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Cited by 771

The DOI matches its Crossref record; 67 of the 67 references it cites were found in a registry or an index.

Hydrated Eutectic Electrolytes with Ligand-Oriented Solvation Shells for Long-Cycling Zinc-Organic Batteries

Open access
Yang, Wuhai, Du, Xiaofan, Zhao, Jingwen, Chen, Zheng, Li, Jiajia, Xie, Jian, Zhang, Yaojian, Cui, Zili, Kong, Qingyu, Zhao, Zhiming, Wang, Cunguo, Zhang, Qichun, Cui, Guanglei·2020·Joule
DOI 10.1016/j.joule.2020.05.018
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Abstract

Summary Despite their intrinsic safety and cost-effectiveness, aqueous zinc (Zn)-organic batteries have been struggling with the rapid performance degradation arising from the poor reversibility of Zn anodes and the dissolution of cathodes. Here, we present a new aqueous eutectic electrolyte by coupling a hydrated Zn salt (Zn(ClO4)2·6H2O) exclusively with a neutral ligand (succinonitrile) to mitigate these issues. The unique aqua Zn2+ solvates with a succinonitrile-assisted solvation shell enable an unusual Zn/Zn2+ reversibility of 98.4% Coulombic efficiency along with smooth Zn deposition. Moreover, all water molecules contribute to the formation of the eutectic network, resulting in a delayed oxidation and suppressed solvating ability. When a quinone-based polymer material (38 wt % sulfur content) is utilized as a cathode, the Zn-organic battery with this aqueous eutectic electrolyte exhibits an unprecedented cyclability with a low capacity decay rate (0.004% per cycle over 3,500 cycles) and superior low-temperature performance.

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Metadata

Authors
Yang, W., Du, X., Zhao, J., Chen, Z., Li, J., Xie, J., Zhang, Y., Cui, Z., Kong, Q., Zhao, Z., Wang, C., Zhang, Q., & Cui, G.
Venue
Joule
Publisher
Elsevier BV
Published
2020-07
Volume
4
Issue
7
Pages
1557-1574
ISSN
2542-4351 (ISSN-L)
DOI
10.1016/j.joule.2020.05.018
OpenAlex
W3040611391
Cited by
771
References
67
FWCI
33.42
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Hydrated Eutectic Electrolytes with Ligand-Oriented Solvation Shells for Long-Cycling Zinc-Organic Batteries. https://app.cochat.ai/papers/10.1016/j.joule.2020.05.018
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Yang, W., Du, X., Zhao, J., Chen, Z., Li, J., Xie, J., Zhang, Y., Cui, Z., Kong, Q., Zhao, Z., Wang, C., Zhang, Q., & Cui, G. (2020). Hydrated Eutectic Electrolytes with Ligand-Oriented Solvation Shells for Long-Cycling Zinc-Organic Batteries. Joule. https://doi.org/10.1016/j.joule.2020.05.018

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.