Lithium extraction from complex aqueous solutions using supported ionic liquid membranes
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IL-TBP ILMED achieved a maximum extraction efficiency of 80% and high selectivity for Li+ over Mg2+ and Na+, even when the competing ions were present in high concentrations.
“IL-TBP ILMED achieved a maximum extraction ef fi ciency of 80%, and high selectivity for Li + over Mg 2+ and Na + , even when the competing ions were present in high concentrations.”
From A review of technologies for direct lithium extraction from low Li+ concentration aqueous solutions (2022) · cites this paper as Zante et al. (2019)
The main challenges facing the commercialization of ILMED for industrial-scale Li recovery from aqueous solutions are flux drops in membrane stability and the dissolution of IL to the feedstream after short periods (2 days) of continuous use.
“The main challenges facing the commercialization of ILMED for industrial-scale Li recovery from aqueous solutions are the fl ux drops in membrane stability and the dissolution of IL to the feedstream after short periods of (2 days) of continuous use (Ma et al., 2000; Zante et al., 2019).”
From A review of technologies for direct lithium extraction from low Li+ concentration aqueous solutions (2022) · cites this paper as Zante et al., 2019
Zante et al. (2019) found that for an IL-TBP ILMED, adding equimolar sodium carbonate and sodium hydrogen carbonate to the feedstream could reduce the loss of IL and extend the lifetime of the ILM.
“Zante et al. (2019) found that for an IL-TBP ILMED adding equimolar sodium carbonate and sodium hydrogen carbonate to the feedstream could reduce the loss of IL and extend the lifetime of the ILM.”
From A review of technologies for direct lithium extraction from low Li+ concentration aqueous solutions (2022) · cites this paper as Zante et al. (2019)
ILMs have successfully been used for critical and heavy metals from aqueous solutions.
“ILMs have successfully been used for critical and heavy metals from aqueous solutions (Chen and Chen, 2016; Makanyire et al., 2016; Zante et al., 2019; Imdad and Dohare, 2022).”
From A review of technologies for direct lithium extraction from low Li+ concentration aqueous solutions (2022) · cites this paper as Zante et al., 2019
Cites
Lithium market research – global supply, future demand and price development
Martin, G., Rentsch, L., Höck, M., & Bertau, M. (2017) · Energy Storage Materials · doi:10.1016/j.ensm.2016.11.004 · Cited by 740 · see citing works
Global Lithium Availability: A Constraint for Electric Vehicles?
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Recovery of lithium from Uyuni salar brine
An, J. W., Kang, D. J., Tran, K. T., Kim, M. J., Lim, T., & Tran, T. (2012) · Hydrometallurgy · doi:10.1016/j.hydromet.2012.02.008 · Cited by 509 · see citing works
Recovery of lithium from geothermal water by solvent extraction technique
HANO, T., MATSUMOTO, M., OHTAKE, T., EGASHIR, N., & HORI, F. (1992) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299208918100 · Cited by 94 · see citing works
de los Ríos, A. P., Hernández-Fernández, F. J., Lozano, L. J., Sánchez-Segado, S., Ginestá-Anzola, A., Godínez, C., Tomás-Alonso, F., & Quesada-Medina, J. (2013) · Journal of Membrane Science · doi:10.1016/j.memsci.2013.05.006 · Cited by 58 · see citing works
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Membrane-based technologies for lithium recovery from water lithium resources: A review
Li, X., Mo, Y., Qing, W., Shao, S., Tang, C. Y., & Li, J. (2019) · Journal of Membrane Science · doi:10.1016/j.memsci.2019.117317 · Cited by 756 · see citing works
Lithium recovery from brine: Recent developments and challenges
Khalil, A., Mohammed, S., Hashaikeh, R., & Hilal, N. (2022) · Desalination · doi:10.1016/j.desal.2022.115611 · Cited by 396 · see citing works
Direct lithium extraction: A new paradigm for lithium production and resource utilization
Farahbakhsh, J., Arshadi, F., Mofidi, Z., Mohseni-Dargah, M., Kök, C., Assefi, M., Soozanipour, A., Zargar, M., Asadnia, M., Boroumand, Y., et al. (2024) · Desalination · doi:10.1016/j.desal.2023.117249 · Cited by 260 · see citing works
Highly selective lithium recovery from high Mg/Li ratio brines
Liu, G., Zhao, Z., & He, L. (2020) · Desalination · doi:10.1016/j.desal.2019.114185 · Cited by 185 · see citing works
A review of technologies for direct lithium extraction from low Li+ concentration aqueous solutions
Murphy, O., & Haji, M. N. (2022) · Frontiers in Chemical Engineering · doi:10.3389/fceng.2022.1008680 · Cited by 157 · see citing works
“The main challenges facing the commercialization of ILMED for industrial-scale Li recovery from aqueous solutions are the flux drops in membrane stability and the dissolution of IL to the feedstream after short periods of (2 days) of continuous use (Ma et al., 2000; Zante et al., 2019).”
BackgroundNikkhah, H., Ipekçi, D., Xiang, W., Stoll, Z., Xu, P., Li, B., McCutcheon, J. R., & Beykal, B. (2024) · Chemical Engineering Journal · doi:10.1016/j.cej.2024.155349 · Cited by 154 · see citing works
Zhao, Z., Liu, G., Jia, H., & He, L. (2020) · Journal of Membrane Science · doi:10.1016/j.memsci.2019.117685 · Cited by 132 · see citing works
Zhang, C., Mu, Y., Zhao, S., Zhang, W., & Wang, Y. (2020) · Desalination · doi:10.1016/j.desal.2020.114710 · Cited by 109 · see citing works
- Authors
- Zante, G., Boltoeva, M., Masmoudi, A., Barillon, R., & Trébouet, D.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Zante, Guillaume
- Venue
- Journal of Membrane Science
- Publisher
- Elsevier BV
- Published
- 2019-06
- Volume
- 580
- Pages
- 62-76
- ISSN
- 0376-7388 (ISSN-L)
- OpenAlex
- W2922229572
- Cited by
- 142
- References
- 5
- Citations by year
- 2026: 19 · 2025: 19 · 2024: 22 · 2023: 20 · 2022: 22 · 2021: 13 · 2020: 23 · 2019: 4
- FWCI
- 8.72
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Journal of Membrane Science (acceptedVersion)
- HAL (submittedVersion, cc-by-nc)
- Funders
- French Environment & Energy Management Agency
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
- Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Keywords
- lithium recovery, supported ionic liquid membranes, selective ion separation, lithium-magnesium separation, hydrophobic ionic liquids, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, tributyl phosphate, PVDF membranes, membrane impregnation, ionic liquid stability, carrier-mediated transport
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