Cited by 433Advancements in Battery MaterialsAdvanced Battery Technologies ResearchExtraction and Separation Processes

Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells

Zheng, Honghe, Sun, Qingna, Liu, Gao, Song, Xiangyun, Battaglia, Vincent S.·2012·Journal of Power Sources

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Crossref · 10.1016/j.jpowsour.2012.01.122

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35 of 35 references verified0 citation errors · 0 not checkable

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  • Overcharging causes cathode overdelithiation and anode over-lithiation; cathode suffers irreversible structural change when overdelithiated, followed by dissolution of transition metal ions and active material decomposition.

    “When a cell is overcharged, the cathode is overdelithiated (no active lithium available) and the anode is over-lithiated (no more 'room' for lithium).The cathode material suffers from irreversible structural change when overdelithiated [33], followed by the dissolution of transition metal ions (such as Mn 2+ ) and active material decomposition [34].”

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Authors
Zheng, H., Sun, Q., Liu, G., Song, X., & Battaglia, V. S.
Affiliations
  • Lawrence Berkeley National Laboratory (US)
  • Soochow University (CN)
Corresponding author
Zheng, Honghe
Venue
Journal of Power Sources
Publisher
Elsevier BV
Published
2012-06
Volume
207
Pages
134-140
ISSN
0378-7753 (ISSN-L)
OpenAlex
W2069786258
Cited by
433
References
35
Citations by year
2026: 12 · 2025: 19 · 2024: 31 · 2023: 34 · 2022: 38 · 2021: 39 · 2020: 49 · 2019: 53 · 2018: 47 · 2017: 34 · 2016: 21 · 2015: 21 · 2014: 19 · 2013: 12 · 2012: 4
FWCI
11.45
Type
journal article
Language
en
Open access
closed
Locations
Journal of Power Sources (publishedVersion)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
  • Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
Keywords
NCM cathode, LiNi1/3Co1/3Mn1/3O2, transition metal dissolution, lithium-ion cells, capacity decay, metal ion deposition, cycle life, specific capacity, energy density, electrolytes

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