Activity and stability of cobalt phosphides for hydrogen evolution upon water splitting

Ha, Don-Hyung; Han, Binghong; Risch, Marcel; Giordano, Livia; Yao, Koffi P.C.; Karayaylali, Pinar; Shao-Horn, Yang

doi:10.1016/j.nanoen.2016.04.034

Cited by 199Electrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesCO2 Reduction Techniques and Catalysts

Activity and stability of cobalt phosphides for hydrogen evolution upon water splitting

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Ha, Don-Hyung, Han, Binghong, Risch, Marcel, Giordano, Livia, Yao, Koffi P.C., Karayaylali, Pinar, Shao-Horn, Yang·2016·Nano Energy

DOI 10.1016/j.nanoen.2016.04.034

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The (011) facet is the predominantly exposed facet of CoP.
“(011) is predominantly exposed facet for CoP.[38]”
From Sub‐1.5 nm Ultrathin CoP Nanosheet Aerogel: Efficient Electrocatalyst for Hydrogen Evolution Reaction at All pH Values (2018) · cites this paper as [38]
The Results and discussion section says the authors calculated which facets of CoP nanoparticles are most likely exposed; (011) had the lowest computed surface energy. Table S3 in DFT calculations confirms that ranking. This supports (011) as a likely exposed facet, but the paper does not establish that it is predominantly exposed. (LLM, conf=0.85)
Experimental — accuracy not yet measured
The reduction in P exposure and P oxidation results in a reduction of the O/Co ratio.
“CoP surface, thus reducing the exposure of P atoms and the degree of P oxidation, resulting in the reduction of O/Co ratio, so that more CoP can participates in HER process and enhance its catalytic ability [49].”
From CoP aerogels assisted by selenite etching as high activity electrocatalysts for water splitting (2023) · cites this paper as [49]
The Results and discussion section links oxidation and (oxy)phosphate formation to an increased O/Co ratio, which supports the proposed direction for reduced oxidation. But it reports that lower P/Co accompanies higher—not lower—O/Co; it does not support reduced P exposure as a cause of lower O/Co. The section also associates higher P/Co with greater HER activity. (LLM, conf=0.85)
Experimental — accuracy not yet measured
Selenite etching reduces the exposure of P atoms and the degree of P oxidation on the CoP surface.
“CoP surface, thus reducing the exposure of P atoms and the degree of P oxidation, resulting in the reduction of O/Co ratio, so that more CoP can participates in HER process and enhance its catalytic ability [49].”
From CoP aerogels assisted by selenite etching as high activity electrocatalysts for water splitting (2023) · cites this paper as [49]
The Results and discussion section links higher O/Co ratios and P oxidation with lower HER activity, supporting the general connection between oxidation and activity. It does not study selenite etching or show that etching reduces P exposure or oxidation; it instead reports that higher P/Co ratios correlate with higher HER activity. Page numbers are unavailable in our copy. (LLM, conf=0.85)
Experimental — accuracy not yet measured
The reduction of the O/Co ratio allows more CoP to participate in the HER process and enhances its catalytic ability.
“CoP surface, thus reducing the exposure of P atoms and the degree of P oxidation, resulting in the reduction of O/Co ratio, so that more CoP can participates in HER process and enhance its catalytic ability [49].”
From CoP aerogels assisted by selenite etching as high activity electrocatalysts for water splitting (2023) · cites this paper as [49]
The Results and discussion section (page not provided) reports that increasing O/Co accompanied reduced HER activity, while higher P/Co correlated with higher activity. It does not establish that reducing O/Co itself causes more CoP to participate in HER; that mechanism goes beyond the reported correlation. (LLM, conf=0.84)
Experimental — accuracy not yet measured
Adsorption of H on the P sites of the CoP (011) facet is more active than on the other sites, consistent with a previous report.
“the adsorption of H on the P sites of (011) is more active than others”
From Sub‐1.5 nm Ultrathin CoP Nanosheet Aerogel: Efficient Electrocatalyst for Hydrogen Evolution Reaction at All pH Values (2018) · cites this paper as [38]

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Authors: Ha, D.-H., Han, B., Risch, M., Giordano, L., Yao, K. P. C., Karayaylali, P., & Shao-Horn, Y.
Affiliations: Massachusetts Institute of Technology (US)
ORCID: Ha, Don-Hyung
Han, Binghong
Risch, Marcel
Giordano, Livia
Yao, Koffi P.C.
Venue: Nano Energy
Publisher: Elsevier BV
Published: 2016-11
Volume: 29
Pages: 37-45
ISSN: 2211-2855 (ISSN-L)
DOI: 10.1016/j.nanoen.2016.04.034
OpenAlex: W2341234305
Cited by: 199
References: 0
Citations by year: 2026: 8 · 2025: 11 · 2024: 17 · 2023: 16 · 2022: 21 · 2021: 23 · 2020: 21 · 2019: 30 · 2018: 36 · 2017: 13 · 2016: 3
FWCI: 7.42
Type: journal article
Language: en
Open access: bronze
doi.org
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
www.elsevier.com/legal/tdmrep-license (tdm)
www.elsevier.com/open-access/userlicense/1.0/ (am, 395 d)
Locations: Nano Energy (acceptedVersion)
BOA (University of Milano-Bicocca) (submittedVersion, other-oa)
DSpace@MIT (Massachusetts Institute of Technology) (submittedVersion, cc-by-nc-nd)
OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
Funders: BASF (022278)
U.S. Department of Energy
Argonne National Laboratory
National Science Foundation (DMR-1419807)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Keywords: cobalt phosphide, hydrogen evolution reaction, water splitting, electrocatalysis, catalyst stability, phosphate formation, colloidal synthesis, photoelectrochemical hydrogen production

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