The DOI matches its Crossref record; 64 of the 64 references it cites were found in a registry or an index.
The Controllable Reconstruction of Bi‐MOFs for Electrochemical CO2 Reduction through Electrolyte and Potential Mediation
Abstract
Monitoring and controlling the reconstruction of materials under working conditions is crucial for the precise identification of active sites, elucidation of reaction mechanisms, and rational design of advanced catalysts. Herein, a Bi‐based metal–organic framework (Bi‐MOF) for electrochemical CO 2 reduction is selected as a case study. In situ Raman spectra combined with ex situ electron microscopy reveal that the intricate reconstruction of the Bi‐MOF can be controlled using two steps: 1) electrolyte‐mediated dissociation and conversion of Bi‐MOF to Bi 2 O 2 CO 3, and 2) potential‐mediated reduction of Bi 2 O 2 CO 3 to Bi. The intentionally reconstructed Bi catalyst exhibits excellent activity, selectivity, and durability for formate production, and the unsaturated surface Bi atoms formed during reconstruction become the active sites. This work emphasizes the significant impact of pre‐catalyst reconstruction under working conditions and provides insight into the design of highly active and stable electrocatalysts through the regulation of these processes.
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Cites
Infrared and Raman Characteristic Group Frequencies: Tables and Charts
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Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
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CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Self-citationJiao, Y., Zheng, Y., Davey, K., & Qiao, S.-Z. (2016) · Nature Energy · doi:10.1038/nenergy.2016.130 · Cited by 1,196
Self-citationZheng, Y., Vasileff, A., Zhou, X., Jiao, Y., Jaroniec, M., & Qiao, S.-Z. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02124 · Cited by 1,075
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Metadata
- Authors
- Yao, D., Tang, C., Vasileff, A., Zhi, X., Jiao, Y., & Qiao, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-07-09
- Volume
- 60
- Issue
- 33
- Pages
- 18178-18184
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3181081593
- Cited by
- 312
- References
- 64
- FWCI
- 10.14
- Type
- journal article
- Language
- en
- Open access
- closed
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