The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Surface step decoration of isolated atom as electron pumping: Atomic-level insights into visible-light hydrogen evolution
Abstract
Abstract Here we realize the decoration of isolated platinum atoms onto the surface step of CdS nanowires. The single-atom co-catalyst with high stability can realize maximum atom efficiency and significantly boost electron-hole separation efficiency in chromophore units, generating a greatly enhanced photocatalytic hydrogen evolution performance, 7.69 times as high as Pt nanoparticles do and 63.77 times higher than that of bare CdS nanowires. Directional migrations of photogenerated excitons from the conduction band of CdS to catalytic platinum centers have been witnessed by transient absorption spectroscopy, leading to the supply of long-lived electrons for highly efficient photocatalytic hydrogen evolution. Density functional theory calculations further confirm that the excellent catalytic performance is associated with positively charged platinum sites with partially vacant 5d orbitals, which change distribution of charge density and facilitate higher excited carrier density.
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Cites
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
Cheng, N., Stambula, S., Wang, D., Banis, M. N., Liu, J., Riese, A., Xiao, B., Li, R., Sham, T.-K., Liu, L.-M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13638 · Cited by 2,072
Atomic cobalt on nitrogen-doped graphene for hydrogen generation
Fei, H., Dong, J., Arellano-Jiménez, M. J., Ye, G., Dong Kim, N., Samuel, E. L. G., Peng, Z., Zhu, Z., Qin, F., Bao, J., et al. (2015) · Nature Communications · doi:10.1038/ncomms9668 · Cited by 1,621
Self-citationTuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst
Choi, C. H., Kim, M., Kwon, H. C., Cho, S. J., Yun, S., Kim, H.-T., Mayrhofer, K. J. J., Kim, H., & Choi, M. (2016) · Nature Communications · doi:10.1038/ncomms10922 · Cited by 849
Molecular metal–Nx centres in porous carbon for electrocatalytic hydrogen evolution
Liang, H.-W., Brüller, S., Dong, R., Zhang, J., Feng, X., & Müllen, K. (2015) · Nature Communications · doi:10.1038/ncomms8992 · Cited by 655
Self-citation
Cited by
Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications
Gao, C., Low, J., Long, R., Kong, T., Zhu, J., & Xiong, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00840 · Cited by 1,050
Ultrasmall MoOx Clusters as a Novel Cocatalyst for Photocatalytic Hydrogen Evolution
Zhang, H., Zhang, P., Qiu, M., Dong, J., Zhang, Y., & Lou, X. W. (. (2019) · Advanced Materials · doi:10.1002/adma.201804883 · Cited by 309
Self-citationXu, G., Zhang, H., Wei, J., Zhang, H.-X., Wu, X., Li, Y., Li, C., Zhang, J., & Ye, J. (2018) · ACS Nano · doi:10.1021/acsnano.8b00110 · Cited by 298
Self-citationSolanki, R., Patra, I., Ahmad, N., Kumar, N. B., Parra, R. M. R., Zaidi, M., Yasin, G., Anil Kumar, T. C., Hussein, H. A., Sivaraman, R., et al. (2022) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2022.108207 · Cited by 49
Metadata
- Authors
- Wu, X., Zhang, H., Dong, J., Qiu, M., Kong, J., Zhang, Y., Li, Y., Xu, G., Zhang, J., & Ye, J.
- Venue
- Nano Energy
- Publisher
- Elsevier BV
- Published
- 2018-03
- Volume
- 45
- Pages
- 109-117
- ISSN
- 2211-2855 (ISSN-L)
- OpenAlex
- W2778011457
- Cited by
- 158
- References
- 4
- FWCI
- 3.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wu, X., Zhang, H., Dong, J., Qiu, M., Kong, J., Zhang, Y., Li, Y., Xu, G., Zhang, J., & Ye, J. (2018). Surface step decoration of isolated atom as electron pumping: Atomic-level insights into visible-light hydrogen evolution. Nano Energy. https://doi.org/10.1016/j.nanoen.2017.12.039
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