LiBOB: Is it an alternative salt for lithium ion chemistry?
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A LiBF4:LiBOB (9:1, molar ratio) dual-salt system in PC/EC/EMC ternary solvent enabled a Li-LiFePO4 cell to show enhanced cyclic performance in a wide temperature range from -50 to 90 °C.
“To combine the good ionic conductivity of LiBF 4 and decent SEI formation capability from LiBOB, a LiBF 4 :LiBOB (9:1, molar ratio) dual-salt system was developed by Xu et al. [99,102], in PC/EC/EMC ternary solvent the Li-LiFePO 4 (LFP) cell showed enhanced cyclic performance in a wide-temperature range from -50 to 90 °C.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [102]
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“…conductivity of LiBF 4 and decent SEI formation capability from LiBOB, a LiBF 4 :LiBOB (9:1, molar ratio) dual-salt system was developed by Xu et al. [99, 102], in PC/EC/EMC ternary solvent the Li-LiFePO 4 (LFP) cell showed enhanced cyclic performance in a wide-temperature range from −50 to 90 °C.”
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“LiBC4O8 (LiBOB) has also been investigated due to its great film-forming capability, but its high viscosity and low solubility in carbonate seriously deteriorate its practicality at low temperature when used in LIBs [124].”
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“86 In contrast, LiDFOB brings together the bene ts of LiBF 4 and LiBOB.”
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“Among the alternatives investigated so far, namely borate salts (lithium tetrafluoroborate (LiBF 4 ) [50,51] , lithium bis(oxalato)borate (LiBOB) [50,52,53 towards hydrolysis and lower fluorine content compared to LiPF 6 .”
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Fan, L.-Z., Xing, T.-F., Awan, R., & Qiu, W. (2011) · doi:10.1007/s11581-011-0551-5 · Cited by 21
- Authors
- Xu, K., Zhang, S. S., Lee, U., Allen, J. L., & Jow, T. R.
- Affiliations
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Xu, Kang
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2005-08
- Volume
- 146
- Issue
- 1-2
- Pages
- 79-85
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W2079221214
- Cited by
- 203
- References
- 0
- Citations by year
- 2026: 9 · 2025: 16 · 2024: 14 · 2023: 9 · 2022: 15 · 2021: 10 · 2020: 7 · 2019: 7 · 2018: 15 · 2017: 13 · 2016: 9 · 2015: 17 · 2014: 15 · 2013: 6 · 2012: 8
- FWCI
- 5.07
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Power Sources (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- LiBOB, lithium-ion batteries, electrolyte salts, metal oxide cathodes, electrochemistry, salt impurities, battery safety
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