CoP nanosheet assembly grown on carbon cloth: A highly efficient electrocatalyst for hydrogen generation

Yang, Xiulin; Lu, Ang-Yu; Zhu, Yihan; Hedhili, Mohamed Nejib; Min, Shixiong; Huang, Kuo-Wei; Han, Yu; Li, Lain-Jong

doi:10.1016/j.nanoen.2015.05.026

Cited by 385Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsHydrogen Storage and Materials

CoP nanosheet assembly grown on carbon cloth: A highly efficient electrocatalyst for hydrogen generation

Yang, Xiulin, Lu, Ang-Yu, Zhu, Yihan, Hedhili, Mohamed Nejib, Min, Shixiong, Huang, Kuo-Wei, Han, Yu, Li, Lain-Jong·2015·Nano Energy

DOI 10.1016/j.nanoen.2015.05.026

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Abstract

There exists a strong demand to replace expensive noble metal catalysts with cheap metal sulfides or phosphides for hydrogen evolution reaction (HER). Recently metal phosphides such as NixP, FeP and CoP have been considered as promising candidates to replace Pt cathodes. Here we report that the nanocrystalline CoP nanosheet assembly on carbon cloth can be formed by a two-step process: electrochemical deposition of Co species followed by gas phase phosphidation. The CoP catalyst in this report exhibits a Tafel slope of 30.1 mV/dec in 0.5 M H2SO4 and 42.6 mV/dec in 1 M KOH. The high HER performance of our CoP catalysts is attributed to the rugae-like morphology which results in a high double-layer capacitance and high density of active sites, estimated as 7.77×1017 sites/cm2.

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The Co 2p peaks at 779.0 eV and 793.7 eV are assigned to Co 2p3/2 and Co 2p1/2, attributed to CoP.
“the two peaks at 779.0 eV and 793.7 eV are assigned to Co 2p3/2 and Co 2p1/2, respectively, which are attributed to the binding energies of Co 2p in CoP.38,39”
From M X P(M = Co/Ni)@carbon core–shell nanoparticles embedded in 3D cross-linked graphene aerogel derived from seaweed biomass for hydrogen evolution reaction (2018) · cites this paper as [39]

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Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001 · see citing works
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911 · see citing works
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Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D. C. B., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., et al. (2013) · Nature Materials · doi:10.1038/nmat3700 · Cited by 2,641 · see citing works
Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373 · see citing works
Synthesis of MoS 2 and MoSe 2 Films with Vertically Aligned Layers
Kong, D., Wang, H., Cha, J. J., Pasta, M., Koski, K. J., Yao, J., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl400258t · Cited by 2,250 · see citing works
Two-dimensional transition metal dichalcogenide nanosheet-based composites
Tan, C., & Zhang, H. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00182f · Cited by 1,605 · see citing works
CoSe 2 Nanoparticles Grown on Carbon Fiber Paper: An Efficient and Stable Electrocatalyst for Hydrogen Evolution Reaction
Kong, D., Wang, H., Lu, Z., & Cui, Y. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501497n · Cited by 1,392 · see citing works
Catalysts for Hydrogen Evolution from the [NiFe] Hydrogenase to the Ni 2 P(001) Surface: The Importance of Ensemble Effect
Liu, P., & Rodriguez, J. A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0540019 · Cited by 1,244 · see citing works
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240 · see citing works
Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces
Sheng, W., Myint, M., Chen, J. G., & Yan, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00045a · Cited by 1,202 · see citing works
XPS studies of solvated metal atom dispersed (SMAD) catalysts. Evidence for layered cobalt-manganese particles on alumina and silica
Tan, B. J., Klabunde, K. J., & Sherwood, P. M. A. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00003a019 · Cited by 1,094 · see citing works
Carbon nanotubes decorated with CoP nanocrystals: a highly active non-noble-metal nanohybrid electrocatalyst for hydrogen evolution.
Liu, Q., Tian, J.-Q., Cui, W., Jiang, P., Cheng, N., Asiri, A. M., & Sun, X.-P. (2014) · Angewandte Chemie · doi:10.1002/anie.201404161 · Cited by 1,057 · see citing works
Molybdenum Phosphosulfide: An Active, Acid‐Stable, Earth‐Abundant Catalyst for the Hydrogen Evolution Reaction
Kibsgaard, J., & Jaramillo, T. F. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408222 · Cited by 1,048 · see citing works
A nanoporous molybdenum carbide nanowire as an electrocatalyst for hydrogen evolution reaction
Liao, L., Wang, S., Xiao, J., Bian, X., Zhang, Y., Scanlon, M. D., Hu, X., Tang, Y. D., Liu, B., & Girault, H. H. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42441c · Cited by 1,044 · see citing works
First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
Kong, D., Cha, J. J., Wang, H., Lee, H. R., & Cui, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42413h · Cited by 1,031 · see citing works
From Hydrogenases to Noble Metal–Free Catalytic Nanomaterials for H 2 Production and Uptake
Goff, A. L., Artero, V., Jousselme, B., Tran, P. D., Guillet, N., Metayé, R., Fihri, A., Palacin, S., & Fontecave, M. (2009) · Science · doi:10.1126/science.1179773 · Cited by 955 · see citing works
Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production
Chen, W., Wang, C., Sasaki, K., Marinković, N., Xu, W., Muckerman, J. T., Zhu, Y., & Adžić, R. R. (2013) · Energy & Environmental Science · doi:10.1039/c2ee23891h · Cited by 934 · see citing works
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Jiang, P., Liu, Q., Liang, Y., Tian, J., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201406848 · Cited by 885 · see citing works
Self‐Supported Cu3P Nanowire Arrays as an Integrated High‐Performance Three‐Dimensional Cathode for Generating Hydrogen from Water
Tian, J., Liu, Q., Cheng, N., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403842 · Cited by 851 · see citing works
Solution-phase epitaxial growth of noble metal nanostructures on dispersible single-layer molybdenum disulfide nanosheets
Huang, X., Zeng, Z., Bao, S., Wang, M., Qi, X., Fan, Z., & Zhang, H. (2013) · Nature Communications · doi:10.1038/ncomms2472 · Cited by 849 · see citing works
Multiple Phases of Molybdenum Carbide as Electrocatalysts for the Hydrogen Evolution Reaction
Wan, C., Regmi, Y. N., & Leonard, B. M. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402998 · Cited by 827 · see citing works
One‐Pot, Facile, and Versatile Synthesis of Monolayer MoS 2 /WS 2 Quantum Dots as Bioimaging Probes and Efficient Electrocatalysts for Hydrogen Evolution Reaction
Xu, S., Li, D., & Wu, P. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201403863 · Cited by 823 · see citing works
Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting
Rausch, B., Symes, M. D., Chisholm, G., & Cronin, L. (2014) · Science · doi:10.1126/science.1257443 · Cited by 770 · see citing works
Highly Efficient Electrocatalytic Hydrogen Production by MoS x Grown on Graphene‐Protected 3D Ni Foams
Chang, Y., Lin, C., Chen, T., Hsu, C., Lee, Y., Zhang, W., Wei, K., & Li, L. (2013) · Advanced Materials · doi:10.1002/adma.201202920 · Cited by 744 · see citing works
Self-citation
MoSe 2 and WSe 2 Nanofilms with Vertically Aligned Molecular Layers on Curved and Rough Surfaces
Wang, H., Kong, D., Johanes, P., Cha, J. J., Zheng, G., Yan, K., Liu, N., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl401944f · Cited by 693 · see citing works
Ultrathin WS2 Nanoflakes as a High‐Performance Electrocatalyst for the Hydrogen Evolution Reaction
Cheng, L., Huang, W., Gong, Q., Liu, C., Liu, Z., Li, Y., & Dai, H. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402315 · Cited by 690 · see citing works
One‐pot Synthesis of CdS Nanocrystals Hybridized with Single‐Layer Transition‐Metal Dichalcogenide Nanosheets for Efficient Photocatalytic Hydrogen Evolution
Chen, J., Wu, X., Yin, L., Li, B., Hong, X., Fan, Z., Chen, B., Xue, C., & Zhang, H. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201410172 · Cited by 668 · see citing works
25th Anniversary Article: Hybrid Nanostructures Based on Two‐Dimensional Nanomaterials
Huang, X., Tan, C., Yin, Z., & Zhang, H. (2014) · Advanced Materials · doi:10.1002/adma.201304964 · Cited by 632 · see citing works
Two‐Dimensional Hybrid Nanosheets of Tungsten Disulfide and Reduced Graphene Oxide as Catalysts for Enhanced Hydrogen Evolution
Yang, J., Voiry, D., Ahn, S. J., Kang, D., Kim, A., Chhowalla, M., & Shin, H. S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201307475 · Cited by 529 · see citing works
Nanocrystalline Ni 5 P 4 : a hydrogen evolution electrocatalyst of exceptional efficiency in both alkaline and acidic media
Laursen, A. B., Patraju, K., Whitaker, M. J., Retuerto, M., Sarkar, T., Yao, N., Ramanujachary, K. V., Greenblatt, M., & Dismukes, G. C. (2015) · Energy & Environmental Science · doi:10.1039/c4ee02940b · Cited by 482 · see citing works
Electrocatalytic and Photocatalytic Hydrogen Production from Acidic and Neutral-pH Aqueous Solutions Using Iron Phosphide Nanoparticles
Callejas, J. F., McEnaney, J. M., Read, C. G., Crompton, J. C., Biacchi, A. J., Popczun, E. J., Gordon, T. R., Lewis, N. S., & Schaak, R. E. (2014) · ACS Nano · doi:10.1021/nn5048553 · Cited by 464 · see citing works
Determination of the Platinum and Ruthenium Surface Areas in Platinum−Ruthenium Alloy Electrocatalysts by Underpotential Deposition of Copper. I. Unsupported Catalysts
Green, C. L., & Kucernak, A. R. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0131931 · Cited by 423 · see citing works
Nickel/Nickel(II) Oxide Nanoparticles Anchored onto Cobalt(IV) Diselenide Nanobelts for the Electrochemical Production of Hydrogen
Xu, Y., Gao, M., Zheng, Y., Jiang, J., & Yu, S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201303495 · Cited by 403 · see citing works
Easily-prepared dinickel phosphide (Ni2P) nanoparticles as an efficient and robust electrocatalyst for hydrogen evolution
Feng, L., Vrubel, H., Bensimon, M., & Hu, X. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp00482e · Cited by 402 · see citing works
Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions
Vrubel, H., & Hu, X. (2012) · Angewandte Chemie · doi:10.1002/ange.201207111 · Cited by 389 · see citing works
Ultrathin S-doped MoSe 2 nanosheets for efficient hydrogen evolution
Xu, C. G., Peng, S., Tan, C., Ang, E. H., Tan, H., Zhang, H., & Yan, Q. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta00458b · Cited by 366 · see citing works
Novel Molybdenum Carbide–Tungsten Carbide Composite Nanowires and Their Electrochemical Activation for Efficient and Stable Hydrogen Evolution
Xiao, P., Ge, X., Wang, H., Liu, Z., Fisher, A. C., & Wang, X. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201403633 · Cited by 356 · see citing works
Growth of noble metal nanoparticles on single-layer TiS 2 and TaS 2 nanosheets for hydrogen evolution reaction
Zeng, Z., Tan, C., Huang, X., Bao, S., & Zhang, H. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42620c · Cited by 355 · see citing works
Component-Controllable WS2(1– x )Se2 x Nanotubes for Efficient Hydrogen Evolution Reaction
Xu, K., Wang, F., Wang, Z., Zhan, X., Wang, Q., Cheng, Z., Safdar, M., & He, J. (2014) · ACS Nano · doi:10.1021/nn503027k · Cited by 341 · see citing works
MoS2 nanoflower-decorated reduced graphene oxide paper for high-performance hydrogen evolution reaction
Ma, C.-B., Qi, X., Chen, B., Bao, S., Yin, Z., Wu, X.-J., Luo, Z., Wei, J., Zhang, H.-L., & Zhang, H. (2014) · Nanoscale · doi:10.1039/c3nr04975b · Cited by 331 · see citing works
Perpendicularly Oriented MoSe 2 /Graphene Nanosheets as Advanced Electrocatalysts for Hydrogen Evolution
Mao, S., Wen, Z., Ci, S., Guo, X., Ostrikov, K. K., & Chen, J. (2015) · Small · doi:10.1002/smll.201401598 · Cited by 298 · see citing works
CoP Nanosheet Arrays Supported on a Ti Plate: An Efficient Cathode for Electrochemical Hydrogen Evolution
Pu, Z., Liu, Q., Jiang, P., Asiri, A. M., Obaid, A. Y., & Sun, X. (2014) · Chemistry of Materials · doi:10.1021/cm501273s · Cited by 292 · see citing works
Recent advances in layered transition metal dichalcogenides for hydrogen evolution reaction
Yang, J., & Shin, H. S. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta14151a · Cited by 290 · see citing works
Polymorphic CoSe2with Mixed Orthorhombic and Cubic Phases for Highly Efficient Hydrogen Evolution Reaction
Zhang, H., Yang, B., Wu, X., Li, Z., Lei, L., & Zhang, X. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am507373g · Cited by 278 · see citing works
MoP nanosheets supported on biomass-derived carbon flake: One-step facile preparation and application as a novel high-active electrocatalyst toward hydrogen evolution reaction
Cui, W., Liu, Q., Xing, Z., Asiri, A. M., Alamry, K., & Sun, X.-P. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2014.09.016 · Cited by 247 · see citing works
CoP as an Acid-Stable Active Electrocatalyst for the Hydrogen-Evolution Reaction: Electrochemical Synthesis, Interfacial Characterization and Performance Evaluation
Saadi, F. H., Carim, A. I., Verlage, E., Hemminger, J. C., Lewis, N. S., & Soriaga, M. P. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp5054452 · Cited by 241 · see citing works
Comparative study on MoS2 and WS2 for electrocatalytic water splitting
Chen, T.-Y., Chang, Y., Hsu, C.-L., Wei, K., Chiang, C., & Li, L. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.07.021 · Cited by 221 · see citing works
Self-citation
Deposition of β-Co(OH)2 Films by Electrochemical Reduction of Tris(ethylenediamine)cobalt(III) in Alkaline Solution
Koza, J. A., Hull, C. M., Liu, Y.-C., & Switzer, J. A. (2013) · Chemistry of Materials · doi:10.1021/cm400579k · Cited by 212 · see citing works
Electrochemically Fabricated Polypyrrole and MoSx Copolymer Films as a Highly Active Hydrogen Evolution Electrocatalyst
Wang, T., Zhuo, J., Du, K., Chen, B., Zhu, Z., Shao, Y., & Li, M. (2014) · Advanced Materials · doi:10.1002/adma.201400265 · Cited by 201 · see citing works
Amorphous MoS x Cl y electrocatalyst supported by vertical graphene for efficient electrochemical and photoelectrochemical hydrogen generation
Zhang, X., Meng, F., Mao, S., Ding, Q., Shearer, M. J., Faber, M. S., Chen, J., Hamers, R. J., & Jin, S. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03240c · Cited by 195 · see citing works
Nano-tungsten carbide decorated graphene as co-catalysts for enhanced hydrogen evolution on molybdenum disulfide
Yan, Y. P., Xia, B. Y., Qi, X., Wang, H., Xu, R. Q., Wang, J., Zhang, H., & Wang, X. (2013) · Chemical Communications · doi:10.1039/c3cc41031e · Cited by 185 · see citing works
FeP Nanoparticles Film Grown on Carbon Cloth: An Ultrahighly Active 3D Hydrogen Evolution Cathode in Both Acidic and Neutral Solutions
Tian, J., Liu, Q., Liang, Y., Xing, Z., Asiri, A. M., & Sun, X. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am5064684 · Cited by 180 · see citing works
Facile synthesis of various highly dispersive CoP nanocrystal embedded carbon matrices as efficient electrocatalysts for the hydrogen evolution reaction
Li, M., Liu, X., Xiong, Y., Bo, X., Zhang, Y., Han, C., & Guo, L. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06630h · Cited by 165 · see citing works
Template-assisted synthesis of CoP nanotubes to efficiently catalyze hydrogen-evolving reaction
Du, H., Liu, Q., Cheng, N., Asiri, A. M., Sun, X., & Li, C. M. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta02368d · Cited by 152 · see citing works
Phosphides of the B31 (MnP) Structure Type.
Rundqvist, S., Sillén, L. G., Timm, D., Motzfeldt, K., Theander, O., & Flood, H. (1962) · Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry · doi:10.3891/acta.chem.scand.16-0287 · Cited by 149 · see citing works
Low-cost industrially available molybdenum boride and carbide as “platinum-like” catalysts for the hydrogen evolution reaction in biphasic liquid systems
Scanlon, M. D., Bian, X., Vrubel, H., Amstutz, V., Schenk, K., Hu, X., Liu, B., & Girault, H. H. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp44522k · Cited by 145 · see citing works
Electrocatalytic behaviour of Co–Ni–R (R=Rare earth metal) crystalline alloys as electrode materials for hydrogen evolution reaction in alkaline medium
Rosalbino, F., Delsante, S., Borzone, G., & Angelini, E. P. M. V. (2008) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2008.07.125 · Cited by 139 · see citing works
Enhanced electrocatalytic activity of MoP microparticles for hydrogen evolution by grinding and electrochemical activation
Wang, T., Du, K., Liu, W., Zhu, Z., Shao, Y., & Li, M. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06651k · Cited by 103 · see citing works
One-pot synthesis of diiron phosphide/nitrogen-doped graphene nanocomposite for effective hydrogen generation
Huang, Z., Lv, C., Chen, Z., Chen, Z., Tian, F., & Zhang, C. (2015) · Nano Energy · doi:10.1016/j.nanoen.2015.01.027 · Cited by 97 · see citing works
Cobalt phosphide nanoparticles film growth on carbon cloth: A high-performance cathode for electrochemical hydrogen evolution
Li, Q., Xing, Z., Asiri, A. M., Jiang, P., & Sun, X. (2014) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2014.08.099 · Cited by 94 · see citing works
Three‐Dimensional Molybdenum Sulfide Sponges for Electrocatalytic Water Splitting
Chang, Y., Wu, F., Chen, T., Hsu, C., Chen, C., Wiryo, F., Wei, K., Chiang, C., & Li, L. (2013) · Small · doi:10.1002/smll.201302407 · Cited by 88 · see citing works
Self-citation
X-ray photoelectron spectroscopic evidence of interlayer complex formation between Co(II) and N-heterocycles in α-Zr(hpo4)2 · H2O
Mattogno, G., Ferragina, C., Massucci, M. A., Patrono, P., & Ginestra, A. L. (1988) · Journal of Electron Spectroscopy and Related Phenomena · doi:10.1016/0368-2048(88)85026-6 · Cited by 62 · see citing works
Molybdenum Phosphide Flakes Catalyze Hydrogen Generation in Acidic and Basic Solutions
Chen, Z., Lv, C., Chen, Z., Jin, L., Wang, J. X., & Huang, Z. (2014) · American Journal of Analytical Chemistry · doi:10.4236/ajac.2014.517127 · Cited by 21 · see citing works
Copper Underpotential Deposition on Gold in the Presence of Polyethylene Glycol and Chloride
Chiu, Y.-D., Dow, W., Liu, Y.-F., Lee, Y., Yau, S.-L., & Huang, S.-M. (2011) · International Journal of Electrochemical Science · doi:10.1016/s1452-3981(23)18261-7 · Cited by 14 · see citing works
Structure transitions between copper-sulphate and copper-chloride UPD phases on Au(111)
Pobelov, I. V., Nagy, G., & Wandlowski, T. (2009) · Journal of Chemical Sciences · doi:10.1007/s12039-009-0089-5 · Cited by 9 · see citing works

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One‐Step Construction of N,P‐Codoped Porous Carbon Sheets/CoP Hybrids with Enhanced Lithium and Potassium Storage
Bai, J., Xi, B. J., Mao, H., Lin, Y., Ma, X., Feng, J., & Xiong, S. L. (2018) · Advanced Materials · doi:10.1002/adma.201802310 · Cited by 446 · see citing works
Electrocatalysts for the hydrogen evolution reaction in alkaline and neutral media. A comparative review
Ďurovič, M., Hnát, J., & Bouzek, K. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.229708 · Cited by 436 · see citing works
Noble-metal-free cobalt phosphide modified carbon nitride: An efficient photocatalyst for hydrogen generation
Yi, S., Yan, J., Wulan, B., Li, S., Liu, K., & Jiang, Q. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.07.046 · Cited by 418 · see citing works
Nickel foam and stainless steel mesh as electrocatalysts for hydrogen evolution reaction, oxygen evolution reaction and overall water splitting in alkaline media
Hu, X., Tian, X., Lin, Y., & Wang, Z. (2019) · RSC Advances · doi:10.1039/c9ra07258f · Cited by 412 · see citing works
Vertical CoP Nanoarray Wrapped by N,P‐Doped Carbon for Hydrogen Evolution Reaction in Both Acidic and Alkaline Conditions
Huang, X., Xu, X., Li, C., Wu, D., Cheng, D., & Cao, D. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201803970 · Cited by 351 · see citing works
MOF-Derived Formation of Ni 2 P–CoP Bimetallic Phosphides with Strong Interfacial Effect toward Electrocatalytic Water Splitting
Liang, X., Zheng, B., Chen, L., Zhang, J., Zhuang, Z., & Chen, B. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b06152 · Cited by 328 · see citing works
Lithiation-induced amorphization of Pd3P2S8 for highly efficient hydrogen evolution
Zhang, X., Luo, Z., Yu, P., Cai, Y., Du, Y., Wu, D., Gao, S. J., Tan, C., Li, Z. A., Ren, M., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0072-y · Cited by 314 · see citing works
Al-Doped CoP nanoarray: a durable water-splitting electrocatalyst with superhigh activity
Zhang, R., Tang, C., Kong, R., Du, G., Asiri, A. M., Chen, L., & Sun, X. (2017) · Nanoscale · doi:10.1039/c7nr00740j · Cited by 308 · see citing works
Hierarchical NiCoP nanocone arrays supported on Ni foam as an efficient and stable bifunctional electrocatalyst for overall water splitting
Li, J., Wei, G., Zhu, Y., Xi, Y., Pan, X., Ji, Y., Zatovsky, I. V., & Han, W. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta03947f · Cited by 306 · see citing works
Self-citation
Recent developments in earth-abundant and non-noble electrocatalysts for water electrolysis
Yu, F., Yu, L., Mishra, I. K., Yu, Y., Ren, Z., & Zhou, H. (2018) · Materials Today Physics · doi:10.1016/j.mtphys.2018.11.007 · Cited by 284 · see citing works
CoP nanowires coupled with CoMoP nanosheets as a highly efficient cooperative catalyst for hydrogen evolution reaction
Huang, X., Xu, X., Luan, X., & Cheng, D. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.104332 · Cited by 282 · see citing works
Highly acid-durable carbon coated Co3O4 nanoarrays as efficient oxygen evolution electrocatalysts
Yang, X., Li, H., Lu, A., Min, S., Idriss, Z., Hedhili, M. N., Huang, K., Idriss, H., & Li, L. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.035 · Cited by 262 · see citing works
Self-citation
Unique synergistic effects of ZIF-9(Co)-derived cobalt phosphide and CeVO4 heterojunction for efficient hydrogen evolution
Zhang, L., Hao, X., Li, J., Wang, Y., & Jin, Z. (2019) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(19)63454-6 · Cited by 262 · see citing works
Selective phosphidation: an effective strategy toward CoP/CeO 2 interface engineering for superior alkaline hydrogen evolution electrocatalysis
Zhang, R., Ren, X. Z., Hao, S., Ge, R., Liu, Z., Asiri, A. M., Chen, L., Zhang, Q., & Sun, X. (2018) · Journal of Materials Chemistry A · doi:10.1039/c7ta10237b · Cited by 246 · see citing works
In Situ Coupling of CoP Polyhedrons and Carbon Nanotubes as Highly Efficient Hydrogen Evolution Reaction Electrocatalyst
Wu, C., Yang, Y., Dong, D., Zhang, Y., & Li, J. (2017) · Small · doi:10.1002/smll.201602873 · Cited by 243 · see citing works
Preparation of NiCoP Hollow Quasi-Polyhedra and Their Electrocatalytic Properties for Hydrogen Evolution in Alkaline Solution
Li, Y., Liu, J., Chen, C., Zhang, X., & Chen, J. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b14127 · Cited by 235 · see citing works
Two-dimensional ultrathin arrays of CoP: Electronic modulation toward high performance overall water splitting
Zhou, L., Shao, M., Li, J., Jiang, S., Wei, M., & Duan, X. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.10.009 · Cited by 234 · see citing works
A layered Na 1−x Ni y Fe 1−y O 2 double oxide oxygen evolution reaction electrocatalyst for highly efficient water-splitting
Weng, B., Xu, F., Wang, C., Meng, W., Grice, C. R., & Yan, Y. (2016) · Energy & Environmental Science · doi:10.1039/c6ee03088b · Cited by 233 · see citing works
Surface reconstruction of cobalt phosphide nanosheets by electrochemical activation for enhanced hydrogen evolution in alkaline solution
Su, L., Cui, X., He, T., Zeng, L., Tian, H., Song, Y., Qi, K., & Xia, B. Y. (2018) · Chemical Science · doi:10.1039/c8sc04589e · Cited by 224 · see citing works
Transforming Nickel Hydroxide into 3D Prussian Blue Analogue Array to Obtain Ni2P/Fe2P for Efficient Hydrogen Evolution Reaction
Ge, Y., Dong, P. T., Craig, S. R., Ajayan, P. M., Ye, M., & Shen, J. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201800484 · Cited by 217 · see citing works
The urchin-like sphere arrays Co3O4 as a bifunctional catalyst for hydrogen evolution reaction and oxygen evolution reaction
Li, R., Zhou, D., Luo, J., Xu, W. M., Li, J., Li, S., Cheng, P., & Yuan, D. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.10.096 · Cited by 213 · see citing works
High‐Sulfur‐Vacancy Amorphous Molybdenum Sulfide as a High Current Electrocatalyst in Hydrogen Evolution
Lu, A., Yang, X., Tseng, C., Min, S., Lin, S., Hsu, C., Li, H., Idriss, H., Kuo, J., Huang, K., et al. (2016) · Small · doi:10.1002/smll.201602107 · Cited by 211 · see citing works
Self-citation
From water reduction to oxidation: Janus Co-Ni-P nanowires as high-efficiency and ultrastable electrocatalysts for over 3000 h water splitting
Li, W., Gao, X., Wang, X., Xiong, D., Huang, P., Song, W.-G., Bao, X., & Liu, L. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.08.126 · Cited by 211 · see citing works
Ultrafine CoP Nanoparticles Supported on Carbon Nanotubes as Highly Active Electrocatalyst for Both Oxygen and Hydrogen Evolution in Basic Media
Hou, C., Cao, S., Fu, W., & Chen, Y. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b09207 · Cited by 197 · see citing works
Theory-guided electrocatalyst engineering: From mechanism analysis to structural design
Zhang, M., Zhang, K., Ai, X., Liang, X., Zhang, Q., Chen, H., & Zou, X. (2022) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(22)64103-2 · Cited by 188 · see citing works
Structural Design of Amorphous CoMoPx with Abundant Active Sites and Synergistic Catalysis Effect for Effective Water Splitting
Huang, H., Cho, A., Kim, S., Jun, H., Lee, A., Han, J. W., & Lee, J. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202003889 · Cited by 187 · see citing works
Metal Doping Effect of the M-Co2P/Nitrogen-Doped Carbon Nanotubes (M = Fe, Ni, Cu) Hydrogen Evolution Hybrid Catalysts.
Pan, Y., Liu, Y.-Q., Lin, Y., & Liu, C.-G. (2016) · ACS Applied Materials and Interfaces · doi:10.1021/acsami.6b02023 · Cited by 162 · see citing works
Electrospun three dimensional Co/CoP@nitrogen-doped carbon nanofibers network for efficient hydrogen evolution
Li, Y., Li, H., Cao, K., Jin, T., Wang, X., Sun, H., Ning, J., Wang, Y., & Jiao, L. (2017) · Energy storage materials · doi:10.1016/j.ensm.2017.11.006 · Cited by 183 · see citing works
Facile Synthesis of Hierarchical Hollow CoP@C Composites with Superior Performance for Sodium and Potassium Storage
Liu, Q., Hu, Z., Liang, Y., Li, L., Zou, C., Jin, H., Wang, S., Lu, H., Gu, Q., Chou, S., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201913683 · Cited by 182 · see citing works
Self-citation
Robust NiCoP/CoP Heterostructures for Highly Efficient Hydrogen Evolution Electrocatalysis in Alkaline Solution
Liu, H., Ma, X., Hu, H., Pan, Y., Zhao, W., Liu, J., Zhao, X., Wang, J., Yang, Z., Zhao, Q., et al. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b00592 · Cited by 181 · see citing works
Applications of metal–organic framework-derived N, P, S doped materials in electrochemical energy conversion and storage
Peng, Y., Bai, Y., Liu, C., Cao, S., Kong, Q., & Pang, H. (2022) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214602 · Cited by 179 · see citing works
Electroless plated Ni–B films as highly active electrocatalysts for hydrogen production from water over a wide pH range
Zhang, P., Wang, M., Yang, Y., Yao, T., Han, H., & Sun, L. (2015) · Nano Energy · doi:10.1016/j.nanoen.2015.11.020 · Cited by 175 · see citing works
Novel thin/tunable gas diffusion electrodes with ultra-low catalyst loading for hydrogen evolution reactions in proton exchange membrane electrolyzer cells
Kang, Z., Yang, G., Mo, J., Li, Y., Yu, S., Cullen, D. A., Retterer, S. T., Toops, T. J., Bender, G., Pivovar, B. S., et al. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.03.015 · Cited by 175 · see citing works
Intermetallic borides: structures, synthesis and applications in electrocatalysis
Chen, H., & Zou, X. (2020) · Inorganic Chemistry Frontiers · doi:10.1039/d0qi00146e · Cited by 173 · see citing works
Vapor–solid synthesis of monolithic single-crystalline CoP nanowire electrodes for efficient and robust water electrolysis
Li, W., Gao, X., Xiong, D., Xia, F., Liu, J., Song, W.-G., Xu, J., Thalluri, S. M., Cerqueira, M. F., Fu, X., et al. (2017) · Chemical Science · doi:10.1039/c6sc05167g · Cited by 172 · see citing works
Metal–Organic Framework-Derived CoWP@C Composite Nanowire Electrocatalyst for Efficient Water Splitting
Weng, B., Grice, C. R., Meng, W., Guan, L., Xu, F., Yu, Y., Wang, C., Zhao, D., & Yan, Y. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00584 · Cited by 168 · see citing works
Two-dimensional metal–organic frameworks and their derivatives for electrochemical energy storage and electrocatalysis
Zhao, K., Zhu, W., Liu, S., Wei, X., Ye, G., Su, Y., & He, Z. (2020) · Nanoscale Advances · doi:10.1039/c9na00719a · Cited by 167 · see citing works
Multiscale structural optimization: Highly efficient hollow iron-doped metal sulfide heterostructures as bifunctional electrocatalysts for water splitting
Guo, Y., Zhou, X. H., Tang, J., Tanaka, S., Kaneti, Y. V., Na, J., Jiang, B., Yamauchi, Y., Bando, Y., & Sugahara, Y. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.104913 · Cited by 167 · see citing works
Interfacial Engineering of Nickel Hydroxide on Cobalt Phosphide for Alkaline Water Electrocatalysis
Yu, X., Zhao, J. H., & Johnsson, M. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202101578 · Cited by 167 · see citing works
Hollow CoP nanopaticle/N-doped graphene hybrids as highly active and stable bifunctional catalysts for full water splitting
Yu, X., Zhang, S., Li, C., Zhu, C., Chen, Y., Gao, P., Qi, L., & Zhang, X. (2016) · Nanoscale · doi:10.1039/c6nr01867j · Cited by 165 · see citing works
Cobalt Phosphide Modified Titanium Oxide Nanophotocatalysts with Significantly Enhanced Photocatalytic Hydrogen Evolution from Water Splitting
Yue, X., Yi, S., Wang, R., Zhang, Z., & Qiu, S. (2017) · Small · doi:10.1002/smll.201603301 · Cited by 165 · see citing works
Fe( iii ) doped NiS 2 nanosheet: a highly efficient and low-cost hydrogen evolution catalyst
Yan, J., Wu, H., li, P., Chen, H., Jiang, R., & Liu, S. F. (2017) · Journal of Materials Chemistry A · doi:10.1039/c6ta11041j · Cited by 164 · see citing works
Activating basal-plane catalytic activity of two-dimensional MoS2 monolayer with remote hydrogen plasma
Cheng, C.-C., Lu, A., Tseng, C., Yang, X., Hedhili, M. N., Chen, M., Wei, K., & Li, L. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.09.010 · Cited by 163 · see citing works
Self-citation
A ternary cobalt–molybdenum–vanadium layered double hydroxide nanosheet array as an efficient bifunctional electrocatalyst for overall water splitting
Bao, J., Wang, Z., Xie, J., Xu, L., Lei, F., Guan, M., Zhao, Y. C., Huang, Y., & Li, H. (2019) · Chemical Communications · doi:10.1039/c9cc00269c · Cited by 160 · see citing works
Transition Metal Non‐Oxides as Electrocatalysts: Advantages and Challenges
Das, C., Sinha, N., & Roy, P. (2022) · Small · doi:10.1002/smll.202202033 · Cited by 162 · see citing works
Hierarchical Microcables Constructed by CoP@C⊂Carbon Framework Intertwined with Carbon Nanotubes for Efficient Lithium Storage
Guo, K., Xi, B. J., Wei, R., Li, H., Feng, J., & Xiong, S. L. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902913 · Cited by 157 · see citing works
Carbon quantum dots enhanced the activity for the hydrogen evolution reaction in ruthenium-based electrocatalysts
Li, W., Wei, Z., Wang, B., Liu, Y., Song, H., Tang, Z., Yang, B. J., & Lu, S. (2019) · Materials Chemistry Frontiers · doi:10.1039/c9qm00618d · Cited by 156 · see citing works
Developments and Perspectives on Robust Nano‐ and Microstructured Binder‐Free Electrodes for Bifunctional Water Electrolysis and Beyond
Chandrasekaran, S., Khandelwal, M., Fan, D., Sui, L., Chung, J. S., Misra, R. D. K., Yin, P., Kim, E. J., Kim, W., Vanchiappan, A., et al. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202200409 · Cited by 155 · see citing works
Configuration‐dependent stretchable all‐solid‐state supercapacitors and hybrid supercapacitors
Amiri, A., Bruno, A., & Polycarpou, A. A. (2023) · Carbon Energy · doi:10.1002/cey2.320 · Cited by 155 · see citing works
NiCoP Nanoarray: A Superior Pseudocapacitor Electrode with High Areal Capacitance
Kong, M., Wang, Z., Wang, W., Ma, M., Liu, D., Hao, S., Kong, R., Du, G., Asiri, A. M., Yao, Y., et al. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201700017 · Cited by 152 · see citing works
Recent advances in cobalt phosphide based materials for energy-related applications
Wang, J., Liu, Z., Zheng, Y., Cui, L., Yang, W. R., & Liu, J. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta08386f · Cited by 149 · see citing works
Morphology-Controllable Synthesis of Cobalt Telluride Branched Nanostructures on Carbon Fiber Paper as Electrocatalysts for Hydrogen Evolution Reaction
Wang, K., Ye, Z., Liu, C., Xi, D., Zhou, C., Shi, Z., Xia, H., Liu, G., & Qiao, G. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b10835 · Cited by 148 · see citing works
Porous Co–P foam as an efficient bifunctional electrocatalyst for hydrogen and oxygen evolution reactions
Oh, S., Kim, H., Kwon, Y., Kim, M., Cho, E., & Kwon, H. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta06761a · Cited by 148 · see citing works
Nanoporous CoP3 Nanowire Array: Acid Etching Preparation and Application as a Highly Active Electrocatalyst for the Hydrogen Evolution Reaction in Alkaline Solution
Ji, Y., Li, Y., Ren, X. Z., Cui, G., Xiong, X., & Sun, X. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b01714 · Cited by 148 · see citing works
Flexible 3D carbon cloth as a high-performing electrode for energy storage and conversion
Shi, H., Wen, G., Nie, Y. G., Zhang, G., & Duan, H. (2020) · Nanoscale · doi:10.1039/c9nr09785f · Cited by 146 · see citing works
Rugae-like Ni2P-CoP nanoarrays as a bi-functional catalyst for hydrogen generation: NaBH4 hydrolysis and water reduction
Guo, J., Wang, B., Yang, D., Wan, Z., Yan, P., Tian, J., Isimjan, T. T., & Yang, X. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118584 · Cited by 145 · see citing works
Self-citation
A review of the electrocatalysts on hydrogen evolution reaction with an emphasis on Fe, Co and Ni-based phosphides
Ge, Z., Fu, B., Zhao, J., Li, X., Ma, B., & Chen, Y. (2020) · Journal of Materials Science · doi:10.1007/s10853-020-05010-w · Cited by 143 · see citing works
Atom Doping Engineering of Transition Metal Phosphides for Hydrogen Evolution Reactions
Bai, H., Chen, D., Ma, Q., Qin, R., Xu, H., Zhao, Y., Chen, J., & Mu, S. C. (2022) · Electrochemical Energy Reviews · doi:10.1007/s41918-022-00161-7 · Cited by 142 · see citing works
Towards the prominent cocatalytic effect of ultra-small CoP particles anchored on g-C3N4 nanosheets for visible light driven photocatalytic H2 production
Luo, B., Song, R., Geng, J., Liu, X., Jing, D., Wang, M., & Cheng, C. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.117819 · Cited by 137 · see citing works
Construction of hierarchical FeP/Ni 2 P hollow nanospindles for efficient oxygen evolution
Feng, Y., Xu, C., Hu, E., Xia, B., Ning, J., Zheng, C., Zhong, Y., Zhang, Z., & Hu, Y. M. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta03933j · Cited by 136 · see citing works
Multiregion Janus-Featured Cobalt Phosphide-Cobalt Composite for Highly Reversible Room-Temperature Sodium-Sulfur Batteries
Yan, Z., Liang, Y., Hua, W., Zhang, X., Lai, W., Hu, Z., Wang, W., Peng, J., Indris, S., Wang, Y., et al. (2020) · ACS Nano · doi:10.1021/acsnano.0c03737 · Cited by 135 · see citing works
Symmetrical synergy of hybrid Co9S8-MoSx electrocatalysts for hydrogen evolution reaction
Zhou, X., Yang, X., Hedhili, M. N., Li, H., Min, S., Ming, J., Huang, K., Zhang, W., & Li, L. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.01.011 · Cited by 133 · see citing works
Self-citation
Designing Self-Supported Electrocatalysts for Electrochemical Water Splitting: Surface/Interface Engineering toward Enhanced Electrocatalytic Performance
Wang, P., & Wang, B. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c17448 · Cited by 133 · see citing works
Recent advances in cobalt phosphide-based materials for electrocatalytic water splitting: From catalytic mechanism and synthesis method to optimization design
Deng, R., Guo, M., Wang, C., & Zhang, Q. (2022) · Nano Materials Science · doi:10.1016/j.nanoms.2022.04.003 · Cited by 133 · see citing works
Formation of three-dimensional hierarchical pompon-like cobalt phosphide hollow microspheres for asymmetric supercapacitor with improved energy density
Ding, L., Zhang, K., Chen, L., Yu, Z., Zhao, Y., Zhu, G., Chen, G., Yan, D., Xu, H., & Yu, A. (2019) · Electrochimica Acta · doi:10.1016/j.electacta.2018.12.180 · Cited by 132 · see citing works
Highly Efficient Hydrogen Evolution from a Mesoporous Hybrid of Nickel Phosphide Nanoparticles Anchored on Cobalt Phosphosulfide/Phosphide Nanosheet Arrays
Sun, J., Ren, M., Yu, L., Yang, Z., Xie, L., Tian, F., Yu, Y., Ren, Z., Chen, S., & Zhou, H. (2019) · Small · doi:10.1002/smll.201804272 · Cited by 132 · see citing works
Carbon cloth/transition metals-based hybrids with controllable architectures for electrocatalytic hydrogen evolution - A review
Koutavarapu, R., Reddy, C. V., Babu, B., Reddy, K. R., Cho, M., & Shim, J. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.05.163 · Cited by 132 · see citing works
A critical review: 1D/2D nanostructured self-supported electrodes for electrochemical water splitting
Wang, P., Jia, T., & Wang, B. (2020) · Journal of Power Sources · doi:10.1016/j.jpowsour.2020.228621 · Cited by 132 · see citing works
Combining Heterojunction Engineering with Surface Cocatalyst Modification To Synergistically Enhance the Photocatalytic Hydrogen Evolution Performance of Cadmium Sulfide Nanorods
Wang, P., Wu, T., Wang, C., Hou, J., Qian, J., & Ao, Y. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b01043 · Cited by 131 · see citing works
CoP/N-Doped Carbon Hollow Spheres Anchored on Electrospinning Core–Shell N-Doped Carbon Nanofibers as Efficient Electrocatalysts for Water Splitting
Tong, J., Li, Y., Bo, L., Li, W., Li, T., Zhang, Q., Kong, D., Wang, H., & Li, C. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b04643 · Cited by 131 · see citing works
A novel CoP/MoS 2 -CNTs hybrid catalyst with Pt-like activity for hydrogen evolution
Pan, Y., Lin, Y., Liu, Y., & Liu, C. (2016) · Catalysis Science & Technology · doi:10.1039/c5cy02299a · Cited by 130 · see citing works
Noble-metal-free nickel phosphide modified CdS/C 3 N 4 nanorods for dramatically enhanced photocatalytic hydrogen evolution under visible light irradiation
Wu, T., Wang, P., Qian, J., Ao, Y., Wang, C., & Hou, J. (2017) · Dalton Transactions · doi:10.1039/c7dt02929b · Cited by 127 · see citing works
Three-dimensional well-mixed / highly-densed NiS-CoS nanorod arrays: An efficient and stable bifunctional electrocatalyst for hydrogen and oxygen evolution reactions
Ma, Z., Zhao, Q., Li, J., Tang, B., Zhang, Z., & Wang, X. (2017) · Electrochimica Acta · doi:10.1016/j.electacta.2017.11.055 · Cited by 123 · see citing works
Nanostructured palladium catalyst poisoning depressed by cobalt phosphide in the electro-oxidation of formic acid for fuel cells
Feng, L., Chang, J., Jiang, K. P., Xue, H., Liu, C., Cai, W., Xing, W., & Zhang, J. J. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.10.023 · Cited by 122 · see citing works
Hierarchical three-dimensional framework interface assembled from oxygen-doped cobalt phosphide layer-shelled metal nanowires for efficient electrocatalytic water splitting
Doan, T. L. L., Tran, D. T., Nguyen, D. C., Le, H. T., Kim, N. H., & Lee, J. H. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118268 · Cited by 120 · see citing works
A Minireview on Nickel‐Based Heterogeneous Electrocatalysts for Water Splitting
Li, Y., Bao, X., Chen, D., Wang, Z., Dewangan, N., Li, M., Xu, Z. Q., Wang, J., Kawi, S., & Zhong, Q. (2019) · ChemCatChem · doi:10.1002/cctc.201901682 · Cited by 118 · see citing works
Anion-Exchange-Membrane Electrolysis with Alkali-Free Water Feed
Muhyuddin, M., Santoro, C., Osmieri, L., Ficca, V. C. A., Friedman, A., Yassin, K., Pagot, G., Negro, E., Konovalova, A., Lindquist, G. A., et al. (2025) · Chemical Reviews · doi:10.1021/acs.chemrev.4c00466 · Cited by 117 · see citing works
CoP nanosheets in-situ grown on N-doped graphene as an efficient and stable bifunctional electrocatalyst for hydrogen and oxygen evolution reactions
Lu, Y., Hou, W., Yang, D., & Chen, Y. (2019) · Electrochimica Acta · doi:10.1016/j.electacta.2019.03.208 · Cited by 116 · see citing works
Boosting alkaline hydrogen evolution: the dominating role of interior modification in surface electrocatalysis
Li, Z., Niu, W., Yang, Z., Kara, A., Wang, Q., Wang, M., Gu, M. D., Feng, Z., Du, Y., & Yang, Y. (2020) · Energy & Environmental Science · doi:10.1039/d0ee01750g · Cited by 116 · see citing works
Co/CoOx nanoparticles inlaid onto nitrogen-doped carbon-graphene as a trifunctional electrocatalyst
Wen, X., Yang, X., Li, M., Bai, L., & Guan, J. (2018) · Electrochimica Acta · doi:10.1016/j.electacta.2018.11.129 · Cited by 115 · see citing works
Self-citation
Low overpotential and high current CO2 reduction with surface reconstructed Cu foam electrodes
Min, S., Yang, X., Lu, A., Tseng, C., Hedhili, M. N., Li, L., & Huang, K. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.06.043 · Cited by 114 · see citing works
Self-citation
Self-supported porous Ni-Fe-P composite as an efficient electrocatalyst for hydrogen evolution reaction in both acidic and alkaline medium
Ma, Z., Li, R., Wang, M., Meng, H., Zhang, F., Bao, X., Tang, B. H., & Wang, X. (2016) · Electrochimica Acta · doi:10.1016/j.electacta.2016.10.004 · Cited by 112 · see citing works
Structure–Activity Relationships for Pt‐Free Metal Phosphide Hydrogen Evolution Electrocatalysts
Owens‐Baird, B., Kolen’ko, Y. V., & Kovnir, K. A. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201705322 · Cited by 108 · see citing works
CoP nanoparticles anchored on N,P-dual-doped graphene-like carbon as a catalyst for water splitting in non-acidic media
Liu, Y., Zhu, Y., Shen, J., Huang, J., Yang, X., & Li, C. (2018) · Nanoscale · doi:10.1039/c7nr07274k · Cited by 107 · see citing works
Self-citation
Amorphous NiP supported on rGO for superior hydrogen generation from hydrolysis of ammonia borane
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Authors: Yang, X., Lu, A.-Y., Zhu, Y., Hedhili, M. N., Min, S., Huang, K.-W., Han, Y., & Li, L.-J.
Affiliations: King Abdullah University of Science and Technology (SA)
Corresponding author: Li, Lain-Jong
ORCID: Yang, Xiulin
Lu, Ang-Yu
Zhu, Yihan
Hedhili, Mohamed Nejib
Min, Shixiong
Huang, Kuo-Wei
Han, Yu
Li, Lain-Jong
Venue: Nano Energy
Publisher: Elsevier BV
Published: 2015-07
Volume: 15
Pages: 634-641
ISSN: 2211-2855 (ISSN-L)
DOI: 10.1016/j.nanoen.2015.05.026
OpenAlex: W1703055330
Cited by: 385
References: 65
Citations by year: 2026: 10 · 2025: 12 · 2024: 22 · 2023: 24 · 2022: 43 · 2021: 43 · 2020: 50 · 2019: 59 · 2018: 48 · 2017: 48 · 2016: 23 · 2015: 3
FWCI: 12.04
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
www.elsevier.com/legal/tdmrep-license (tdm)
Locations: Nano Energy (publishedVersion)
King Abdullah University of Science and Technology Repository (King Abdullah University of Science and Technology) (submittedVersion)
Funders: King Abdullah University of Science and Technology
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
Keywords: cobalt phosphide, carbon cloth, hydrogen evolution reaction, electrocatalysts, metal phosphides, noble metal-free catalysts, electrodeposition, double-layer capacitance, Tafel slope, acidic and alkaline electrolytes

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CoP nanosheet assembly grown on carbon cloth: A highly efficient electrocatalyst for hydrogen generation

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