Pesticide residues in groundwater and surface water: recent advances in solid-phase extraction and solid-phase microextraction sample preparation methods for multiclass analysis by gas chromatography-mass spectrometry
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WHO analyses indicate that annual human mortality from pesticide poisoning via water has surpassed 0.4% and 1.9%.
“The World Health Organization's (WHO) analysis and statistical observations show that the death rate of humans caused by pesticide poisoning by water has exceeded the rates of 0.4% and 1.9% annually [1,10].”
From Natural Thymol– <i>tert</i> ‐Butylhydroquinone–Based Deep Eutectic Solvent/Vortex‐Assisted Dispersive Liquid–Liquid Microextraction for Organophosphorus Pesticide Extraction in Water Samples (2025) · cites this paper as [1]
The Introduction and Conclusions discuss pesticide contamination of water and potential harm to human health, but neither gives an annual mortality rate. Searches for the 0.4% and 1.9% figures and for WHO pesticide-poisoning mortality found no passage addressing the claimed rates. Page numbers were not available in our copy. (LLM, conf=0.75)
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Cites
Solid phase microextraction with thermal desorption using fused silica optical fibers
Arthur, C. L., & Pawliszyn, J. B. (1990) · Analytical Chemistry · doi:10.1021/ac00218a019 · Cited by 5,007 · see citing works
Statistics and Chemometrics for Analytical Chemistry
Miller, J. N., & Miller, J. C. (2005) · Cited by 3,779 · see citing works
Pyrethroid pesticide residues in the global environment: An overview
Tang, W., Wang, D., Wang, J., et al. (2017) · Chemosphere · doi:10.1016/j.chemosphere.2017.10.115 · Cited by 608 · see citing works
Danzer, K., & Currie, L. A. (1998) · Pure and Applied Chemistry · doi:10.1351/pac199870040993 · Cited by 555 · see citing works
Strategies of molecular imprinting-based solid-phase extraction prior to chromatographic analysis
Arabi, M., Ostovan, A., Bagheri, A. R., Guo, X., Wang, L., Li, J., Wang, X., Li, B., & Chen, L. (2020) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2020.115923 · Cited by 465 · see citing works
Pesticides in aquatic environments and their removal by adsorption methods
Mojiri, A., Zhou, J. L., Robinson, B., Ohashi, A., Ozaki, N., Kindaichi, T., Farraji, H., & Vakili, M. (2020) · Chemosphere · doi:10.1016/j.chemosphere.2020.126646 · Cited by 377 · see citing works
A comprehensive look at solid-phase microextraction technique: A review of reviews
Jalili, V., Barkhordari, A., & Ghiasvand, A. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.104319 · Cited by 318 · see citing works
Pesticides in Brazilian freshwaters: a critical review
de Albuquerque, A. F., Ribeiro, J. A., Kummrow, F., et al. (2016) · Environmental Science Processes & Impacts · doi:10.1039/c6em00268d · Cited by 252 · see citing works
Matrix-induced response enhancement in pesticide residue analysis by gas chromatography
Poole, C. F. (2007) · Journal of Chromatography A · doi:10.1016/j.chroma.2007.01.018 · Cited by 247 · see citing works
Antileishmanial Activity of Dimeric Flavonoids Isolated from Arrabidaea brachypoda
Rocha, V. P. C., da Rocha, C. Q., Queiroz, E. F., Marcourt, L., Vilegas, W., Grimaldi, G., Furrer, P., Allémann, É., Wolfender, J., & Soares, M. B. P. (2018) · Molecules · doi:10.3390/molecules24010001 · Cited by 247 · see citing works
Sample preparation and extraction methods for pesticides in aquatic environments: A review
Nasiri, M., Ahmadzadeh, H., & Amiri, A. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.115772 · Cited by 192 · see citing works
Principles of analytical calibration/quantification for the separation sciences
Cuadros-Rodrı́guez, L., Bagur-González, M. G., Sánchez-Viñas, M., et al. (2007) · Journal of Chromatography A · doi:10.1016/j.chroma.2007.03.030 · Cited by 191 · see citing works
Comparison of pesticide residues in surface water and ground water of agriculture intensive areas
Lari, S., Khan, N. A., Gandhi, K. N., Meshram, T. S., & Thacker, N. (2014) · Journal of Environmental Health Science and Engineering · doi:10.1186/2052-336x-12-11 · Cited by 191 · see citing works
Ma, J., Wu, G., Li, S., Tan, W., Wang, X., Li, J., & Chen, L. (2018) · Journal of Chromatography A · doi:10.1016/j.chroma.2018.04.034 · Cited by 188 · see citing works
Gaweł, M., Kiljanek, T., Niewiadowska, A., et al. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.01.003 · Cited by 187 · see citing works
Ma, J., Yao, Z., Hou, L., Lü, W., Yang, Q., Li, J., & Chen, L. (2016) · Talanta · doi:10.1016/j.talanta.2016.09.035 · Cited by 181 · see citing works
Application of carbon nanotubes in extraction and chromatographic analysis: A review
ALOthman, Z. A., & Wabaidur, S. M. (2018) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2018.05.012 · Cited by 175 · see citing works
Huang, Z., & Lee, H. K. (2015) · Journal of Chromatography A · doi:10.1016/j.chroma.2015.04.052 · Cited by 160 · see citing works
Picó, Y., Alfarhan, A., & Barceló, . (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.115720 · Cited by 156 · see citing works
A socio-environmental perspective on pesticide use and food production
Gomes, H. D. O., Menezes, J. M. C., da Costa, J. G. M., et al. (2020) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2020.110627 · Cited by 142 · see citing works
High performance removal and simulation studies of diuron pesticide in water on MWCNTs
Al‐Shaalan, N. H., Ali, I., ALOthman, Z. A., et al. (2019) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2019.111039 · Cited by 139 · see citing works
Liu, G., Li, L., Huang, X., Zheng, S., Xu, D., Xu, X., Zhang, Y., & Lin, H. (2018) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2018.05.023 · Cited by 115 · see citing works
Comparison of gas and liquid chromatography for analysing polar pesticides in water samples
Liška, I., & Slobodnı́k, J. (1996) · Journal of Chromatography A · doi:10.1016/0021-9673(95)01048-3 · Cited by 114 · see citing works
Determination of free fatty acids in olive oils by UPHLC–MS
Wabaidur, S. M., AlAmmari, A. M., Aqel, A., et al. (2016) · Journal of Chromatography B · doi:10.1016/j.jchromb.2016.07.040 · Cited by 106 · see citing works
Ghiasi, A., Malekpour, A., & Mahpishanian, S. (2020) · Talanta · doi:10.1016/j.talanta.2020.121120 · Cited by 94 · see citing works
Li, X., Chen, J., He, X., et al. (2019) · Chemosphere · doi:10.1016/j.chemosphere.2019.05.243 · Cited by 93 · see citing works
Akbarzade, S., Chamsaz, M., Rounaghi, G. H., et al. (2017) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-017-0732-9 · Cited by 89 · see citing works
Lashgari, M., Singh, V., & Pawliszyn, J. B. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.07.029 · Cited by 89 · see citing works
Zaidon, S. Z., Ho, Y. B., Hamsan, H., et al. (2018) · Microchemical Journal · doi:10.1016/j.microc.2018.11.025 · Cited by 84 · see citing works
Alcântara, D. B., Fernandes, T. S. M., do Nascimento, H. O., et al. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.124958 · Cited by 84 · see citing works
Guedes, J. A. C., Silva, R. D. O., Lima, C. G., et al. (2015) · Food Chemistry · doi:10.1016/j.foodchem.2015.12.007 · Cited by 78 · see citing works
Assessment of pesticide contamination in Akkar groundwater, northern Lebanon
Chbib, C., Net, S., Mariam, H., et al. (2017) · Environmental Science and Pollution Research · doi:10.1007/s11356-017-8568-6 · Cited by 77 · see citing works
He, P., & Aga, D. S. (2019) · Analytical Methods · doi:10.1039/c8ay02774a · Cited by 77 · see citing works
In-syringe solid-phase extraction for on-site sampling of pyrethroids in environmental water samples
Han, Q., Aydan, T., Yang, L., et al. (2018) · Analytica Chimica Acta · doi:10.1016/j.aca.2018.01.001 · Cited by 72 · see citing works
Risk assessment of organochlorine pesticides in drinking water source of the Yangtze River
Jin, X., Liu, Y., Qiao, X., et al. (2019) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2019.109390 · Cited by 70 · see citing works
A new type of GC–MS with advanced capabilities
Fialkov, A. B., Steiner, U., Jones, L., et al. (2006) · International Journal of Mass Spectrometry · doi:10.1016/j.ijms.2005.12.045 · Cited by 66 · see citing works
Al-Alam, J., Fajloun, Z., Chbani, A., et al. (2017) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-017-0463-y · Cited by 61 · see citing works
QuEChERS method combined with GC‒MS for pesticide residues determination in water
Ghani, S. B. A., & Hanafi, A. (2016) · Journal of Analytical Chemistry · doi:10.1134/s1061934816050117 · Cited by 60 · see citing works
Cao, X., Liu, G., She, Y., et al. (2016) · RSC Advances · doi:10.1039/c6ra23759b · Cited by 60 · see citing works
Milhome, M. A. L., Sousa, D. O. B., Lima, F. D. A. F., et al. (2009) · Engenharia Sanitaria e Ambiental · doi:10.1590/s1413-41522009000300010 · Cited by 58 · see citing works
Optimization of a DI-SPME-GC–MS/MS method for multi-residue analysis of pesticides in waters
Jabali, Y., Millet, M., & El-Hoz, M. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.03.004 · Cited by 58 · see citing works
Valenzuela, E. F., de Paula, F. G. F., Teixeira, A. P. D. C., et al. (2020) · Talanta · doi:10.1016/j.talanta.2020.121011 · Cited by 58 · see citing works
Tankiewicz, M., & Biziuk, M. (2017) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-017-0798-4 · Cited by 56 · see citing works
Huang, X., Liu, G., Xu, D., Xu, X., Li, L., Zheng, S., Lin, H., & Gao, H. (2018) · Applied Sciences · doi:10.3390/app8060959 · Cited by 56 · see citing works
Liu, A., Kou, W., Zhang, H., et al. (2020) · Analytical Chemistry · doi:10.1021/acs.analchem.0c00304 · Cited by 56 · see citing works
Sun, P., Gao, Y., Xu, C., et al. (2018) · RSC Advances · doi:10.1039/c7ra13316b · Cited by 55 · see citing works
Silva, R. D. O., Menezes, M. G. G. D., de Castro, R. C., et al. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.06.001 · Cited by 55 · see citing works
Tang, X., Yang, Y., Tam, N. F. Y., et al. (2018) · Environmental Science and Pollution Research · doi:10.1007/s11356-018-3808-y · Cited by 54 · see citing works
Liu, H., Jiang, L., Lu, M., Liu, G., Li, T., Xu, X., Li, L., Lin, H., Lv, J., Huang, X., et al. (2019) · Molecules · doi:10.3390/molecules24224038 · Cited by 54 · see citing works
Domínguez, I., Romero‐González, R., Arrebola, F. J., Vidal, J. L. M., & Frenich, A. G. (2016) · Trends in Environmental Analytical Chemistry · doi:10.1016/j.teac.2016.09.001 · Cited by 53 · see citing works
Seasonal variation of chloro-s-triazines in the Hartbeespoort Dam catchment, South Africa
Rimayi, C. C., Odusanya, D., Weiss, J. M., et al. (2017) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2017.09.119 · Cited by 51 · see citing works
Gutiérrez‐Serpa, A., Rocío‐Bautista, P., Pino, V., et al. (2017) · Journal of Separation Science · doi:10.1002/jssc.201700046 · Cited by 49 · see citing works
Wang, H., Qu, B., Liu, H., et al. (2017) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2017.11.046 · Cited by 49 · see citing works
Er, E. Ö., Çağlak, A., Engin, G. Ö., et al. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.01.040 · Cited by 49 · see citing works
Vera, R., Insa, S., Fontàs, C., et al. (2018) · Talanta · doi:10.1016/j.talanta.2018.03.056 · Cited by 45 · see citing works
Aravinna, P., Priyantha, N., Pitawala, H. M. T. G. A., et al. (2016) · Journal of Environmental Science and Health Part B · doi:10.1080/03601234.2016.1229445 · Cited by 44 · see citing works
Applications of solid‐phase micro‐extraction with mass spectrometry in pesticide analysis
Liang, D., Liu, W., Raza, R., Bai, Y., & Liu, H. (2018) · Journal of Separation Science · doi:10.1002/jssc.201800804 · Cited by 44 · see citing works
Kim, Y.-A., El‐Aty, A. M. A., Rahman, M. M., et al. (2018) · Journal of Chromatography B · doi:10.1016/j.jchromb.2018.01.015 · Cited by 40 · see citing works
Kaur, R., Kaur, R., Rani, S., Malik, A. K., Kabir, A., Furton, K. G., & Samanidou, V. (2019) · Molecules · doi:10.3390/molecules24061013 · Cited by 40 · see citing works
Muckoya, V. A., Nomngongo, P. N., & Ngila, J. C. (2020) · International Journal of Environmental Science and Technology · doi:10.1007/s13762-020-02625-z · Cited by 39 · see citing works
Jabali, Y., Millet, M., & El-Hoz, M. (2020) · Environmental Science and Pollution Research · doi:10.1007/s11356-020-08089-5 · Cited by 39 · see citing works
Zhang, Y.-R., Qin, P., Lu, S.-Y., Liu, X.-B., Zhai, J., Xu, J., Wang, Y.-Q., Zhang, G.-D., Liu, X.-H., & Wan, Z. (2020) · Environmental science and pollution research international · doi:10.1007/s11356-020-10288-z · Cited by 39 · see citing works
Ma, J.-P., Xiao, R.-H., Li, J.-H., Li, J., Shi, B., Liang, Y.-J., Lu, W.-H., & Chen, L.-X. (2011) · Journal of Separation Science · doi:10.1002/jssc.201000860 · Cited by 38 · see citing works
Wang, Q., & Kelly, B. C. (2017) · Chemosphere · doi:10.1016/j.chemosphere.2017.05.113 · Cited by 37 · see citing works
Taghani, A., Goudarzi, N., Bagherian, G., et al. (2018) · Journal of Separation Science · doi:10.1002/jssc.201701276 · Cited by 36 · see citing works
Barbosa, P. G. A., Martins, F. I. C. C., Lima, L. K., et al. (2017) · Food Analytical Methods · doi:10.1007/s12161-017-1017-9 · Cited by 32 · see citing works
Silva, R. D. O., de Castro, R. C., Milhome, M. A. L., et al. (2014) · LWT · doi:10.1016/j.lwt.2014.05.035 · Cited by 30 · see citing works
Akkbik, M., & Hazer, O. (2017) · Analytical Letters · doi:10.1080/00032719.2017.1284859 · Cited by 30 · see citing works
Cavalcante, R. M., de Lima, D. M., Fernandes, G. M., & Duaví, W. C. (2012) · Talanta · doi:10.1016/j.talanta.2012.02.015 · Cited by 28 · see citing works
Tak, S., Tiwari, A., & Vellanki, B. P. (2020) · Environmental Monitoring & Assessment · doi:10.1007/s10661-020-08303-4 · Cited by 28 · see citing works
Zhang, X., Ma, X., Li, X., Li, C., Wang, R., & Chen, M. (2018) · Water Air & Soil Pollution · doi:10.1007/s11270-018-3930-y · Cited by 26 · see citing works
Dargahi, R., Ebrahimzadeh, H., & Alizadeh, R. (2018) · Microchimica Acta · doi:10.1007/s00604-018-2692-y · Cited by 25 · see citing works
Kongphonprom, K., & Burakham, R. (2015) · Analytical Letters · doi:10.1080/00032719.2015.1081917 · Cited by 24 · see citing works
Majdafshar, M., Piryaei, M., Abolghasemi, M. M., et al. (2019) · Separation Science and Technology · doi:10.1080/01496395.2019.1572625 · Cited by 22 · see citing works
Tan, B., Xiong, J., Li, H., et al. (2020) · Journal of Separation Science · doi:10.1002/jssc.202000115 · Cited by 21 · see citing works
Pasupuleti, R. R., Tsai, P., & Ponnusamy, V. K. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.05.030 · Cited by 20 · see citing works
Pietrzak, D., Wątor, K., Pękała, D., Wójcik, J., Chochorek, A., Kmiecik, E., & Kania, J. (2019) · Journal of Environmental Science and Health, Part B · doi:10.1080/03601234.2019.1574173 · Cited by 19 · see citing works
Martins, F. I. C. C., Barbosa, P. G. A., Zocolo, G. J., et al. (2018) · Chromatographia · doi:10.1007/s10337-018-3483-7 · Cited by 18 · see citing works
Wang, T., Zhang, R., Gong, Z. L., et al. (2020) · ChemistrySelect · doi:10.1002/slct.201904231 · Cited by 16 · see citing works
Sun, P., Liu, M., Zhang, X., et al. (2020) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-020-01923-0 · Cited by 16 · see citing works
de Pinho, G. P., Silvério, F. O., Neves, A. A., et al. (2010) · Química Nova · doi:10.1590/s0100-40422010000400028 · Cited by 14 · see citing works
Silva, V. P. D. A., Paz, M., Cavalcante, R. M., et al. (2016) · Journal of the Brazilian Chemical Society · doi:10.21577/0103-5053.20160264 · Cited by 13 · see citing works
Derbalah, A. S. H., Tahara, K., & Sakugawa, H. (2019) · International Journal of Environmental Science and Technology · doi:10.1007/s13762-019-02525-x · Cited by 13 · see citing works
Budak, T. B., Ayyıldız, M. F., Chormey, D. S., et al. (2020) · Environmental Monitoring and Assessment · doi:10.1007/s10661-020-8209-2 · Cited by 12 · see citing works
Wang, H., Qu, B., Liu, H., et al. (2018) · International Journal of Environmental & Analytical Chemistry · doi:10.1080/03067319.2018.1475563 · Cited by 9 · see citing works
Sifatullah, K. M., & Semra Tuncel, G. (2018) · Journal of Analytical & Bioanalytical Techniques · doi:10.4172/2155-9872.1000409 · Cited by 5 · see citing works
Sun, Y., Lv, H., Yu, N., et al. (2018) · International Conference on Energy and Environmental Protection (ICEEP) · doi:10.2991/iceep-18.2018.29 · Cited by 3 · see citing works
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Research works printed but not linked: 1
- European Community, Brussels. EC Council Directive 98/83/EC of November 3, on the quality of water intended for human consumption, Official Journal of European Communities, L 330, 32, 1998.
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Salehi, E., Dehghan, K., Najarzadekan, H., Karami, S., & Joolaei Ahranjani, P. (2025) · Journal of Separation Science · doi:10.1002/jssc.70315 · Cited by 11 · see citing works
- Authors
- da Silva Sousa, J., do Nascimento, H. O., de Oliveira Gomes, H., & do Nascimento, R. F.
- Venue
- Microchemical Journal
- Publisher
- Elsevier BV
- Published
- 2021-09
- Volume
- 168
- Pages
- 106359
- ISSN
- 0026-265X (ISSN-L)
- OpenAlex
- W3162521015
- Cited by
- 113
- References
- 87
- Citations by year
- 2026: 8 · 2025: 29 · 2024: 29 · 2023: 21 · 2022: 18 · 2021: 8
- FWCI
- 11.36
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Microchemical Journal (publishedVersion)
- Funders
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior
- CNPq
- FUNCAP
- Topics
- Life Sciences › Agricultural and Biological Sciences › Food Science › Pesticide Residue Analysis and Safety
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Environmental Science › Pollution › Pesticide and Herbicide Environmental Studies
- Keywords
- pesticide residues, groundwater contamination, surface water contamination, solid-phase extraction, solid-phase microextraction, carbamates, neonicotinoids, organochlorine pesticides, organophosphorus pesticides, pyrethroid insecticides, matrix effects, correction factors, matrix-matched calibration, tandem mass spectrometry, pesticide toxicity, water quality regulation
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