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PVC-based hybrid membranes containing metal-organic frameworks for Li+/Mg2+ separation

Zhang, Chengyi, Mu, Yingxin, Zhang, Wen, Zhao, Song, Wang, Yuxin·2020·Journal of Membrane Science

Abstract

Abstract Developing effective technologies for extraction of Li+ from salt-lake brines with high Mg2+/Li+ ratios is paramount for sustainable utilization of lithium resources in electric vehicle and nuclear energy industries. In this work, hybrid membranes were prepared with polyvinyl chloride matrix and six metal−organic frameworks (MOFs@PVC) to separate Li+ from Mg2+ in solution. The effects of pore size sieving and sulfonation of the MOFs on the Li+/Mg2+ separation efficiency were evaluated using the current-voltage (I–V) method, and the stability of the MOFs@PVC membranes was systematically evaluated. The loading amount of MOFs and the thickness of the membranes were also optimized for Li+ transport and selectivity. The results show that the small pore size and sulfonation of MOFs are benefit to separate Li+ from Mg2+. Specifically, PVC-based hybrid membrane containing HSO3-UiO-66 shows the highest selectivity for Li+ (Li+/Mg2+ > 4), with the diffusion coefficient of 2.0×10-10 cm2 s-1 for Li+ and 4.67×10-11 cm2 s-1 for Mg2+. This study highlights the stable sulfonated Zr-based MOF with suitable pore sizes for membrane-based Li+/Mg2+ separation, and provides a potential alternative for recovering lithium from salt-lake brines.

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Metadata

Authors
Zhang, C., Mu, Y., Zhang, W., Zhao, S., & Wang, Y.
Venue
Journal of Membrane Science
Publisher
Elsevier BV
Published
2020-02
Volume
596
Pages
117724
ISSN
0376-7388 (ISSN-L)
OpenAlex
W2993404409
Cited by
188
References
10
FWCI
4.39
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: PVC-based hybrid membranes containing metal-organic frameworks for Li+/Mg2+ separation. https://app.cochat.ai/papers/10.1016/j.memsci.2019.117724
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Zhang, C., Mu, Y., Zhang, W., Zhao, S., & Wang, Y. (2020). PVC-based hybrid membranes containing metal-organic frameworks for Li+/Mg2+ separation. Journal of Membrane Science. https://doi.org/10.1016/j.memsci.2019.117724

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