The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
PVC-based hybrid membranes containing metal-organic frameworks for Li+/Mg2+ separation
Abstract
Abstract Developing effective technologies for extraction of Li+ from salt-lake brines with high Mg2+/Li+ ratios is paramount for sustainable utilization of lithium resources in electric vehicle and nuclear energy industries. In this work, hybrid membranes were prepared with polyvinyl chloride matrix and six metal−organic frameworks (MOFs@PVC) to separate Li+ from Mg2+ in solution. The effects of pore size sieving and sulfonation of the MOFs on the Li+/Mg2+ separation efficiency were evaluated using the current-voltage (I–V) method, and the stability of the MOFs@PVC membranes was systematically evaluated. The loading amount of MOFs and the thickness of the membranes were also optimized for Li+ transport and selectivity. The results show that the small pore size and sulfonation of MOFs are benefit to separate Li+ from Mg2+. Specifically, PVC-based hybrid membrane containing HSO3-UiO-66 shows the highest selectivity for Li+ (Li+/Mg2+ > 4), with the diffusion coefficient of 2.0×10-10 cm2 s-1 for Li+ and 4.67×10-11 cm2 s-1 for Mg2+. This study highlights the stable sulfonated Zr-based MOF with suitable pore sizes for membrane-based Li+/Mg2+ separation, and provides a potential alternative for recovering lithium from salt-lake brines.
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Cites
Flexer, V., Baspineiro, C. F., & Galli, C. I. (2018) · Science of the Total Environment · doi:10.1016/j.scitotenv.2018.05.223 · Cited by 768
Membrane-based technologies for lithium recovery from water lithium resources: A review
Li, X., Mo, Y., Qing, W., Shao, S., Tang, C. Y., & Li, J. (2019) · Journal of Membrane Science · doi:10.1016/j.memsci.2019.117317 · Cited by 756
Novel approaches for lithium extraction from salt-lake brines: A review
Liu, G., Zhao, Z., & Ghahreman, A. (2019) · Hydrometallurgy · doi:10.1016/j.hydromet.2019.05.005 · Cited by 465
Somrani, A., Hamzaoui, A. H., & Pontie, M. (2013) · Desalination · doi:10.1016/j.desal.2013.03.009 · Cited by 388
Lithium extraction from Chinese salt-lake brines: opportunities, challenges, and future outlook
Song, J. F., Nghiem, L. D., Li, X.-M., & He, T. (2017) · Environmental Science: Water Research & Technology · doi:10.1039/c7ew00020k · Cited by 269
Nie, X.-Y., Sun, S.-Y., Song, X., & Yu, J.-G. (2017) · Journal of Membrane Science · doi:10.1016/j.memsci.2017.02.020 · Cited by 195
Ji, P.-Y., Ji, Z.-Y., Chen, Q.-B., Liu, J., Zhao, Y.-Y., Wang, S.-Z., Li, F., & Yuan, J.-S. (2018) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.06.012 · Cited by 169
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Lithium extraction from complex aqueous solutions using supported ionic liquid membranes
Zante, G., Boltoeva, M., Masmoudi, A., Barillon, R., & Trébouet, D. (2019) · Journal of Membrane Science · doi:10.1016/j.memsci.2019.03.013 · Cited by 142
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Cited by
Tabelin, C. B., Dallas, J., Casanova, S., Pelech, T., Bournival, G., Saydam, S., & Canbulat, I. (2021) · Minerals Engineering · doi:10.1016/j.mineng.2020.106743 · Cited by 533
Zhao, Y., Tong, T., Wang, X., Lin, S., Reid, E. M., & Chen, Y. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.0c04593 · Cited by 363
Lithium extraction from salt lake brines with high magnesium/lithium ratio: a review
Zhu, R., Wang, S., Srinivasakannan, C., Li, S., Yin, S., Zhang, L., Jiang, X., Zhou, G., & Zhang, N. (2023) · Environmental Chemistry Letters · doi:10.1007/s10311-023-01571-9 · Cited by 318
Direct lithium extraction: A new paradigm for lithium production and resource utilization
Farahbakhsh, J., Arshadi, F., Mofidi, Z., Mohseni-Dargah, M., Kök, C., Assefi, M., Soozanipour, A., Zargar, M., Asadnia, M., Boroumand, Y., et al. (2024) · Desalination · doi:10.1016/j.desal.2023.117249 · Cited by 260
Lithium Extraction by Emerging Metal-Organic Framework-Based Membranes
Hou, J., Zhang, H., Thornton, A. W., Hill, A. J., Wang, H., & Konstas, K. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202105991 · Cited by 248
Metadata
- Authors
- Zhang, C., Mu, Y., Zhang, W., Zhao, S., & Wang, Y.
- Venue
- Journal of Membrane Science
- Publisher
- Elsevier BV
- Published
- 2020-02
- Volume
- 596
- Pages
- 117724
- ISSN
- 0376-7388 (ISSN-L)
- OpenAlex
- W2993404409
- Cited by
- 188
- References
- 10
- FWCI
- 4.39
- Type
- journal article
- Language
- en
- Open access
- closed
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