., Rossmeisl, J., Bandarenka, A. S., Chorkendorff, I., Escudero‐Escribano, M., & Stephens, I. E. L. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201711858 · Cited by 93 · see citing works

Quantifying Uncertainty in Activity Volcano Relationships for Oxygen Reduction Reaction

Deshpande, S., Kitchin, J. R., & Viswanathan, V. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00509 · Cited by 87 · see citing works

Recent progress in the structure control of Pd–Ru bimetallic nanomaterials

Wu, D., Kusada, K., & Kitagawa, H. (2016) · Science and Technology of Advanced Materials · doi:10.1080/14686996.2016.1221727 · Cited by 67 · see citing works

Trends of Oxygen Reduction Reaction on Platinum Alloys: A Computational and Experimental Study

Lin, S.-P., Wang, K., Liu, C.-W., Chen, H.-S., & Wang, J. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b02849 · Cited by 56 · see citing works

Oxygen Reduction on Structurally Well Defined, Bimetallic PtRu Surfaces: Monolayer PtxRu1−x/Ru(0001) Surface Alloys Versus Pt Film Covered Ru(0001)

Brimaud, S., Engstfeld, A. K., Alves, O. B., Hoster, H. E., & Behm, R. J. (2013) · Topics in Catalysis · doi:10.1007/s11244-013-0177-0 · Cited by 43 · see citing works

Acetylene Adsorption on Pd–Ag Alloys: Evidence for Limited Island Formation and Strong Reverse Segregation from Monte Carlo Simulations

Vignola, E., Steinmann, S. N., Mapihan, K. L., Vandegehuchte, B. D., Curulla‐Ferré, D., & Sautet, P. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b04108 · Cited by 42 · see citing works

Effect of Atomic Vacancies on the Structure and the Electrocatalytic Activity of Pt‐rich/C Nanoparticles: A Combined Experimental and Density Functional Theory Study

Bacq, O. L., Pasturel, A., Chattot, R., Previdello, B. A. F., Nelayah, J., Asset, T., Dubau, L., & Maillard, F. M. (2017) · ChemCatChem · doi:10.1002/cctc.201601672 · Cited by 29 · see citing works

Formulating the bonding contribution equation in heterogeneous catalysis: a quantitative description between the surface structure and adsorption energy

Wang, Z., & Hu, P. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp08493a · Cited by 21 · see citing works

Water adsorption on bimetallic PtRu/Pt(111) surface alloys

Fischer, J. M. T. A., Mahlberg, D., Roman, T., & Groß, A. (2016) · Proceedings of the Royal Society A Mathematical Physical and Engineering Sciences · doi:10.1098/rspa.2016.0618 · Cited by 17 · see citing works

High-entropy ceramics

Oses, C., Toher, C., & Curtarolo, S. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0170-8 · Cited by 2,081 · see citing works

High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery

Yao, Y., Dong, Q., Brozena, A., Luo, J., Miao, J., Chi, M., Wang, C., Kevrekidis, I. G., Ren, Z. J., Greeley, J., et al. (2022) · Science · doi:10.1126/science.abn3103 · Cited by 1,081 · see citing works

High-entropy energy materials: challenges and new opportunities

Ma, Y., Ma, Y., Wang, Q., Schweidler, S., Botros, M., Fu, T., Hahn, H., Brezesinski, T., & Breitung, B. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00505g · Cited by 963 · see citing works

High-entropy materials for catalysis: A new frontier

Sun, Y., & Dai, S. (2021) · Science Advances · doi:10.1126/sciadv.abg1600 · Cited by 942 · see citing works

High-Entropy Alloys as a Platform for Catalysis: Progress, Challenges, and Opportunities

Yue, X., Li, S., Qian, Y., Zhu, W., Yuan, H., Jiang, P., Guo, R., & Wang, L. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03617 · Cited by 850 · see citing works

Open Catalyst 2020 (OC20) Dataset and Community Challenges

Chanussot, L., Das, A., Goyal, S., Lavril, T., Shuaibi, M., Rivière, M., Tran, K., Heras‐Domingo, J., Ho, C., Hu, W., et al. (2021) · ACS Catalysis · doi:10.1021/acscatal.0c04525 · Cited by 786 · see citing works

Electrocatalytic Refinery for Sustainable Production of Fuels and Chemicals

Tang, C., Zheng, Y., Jaroniec, M., & Qiao, S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101522 · Cited by 722 · see citing works

Machine learning for alloys

Hart, G. L. W., Mueller, T., Toher, C., & Curtarolo, S. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00340-w · Cited by 703 · see citing works

Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries

Lun, Z., Ouyang, B., Kwon, D., Ha, Y., Foley, E., Huang, T., Cai, Z., Kim, H., Balasubramanian, M., Sun, Y., et al. (2020) · Nature Materials · doi:10.1038/s41563-020-00816-0 · Cited by 700 · see citing works

Bimetallic Sites for Catalysis: From Binuclear Metal Sites to Bimetallic Nanoclusters and Nanoparticles

Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 696 · see citing works

Untitled work

(2020) · doi:10.1038/s41467-020-19277-9 · Cited by 690 · see citing works

Recent progress of high-entropy materials for energy storage and conversion

Amiri, A., & Shahbazian‐Yassar, R. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta09578h · Cited by 595 · see citing works

Machine Learning for Electrocatalyst and Photocatalyst Design and Discovery

Mai, H., Le, T. C., Chen, D., Winkler, D. A., & Caruso, R. A. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00061 · Cited by 574 · see citing works

High-entropy alloys in electrocatalysis: from fundamentals to applications

Ren, J.-T., Chen, L., Wang, H.-Y., & Yuan, Z.-Y. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00557g · Cited by 551 · see citing works

Synthesis of high-entropy alloy nanoparticles on supports by the fast moving bed pyrolysis

Gao, S., Hao, S., Huang, Z., Yuan, Y., Han, S. Y., Lei, L., Zhang, X., Shahbazian‐Yassar, R., & Lu, J. B. (2020) · Nature Communications · doi:10.1038/s41467-020-15934-1 · Cited by 540 · see citing works

Strategies to break linear scaling relationships

Pérez-Ramírez, J., & López, N. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0376-6 · Cited by 528 · see citing works

High-Entropy Alloys as Catalysts for the CO 2 and CO Reduction Reactions

Pedersen, J. K., Batchelor, T. A. A., Bagger, A., & Rossmeisl, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b04343 · Cited by 497 · see citing works

Multi‐Sites Electrocatalysis in High‐Entropy Alloys

Li, H., Lai, J., Li, Z., & Wang, L. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202106715 · Cited by 494 · see citing works

Subnanometer high-entropy alloy nanowires enable remarkable hydrogen oxidation catalysis

Zhan, C., Xu, Y., Bu, L., Zhu, H., Feng, Y., Yang, T., Zhang, Y., Yang, Z., Huang, B., Shao, Q., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-26425-2 · Cited by 486 · see citing works

What Makes High‐Entropy Alloys Exceptional Electrocatalysts?

Löffler, T., Ludwig, A., Rossmeisl, J., & Schuhmann, W. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202109212 · Cited by 464 · see citing works

Electrocatalytic Hydrogenation of Biomass-Derived Organics: A Review

Akhade, S. A., Singh, N., Gutiérrez, O. Y., Lopez‐Ruiz, J. A., Wang, H., Holladay, J. D., Liu, Y., Karkamkar, A., Weber, R. S., Padmaperuma, A. B., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00158 · Cited by 447 · see citing works

Catalysis of Alloys: Classification, Principles, and Design for a Variety of Materials and Reactions

Nakaya, Y., & Furukawa, S. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00356 · Cited by 419 · see citing works

Noble Metal-Free Nanoporous High-Entropy Alloys as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction

Qiu, H., Fang, G., Gao, J., Wen, Y., Lv, J., Li, H., Xie, G., Liu, X., & Sun, S. (2019) · ACS Materials Letters · doi:10.1021/acsmaterialslett.9b00414 · Cited by 416 · see citing works

Discovery of new materials using combinatorial synthesis and high-throughput characterization of thin-film materials libraries combined with computational methods

Ludwig, A. (2019) · npj Computational Materials · doi:10.1038/s41524-019-0205-0 · Cited by 360 · see citing works

Computationally aided, entropy-driven synthesis of highly efficient and durable multi-elemental alloy catalysts

Yao, Y., Liu, Z., Xie, P., Huang, Z., Li, T., Morris, D. J., Finfrock, Y. Z., Zhou, J., Jiao, M., Gao, J., et al. (2020) · Science Advances · doi:10.1126/sciadv.aaz0510 · Cited by 356 · see citing works

Multifunctional High Entropy Alloys Enabled by Severe Lattice Distortion

Wang, H., He, Q., Gao, X., Shang, Y., Zhu, W., Zhao, W., Chen, Z., Gong, H., & Yang, Y. G. (2023) · Advanced Materials · doi:10.1002/adma.202305453 · Cited by 332 · see citing works

Synergistic effects of mixing and strain in high entropy spinel oxides for oxygen evolution reaction

Baek, J., Hossain, M. D., Mukherjee, P., Lee, J., Winther, K. T., Leem, J., Jiang, Y., Chueh, W. C., Bajdich, M., & Zheng, X. (2023) · Nature Communications · doi:10.1038/s41467-023-41359-7 · Cited by 323 · see citing works

Noble-Metal High-Entropy-Alloy Nanoparticles: Atomic-Level Insight into the Electronic Structure

Wu, D., Kusada, K., Nanba, Y., Koyama, M., Yamamoto, T., Toriyama, T., Matsumura, S., Seo, O., Gueye, I., Kim, J., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c13616 · Cited by 322 · see citing works

On the electronic structure and hydrogen evolution reaction activity of platinum group metal-based high-entropy-alloy nanoparticles

Wu, D., Kusada, K., Yamamoto, T., Toriyama, T., Matsumura, S., Gueye, I., Seo, O., Kim, J., Hiroi, S., Sakata, O., et al. (2020) · Chemical Science · doi:10.1039/d0sc02351e · Cited by 315 · see citing works

High-entropy alloy stabilized active Ir for highly efficient acidic oxygen evolution

Zhu, H., Zhu, Z., Hao, J., Sun, S., Lu, S., Wang, C., Ma, P., Dong, W., & Du, M. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.133251 · Cited by 305 · see citing works

High‐Entropy Alloys for Electrocatalysis: Design, Characterization, and Applications

Zhang, Y., Wang, D., & Wang, S. (2021) · Small · doi:10.1002/smll.202104339 · Cited by 304 · see citing works

The promise of high-entropy materials for high-performance rechargeable Li-ion and Na-ion batteries

Zheng, W., Liang, G., Liu, Q., Li, J., Yuwono, J. A., Zhang, S., Peterson, V. K., & Guo, Z. (2023) · Joule · doi:10.1016/j.joule.2023.10.016 · Cited by 287 · see citing works

High-entropy materials for energy-related applications

Fu, M., Ma, X., Zhao, K., Li, X., & Su, D. (2021) · iScience · doi:10.1016/j.isci.2021.102177 · Cited by 283 · see citing works

Extreme mixing in nanoscale transition metal alloys

Yao, Y., Huang, Z., Hughes, L. A., Gao, J., Li, T., Morris, D. J., Zeltmann, S. E., Savitzky, B. H., Ophus, C., Finfrock, Y. Z., et al. (2021) · Matter · doi:10.1016/j.matt.2021.04.014 · Cited by 279 · see citing works

Recent progress in high-entropy alloys for catalysts: synthesis, applications, and prospects

Li, K., & Chen, W. (2021) · Materials Today Energy · doi:10.1016/j.mtener.2021.100638 · Cited by 279 · see citing works

Electrocatalysis as the Nexus for Sustainable Renewable Energy: The Gordian Knot of Activity, Stability, and Selectivity

Masa, J., Andronescu, C., & Schuhmann, W. W. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202007672 · Cited by 274 · see citing works

Interfacial engineering of heterogeneous catalysts for electrocatalysis

Zhang, Y., Lin, Y., Duan, T., & Song, L. (2021) · Materials Today · doi:10.1016/j.mattod.2021.02.004 · Cited by 268 · see citing works

Promoted self-construction of β-NiOOH in amorphous high entropy electrocatalysts for the oxygen evolution reaction

Han, M., Wang, C., Zhong, J., Han, J., Wang, N., Seifitokaldani, A., Yu, Y., Liu, Y., Sun, X., Vomiero, A., et al. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120764 · Cited by 263 · see citing works

A perspective on the catalysis using the high entropy alloys

Katiyar, N. K., Biswas, K., Yeh, J., Sharma, S., & Tiwary, C. S. (2021) · Nano Energy · doi:10.1016/j.nanoen.2021.106261 · Cited by 262 · see citing works

Machine learned features from density of states for accurate adsorption energy prediction

Fung, V., Hu, G., Ganesh, P., & Sumpter, B. G. (2021) · Nature Communications · doi:10.1038/s41467-020-20342-6 · Cited by 258 · see citing works

Towards ultralow platinum loading proton exchange membrane fuel cells

Fan, L., Deng, H., Zhang, Y., Du, Q., Leung, D. Y. C., Wang, Y., & Jiao, K. (2023) · Energy & Environmental Science · doi:10.1039/d2ee03169h · Cited by 255 · see citing works

Multifunctional high-entropy materials

Han, L., Zhu, S., Rao, Z., Scheu, C., Ponge, D., Ludwig, A., Zhang, H., Gutfleisch, O., Hahn, H., Li, Z., et al. (2024) · Nature Reviews Materials · doi:10.1038/s41578-024-00720-y · Cited by 255 · see citing works

Nanoporous high-entropy alloys with low Pt loadings for high-performance electrochemical oxygen reduction

Li, S., Tang, X., Jia, H., Li, H., Xie, G., Liu, X., Lin, X., & Qiu, H. (2020) · Journal of Catalysis · doi:10.1016/j.jcat.2020.01.024 · Cited by 254 · see citing works

Ultra‐Small High‐Entropy Alloy Nanoparticles: Efficient Nanozyme for Enhancing Tumor Photothermal Therapy

Ai, Y., He, M., Sun, H., Jia, X., Wu, L., Zhang, X., Sun, H., & Liang, Q. (2023) · Advanced Materials · doi:10.1002/adma.202302335 · Cited by 254 · see citing works

Disordered enthalpy–entropy descriptor for high-entropy ceramics discovery

Divilov, S., Eckert, H., Hicks, D., Oses, C., Toher, C., Friedrich, R., Esters, M., Mehl, M. J., Zettel, A. C., Lederer, Y., et al. (2024) · Nature · doi:10.1038/s41586-023-06786-y · Cited by 254 · see citing works

Unlocking the potential: machine learning applications in electrocatalyst design for electrochemical hydrogen energy transformation

Ding, R. F., Chen, J., Chen, Y., Liu, J., Bando, Y., & Wang, X. (2024) · Chemical Society Reviews · doi:10.1039/d4cs00844h · Cited by 252 · see citing works

Bayesian Optimization of High‐Entropy Alloy Compositions for Electrocatalytic Oxygen Reduction**

Pedersen, J. K., Clausen, C. M., Krysiak, O. A., Xiao, B., Batchelor, T. A. A., Löffler, T., Mints, V. A., Banko, L., Arenz, M., Savan, A., et al. (2021) · Angewandte Chemie · doi:10.1002/ange.202108116 · Cited by 248 · see citing works

High-entropy effect of a metal phosphide on enhanced overall water splitting performance

Lai, D., Kang, Q., Gao, F., & Lu, Q. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta04755h · Cited by 248 · see citing works

Promoting Electrocatalytic Hydrogen Evolution Reaction and Oxygen Evolution Reaction by Fields: Effects of Electric Field, Magnetic Field, Strain, and Light

Yao, J., Huang, W., Fang, W., Kuang, M., Jia, N., Ren, H., Liu, D., Lv, C., Liu, C., Xu, J., et al. (2020) · Small Methods · doi:10.1002/smtd.202000494 · Cited by 245 · see citing works

Rugged High-Entropy Alloy Nanowires with in Situ Formed Surface Spinel Oxide As Highly Stable Electrocatalyst in Zn–Air Batteries

Jin, Z., Lyu, J., Zhao, Y.-L., Li, H., Lin, X., Xie, G., Liu, X., Kai, J.-J., & Qiu, H.-J. (2020) · ACS Materials Letters · doi:10.1021/acsmaterialslett.0c00434 · Cited by 244 · see citing works

Beyond Scaling Relations for the Description of Catalytic Materials

Andersen, M., Levchenko, S. V., Scheffler, M., & Reuter, K. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04478 · Cited by 242 · see citing works

Convolutional Neural Network of Atomic Surface Structures To Predict Binding Energies for High-Throughput Screening of Catalysts

Back, S., Yoon, J., Tian, N., Zhong, W., Tran, K., & Ulissi, Z. W. (2019) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.9b01428 · Cited by 242 · see citing works

Eutectic Synthesis of High‐Entropy Metal Phosphides for Electrocatalytic Water Splitting

Zhao, X., Xue, Z., Chen, W., Wang, Y., & Mu, T. (2020) · ChemSusChem · doi:10.1002/cssc.202000173 · Cited by 240 · see citing works

High-throughput, combinatorial synthesis of multimetallic nanoclusters

Yao, Y., Huang, Z., Li, T., Wang, H., Liu, Y., Stein, H. S., Mao, Y., Gao, J., Jiao, M., Dong, Q., et al. (2020) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1903721117 · Cited by 239 · see citing works

Low-cost high entropy alloy (HEA) for high-efficiency oxygen evolution reaction (OER)

Sharma, L., Katiyar, N. K., Parui, A., Das, R., Kumar, R., Tiwary, C. S., Singh, A., Halder, A., & Biswas, K. (2021) · Nano Research · doi:10.1007/s12274-021-3802-4 · Cited by 228 · see citing works

A freestanding nanoporous NiCoFeMoMn high-entropy alloy as an efficient electrocatalyst for rapid water splitting

Liu, H., Qin, H., Kang, J., Ma, L., Chen, G., Huang, Q., Zhang, Z., Liu, E., Lu, H., Li, J., et al. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.134898 · Cited by 221 · see citing works

Three-dimensional atomic structure and local chemical order of medium- and high-entropy nanoalloys

Moniri, S., Yang, Y., Ding, J. C., Yuan, Y., Zhou, J., Yang, L., Zhu, F., Liao, Y., Yao, Y., Hu, L., et al. (2023) · Nature · doi:10.1038/s41586-023-06785-z · Cited by 221 · see citing works

Comprehensive review on high entropy alloy-based coating

Kumar, S. (2023) · Surface and Coatings Technology · doi:10.1016/j.surfcoat.2023.130327 · Cited by 220 · see citing works

Two-Dimensional High-Entropy Metal Phosphorus Trichalcogenides for Enhanced Hydrogen Evolution Reaction

Wang, R., Huang, J., Zhang, X., Han, J., Zhang, Z., Gao, T., Xu, L., Liu, S., Xu, P., & Song, B. (2022) · ACS Nano · doi:10.1021/acsnano.2c01064 · Cited by 215 · see citing works

A high-entropy phosphate catalyst for oxygen evolution reaction

Qiao, H., Wang, X., Dong, Q., Zheng, H., Chen, G., Hong, M., Yang, C., Wu, M., He, K., & Hu, L. (2021) · Nano Energy · doi:10.1016/j.nanoen.2021.106029 · Cited by 212 · see citing works

2D High‐Entropy Transition Metal Dichalcogenides for Carbon Dioxide Electrocatalysis

Cavin, J., Ahmadiparidari, A., Majidi, L., Thind, A. S., Misal, S. N., Prajapati, A., Hemmat, Z., Rastegar, S., Beukelman, A., Singh, M. R., et al. (2021) · Advanced Materials · doi:10.1002/adma.202100347 · Cited by 210 · see citing works

Toward a Paradigm Shift in Electrocatalysis Using Complex Solid Solution Nanoparticles

Löffler, T., Savan, A., Manjón, A. G., Meischein, M., Scheu, C., Ludwig, A., & Schuhmann, W. W. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b00531 · Cited by 208 · see citing works

Rapid Joule-Heating Synthesis for Manufacturing High-Entropy Oxides as Efficient Electrocatalysts

Wu, H., Lu, Q., Li, Y., Wang, J., Li, Y., Jiang, R., Zhang, J., Zheng, X., Han, X., Zhao, N., et al. (2022) · Nano Letters · doi:10.1021/acs.nanolett.2c01147 · Cited by 205 · see citing works

Multi-component nanoporous alloy/(oxy)hydroxide for bifunctional oxygen electrocatalysis and rechargeable Zn-air batteries

Fang, G., Gao, J., Lv, J., Jia, H., Li, H., Liu, W., Xie, G., Chen, Z., Huang, Y., Yuan, Q., et al. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118431 · Cited by 201 · see citing works

High entropy alloy electrocatalysts: a critical assessment of fabrication and performance

Tomboc, G. M., Kwon, T., Joo, J., & Lee, K. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta05176d · Cited by 201 · see citing works

Nanoporous ultra-high-entropy alloys containing fourteen elements for water splitting electrocatalysis

Cai, Z., Goou, H., Ito, Y., Tokunaga, T., Miyauchi, M., Abe, H., & Fujita, T. (2021) · Chemical Science · doi:10.1039/d1sc01981c · Cited by 201 · see citing works

A High-Entropy Oxide as High-Activity Electrocatalyst for Water Oxidation

Kante, M. V., Weber, M. L., Ni, S., van den Bosch, I. C. G., van der Minne, E., Heymann, L., Falling, L. J., Gauquelin, N., Tsvetanova, M., Cunha, D. M., et al. (2023) · ACS Nano · doi:10.1021/acsnano.2c08096 · Cited by 201 · see citing works

More is better: high-entropy electrolyte design in rechargeable batteries

Zhao, X., Fu, Z., Zhang, X., Wang, X., Li, B., Zhou, D., & Kang, F. (2024) · Energy & Environmental Science · doi:10.1039/d3ee03821a · Cited by 200 · see citing works

Understanding the enhanced catalytic activity of high entropy alloys: from theory to experiment

Wang, B., Yao, Y., Yu, X., Wang, C., Wu, C., & Zou, Z. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta02718b · Cited by 198 · see citing works

Engineering Microdomains of Oxides in High‐Entropy Alloy Electrodes toward Efficient Oxygen Evolution

Chen, Z., Zhang, T., Gao, X., Huang, Y., Qin, X., Wang, Y., Zhao, K., Xu, P., Zhang, C., Liu, L., et al. (2021) · Advanced Materials · doi:10.1002/adma.202101845 · Cited by 197 · see citing works

Complex‐Solid‐Solution Electrocatalyst Discovery by Computational Prediction and High‐Throughput Experimentation**

Batchelor, T. A. A., Löffler, T., Xiao, B., Krysiak, O. A., Strotkötter, V., Pedersen, J. K., Clausen, C. M., Savan, A., Li, Y., Schuhmann, W., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202014374 · Cited by 195 · see citing works

Noble-metal-based high-entropy-alloy nanoparticles for electrocatalysis

Huang, X., Yang, G., Li, S., Wang, H., Cao, Y., Peng, F., & Yu, H. (2021) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2021.12.026 · Cited by 195 · see citing works

Heterogeneous Trimetallic Nanoparticles as Catalysts

Crawley, J. W. M., Gow, I. E., Lawes, N., Kowalec, I., Kabalan, L., Catlow, C. R. A., Logsdail, A. J., Taylor, S. H., Dummer, N. F., & Hutchings, G. J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00493 · Cited by 195 · see citing works

High‐Entropy Materials for Water Electrolysis

Xu, X., Shao, Z., & Jiang, S. P. (2022) · Energy Technology · doi:10.1002/ente.202200573 · Cited by 194 · see citing works

Data‐Driven Materials Innovation and Applications

Wang, Z., Sun, Z., Yin, H., Liu, X., Wang, J., Zhao, H., Pang, C. H., Wu, T., Li, S., Yin, Z., et al. (2022) · Advanced Materials · doi:10.1002/adma.202104113 · Cited by 193 · see citing works

High‐Entropy Catalyst—A Novel Platform for Electrochemical Water Splitting

Zhai, Y., Ren, X., Wang, B., & Liu, S. F. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202207536 · Cited by 192 · see citing works

Ambient fast, large-scale synthesis of entropy-stabilized metal–organic framework nanosheets for electrocatalytic oxygen evolution

Zhao, X., Xue, Z., Chen, W., Bai, X., Shi, R., & Mu, T. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta09975a · Cited by 191 · see citing works

From Charge to Spin: An In‐Depth Exploration of Electron Transfer in Energy Electrocatalysis

Sun, S., Zhang, Y., Shi, X., Sun, W. R., Felser, C., Li, W., & Li, G. (2024) · Advanced Materials · doi:10.1002/adma.202312524 · Cited by 187 · see citing works

Sabatier Relations in Electrocatalysts Based on High‐entropy Alloys with Wide‐distributed d‐band Centers for Li‐O 2 Batteries

Tian, J., Rao, Y., Shi, W., Yang, J., Ning, W., Li, H., Yao, Y., Zhou, H. S., & Guo, S. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202310894 · Cited by 186 · see citing works

High‐entropy alloy catalysts: From bulk to nano toward highly efficient carbon and nitrogen catalysis

Yu, L., Zeng, K., Li, C., Lin, X., Liu, H., Shi, W., Qiu, H., Yuan, Y., & Yao, Y. (2022) · Carbon Energy · doi:10.1002/cey2.228 · Cited by 185 · see citing works

Multiple Metal–Nitrogen Bonds Synergistically Boosting the Activity and Durability of High-Entropy Alloy Electrocatalysts

Zhao, X., Cheng, H., Chen, X., Zhang, Q., Li, C., Xie, J., Marinković, N., Ma, L., Zheng, J., & Sasaki, K. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.3c08177 · Cited by 185 · see citing works

A general approach to high-entropy metallic nanowire electrocatalysts

Sun, Y., Zhang, W., Zhang, Q., Li, Y., Gu, L., & Guo, S. (2022) · Matter · doi:10.1016/j.matt.2022.09.023 · Cited by 183 · see citing works

Insights into the pH effect on hydrogen electrocatalysis

Cui, W., Gao, F., Na, G., Wang, X., Li, Z., Yang, Y., Niu, Z., Qu, Y., Wang, D. S., & Pan, H. (2024) · Chemical Society Reviews · doi:10.1039/d4cs00370e · Cited by 179 · see citing works

High-entropy alloy electrocatalysts go to (sub-)nanoscale

Li, M., Lin, F., Zhang, S., Zhao, R., Tao, L., Li, L., Li, J., Zeng, L., Luo, M., & Guo, S. (2024) · Science Advances · doi:10.1126/sciadv.adn2877 · Cited by 177 · see citing works

The self-complementary effect through strong orbital coupling in ultrathin high-entropy alloy nanowires boosting pH-universal multifunctional electrocatalysis

Li, H., Sun, M., Pan, Y., Xiong, J., Du, H., Yu, Y., Feng, S., Li, Z., Lai, J., Huang, B., et al. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.121431 · Cited by 177 · see citing works

High entropy alloy nanoparticles as efficient catalysts for alkaline overall seawater splitting and Zn-air batteries

Zhang, Q., Lian, K., Liu, Q., Qi, G., Zhang, S., Luo, J., & Liu, X. (2023) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2023.05.074 · Cited by 177 · see citing works

High-entropy alloy nanocrystal assembled by nanosheets with d–d electron interaction for hydrogen evolution reaction

Wei, M., Sun, Y., Zhang, J., Ai, F., Xi, S., & Wang, J. (2023) · Energy & Environmental Science · doi:10.1039/d3ee01929b · Cited by 177 · see citing works

Short‐Range Diffusion Enables General Synthesis of Medium‐Entropy Alloy Aerogels

Han, G., Li, M., Liu, H., Zhang, W., He, L., Tian, F., Liu, Y., Yu, Y., Yang, W., & Guo, S. (2022) · Advanced Materials · doi:10.1002/adma.202202943 · Cited by 176 · see citing works

Application of Machine Learning in Optimizing Proton Exchange Membrane Fuel Cells: A Review

Ding, R. F., Zhang, S., Chen, Y., Rui, Z., Hua, K., Wu, Y., Li, X., Duan, X., Wang, X., Li, J., et al. (2022) · Energy and AI · doi:10.1016/j.egyai.2022.100170 · Cited by 176 · see citing works

Opportunities for High-Entropy Materials in Rechargeable Batteries

Chen, Y., Fu, H., Huang, Y., Huang, L., Zheng, X., Dai, Y., Huang, Y., & Luo, W. H. (2020) · ACS Materials Letters · doi:10.1021/acsmaterialslett.0c00484 · Cited by 174 · see citing works

Optimization strategies of high-entropy alloys for electrocatalytic applications

Xiao, L., Wang, Z., & Guan, J. (2023) · Chemical Science · doi:10.1039/d3sc04962k · Cited by 174 · see citing works

Neural Network-Assisted Development of High-Entropy Alloy Catalysts: Decoupling Ligand and Coordination Effects

Lu, Z., Chen, Z., & Singh, C. V. (2020) · Matter · doi:10.1016/j.matt.2020.07.029 · Cited by 173 · see citing works

Top–Down Synthesis of Noble Metal Particles on High-Entropy Oxide Supports for Electrocatalysis

Jin, Z., Lyu, J., Zhao, Y., Li, H., Chen, Z., Lin, X., Xie, G., Liu, X., Kai, J., & Qiu, H. (2021) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c04695 · Cited by 170 · see citing works

Recent applications of machine learning in alloy design: A review

Hu, M., Tan, Q., Knibbe, R., Xu, M., Jiang, B., Wang, S., Li, X., & Zhang, M. (2023) · Materials Science and Engineering R Reports · doi:10.1016/j.mser.2023.100746 · Cited by 169 · see citing works

Noble Metal‐Based Multimetallic Nanoparticles for Electrocatalytic Applications

Kim, H., Yoo, T. Y., Bootharaju, M. S., Kim, J. H., Chung, D. Y., & Hyeon, T. (2021) · Advanced Science · doi:10.1002/advs.202104054 · Cited by 168 · see citing works

Medium/High‐Entropy Amalgamated Core/Shell Nanoplate Achieves Efficient Formic Acid Catalysis for Direct Formic Acid Fuel Cell

Zhan, C., Bu, L., Sun, H., Huang, X., Zhu, Z., Tang, Y., Ma, H., Li, L., Wang, Y., Geng, H., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202213783 · Cited by 168 · see citing works

High Density and Unit Activity Integrated in Amorphous Catalysts for Electrochemical Water Splitting

Zhai, Y., Ren, X., Yan, J., & Liu, S. F. (2020) · Small Structures · doi:10.1002/sstr.202000096 · Cited by 164 · see citing works

Rational design of septenary high-entropy alloy for direct ethanol fuel cells

Chang, J., Wang, G., Li, C., He, Y., Zhu, Y., Zhang, W., Sajid, M., Kara, A., Gu, M. D., & Yang, Y. (2023) · Joule · doi:10.1016/j.joule.2023.02.011 · Cited by 163 · see citing works

Understanding the Structural Evolution of IrFeCoNiCu High-Entropy Alloy Nanoparticles under the Acidic Oxygen Evolution Reaction

Maulana, A. L., Chen, P., Shi, Z., Yang, Y., Lizandara‐Pueyo, C., Seeler, F., Abruña, H. D., Muller, D. A., Schierle‐Arndt, K., & Yang, P. (2023) · Nano Letters · doi:10.1021/acs.nanolett.3c01831 · Cited by 163 · see citing works

Non-noble metal-based amorphous high-entropy oxides as efficient and reliable electrocatalysts for oxygen evolution reaction

Wang, Q., Li, J., Li, Y., Shao, G., Jia, Z., & Shen, B. (2022) · Nano Research · doi:10.1007/s12274-022-4179-8 · Cited by 161 · see citing works

Computational Screening of Pt-Skin Oxygen Reduction Reaction Electrocatalyst Supported by Random Solid-Solution PtPdRhIrRu Alloy

Aliman, J. M., Ebaya, J. L. P., Bongabong, K. J., Domato, D. C., Chan, G. L., & Ambolode, L. C., II (2026) · Journal of Physics Conference Series · doi:10.1088/1742-6596/3268/1/012025

Unraveling Reactivity Origin of Oxygen Reduction at High-Entropy Alloy Electrocatalysts with a Computational and Data-Driven Approach

Huang, Y., Wang, S., Wang, X., Omidvar, N., Achenie, L. E. K., Skrabalak, S. E., & Xin, H. (2024) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.4c01630 · Cited by 29 · see citing works

Inverse design and discovery of high entropy alloy catalysts for efficient oxygen evolution reaction

Thoudam, J., & Jain, A. (2026) · The Journal of Chemical Physics · doi:10.1063/5.0328756

Machine-learning-assisted discovery of highly efficient high-entropy alloy catalysts for the oxygen reduction reaction

Wan, X., Zhang, Z., Yu, W., Niu, H., Wang, X., & Guo, Y. (2022) · Patterns · doi:10.1016/j.patter.2022.100553 · Cited by 92 · see citing works

Following Paths of Maximum Catalytic Activity in the Composition Space of High‐Entropy Alloys

Plenge, M. K., Pedersen, J. K., Mints, V. A., Arenz, M., & Rossmeisl, J. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202202962 · Cited by 44 · see citing works