The DOI matches its Crossref record; 54 of the 54 references it cites were found in a registry or an index.
Anion Etching for Accessing Rapid and Deep Self-Reconstruction of Precatalysts for Water Oxidation
Open accessAbstract
Summary Transition metal-based nanomaterials represent an emerging class of highly active and low-cost precatalysts for the oxygen evolution reaction (OER) in alkaline electrolyzers. However, most OER precatalysts undergo slow or incomplete self-reconstructions to generate real active sites, which is a time-consuming process for achieving high OER performance. Thus, we report a new class of OER precatalysts that can achieve highly active OER species by a rapid and deep self-reconstruction (denoted by SELF-RECON). The precatalysts with a core-shell structure comprising NiMoO4 (core) and NiFe/NiFeOx nanoparticles in N-doped amorphous carbons (shell) (denoted by NiMoFeO@NC), can realize rapid MoO42− dissolution and fast formation of NiOOH with Fe incorporation simultaneously. In situ Raman spectroscopy together with electron microscopy, X-ray photoelectron spectroscopy, and electrochemical tests indicate that the obtained NiFeOOH/NiFe-LDH after SELF-RECON behave as the real active species that outperform NiMoFeO@NC, with ultralow overpotentials and extraordinary long-term stability.
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Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis
He, Z., Zhang, J., Gong, Z., Lei, H., Zhou, D., Zhang, N., Mai, W., Zhao, S., & Chen, Y. (2022) · Nature Communications · doi:10.1038/s41467-022-29875-4 · Cited by 665
Self-citationEvolution of Cationic Vacancy Defects: A Motif for Surface Restructuration of OER Precatalyst
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Surface Reconstruction of Water Splitting Electrocatalysts
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Metadata
- Authors
- Wang, Y., Zhu, Y., Zhao, S., She, S., Zhang, F., Chen, Y., Williams, T., Gengenbach, T., Zu, L., Mao, H., Zhou, W., Shao, Z., Wang, H., Tang, J., Zhao, D., & Selomulya, C.
- Venue
- Matter
- Publisher
- Elsevier BV
- Published
- 2020-12
- Volume
- 3
- Issue
- 6
- Pages
- 2124-2137
- ISSN
- 2590-2385 (ISSN-L)
- OpenAlex
- W3092550585
- Cited by
- 299
- References
- 54
- FWCI
- 8.19
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Wang, Y., Zhu, Y., Zhao, S., She, S., Zhang, F., Chen, Y., Williams, T., Gengenbach, T., Zu, L., Mao, H., Zhou, W., Shao, Z., Wang, H., Tang, J., Zhao, D., & Selomulya, C. (2020). Anion Etching for Accessing Rapid and Deep Self-Reconstruction of Precatalysts for Water Oxidation. Matter. https://doi.org/10.1016/j.matt.2020.09.016
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